Stability of temperatures from TIMED/SABER v1.07 (2002–2009) and Aura/MLS v2.2 (2004–2009) compared with OH(6-2) temperatures observed at Davis Station, Antarctica

Temperature profiles from two satellite instruments – TIMED/SABER and Aura/MLS – have been used to calculate hydroxyl-layer equivalent temperatures for comparison with values measured from OH(6-2) emission lines observed by a ground-based spectrometer located at Davis Station, Antarctica (68° S, 78° E). The profile selection criteria – miss-distance <500 km from the ground station and solar zenith angles >97° – yielded a total of 2359 SABER profiles over 8 years (2002–2009) and 7407 MLS profiles over 5.5 years (2004–2009). The availability of simultaneous OH volume emission rate (VER) profiles from the SABER (OH-B channel) enabled an assessment of the impact of several different weighting functions in the calculation of OH-equivalent temperatures. The maximum difference between all derived hydroxyl layer equivalent temperatures was less than 3 K. Restricting the miss-distance and miss-time criteria showed little effect on the bias, suggesting that the OH layer is relatively uniform over the spatial and temporal scales considered. However, a significant trend was found in the bias between SABER and Davis OH of ~0.7 K/year over the 8-year period with SABER becoming warmer compared with the Davis OH temperatures. In contrast, Aura/MLS exhibited a cold bias of 9.9 ± 0.4 K compared with Davis OH, but importantly, the bias remained constant over the 2004–2009 year period examined. The difference in bias behaviour of the two satellites has significant implications for multi-annual and long-term studies using their data.

Stability of temperatures from TIMED/SABER v1.07 (2002–2009) and Aura/MLS v2.2 (2004–2009) compared with OH(6-2) temperatures observed at Davis Station, Antarctica

Temperature profiles from two satellite instruments – TIMED/SABER and Aura/MLS – have been used to calculate hydroxyl-layer equivalent temperatures for comparison with values measured from OH(6-2) emission lines observed by a ground-based spectrometer located at Davis Station, Antarctica (68° S, 78° E). The profile selection criteria – <500 km from the ground station and solar zenith angles >97° – yielded a total of 2359 SABER profiles over 8 years (2002–2009) and 7407 MLS profiles over 5.5 years (2004–2009). The availability of simultaneous OH volume emission rate (VER) profiles from the SABER (OH-B channel) enabled an assessment of the impact of several different weighting functions in the calculation of OH-equivalent temperatures. The maximum difference between all derived hydroxyl layer equivalent temperatures was less than 3 K. Restricting the miss-distance and miss-time criteria showed little effect on the bias, suggesting that the OH layer is relatively uniform over the spatial and temporal scales considered. However, a significant trend was found in the bias between SABER and Davis OH of ~0.7 K/year over the 8-year period with SABER becoming warmer compared with the Davis OH temperatures. In contrast, Aura MLS exhibited a cold bias of 9.9 ± 0.4 K compared with Davis OH, but importantly, the bias remained constant over the 2004–2009 year period examined. The difference in bias behaviour of the two satellites has significant implications for multi-annual and long-term studies using their data.

Inferring hydroxyl layer peak heights from ground-based measurements of OH(6-2) band integrated emission rate at Longyearbyen (78° N, 16° E)

Measurements of hydroxyl nightglow emissions over Longyearbyen (78° N, 16° E) recorded simultaneously by the SABER instrument onboard the TIMED satellite and a ground-based Ebert-Fastie spectrometer have been used to derive an empirical formula for the height of the OH layer as a function of the integrated emission rate (IER). Altitude profiles of the OH volume emission rate (VER) derived from SABER observations over a period of more than six years provided a relation between the height of the OH layer peak and the integrated emission rate following the procedure described by Liu and Shepherd (2006). An extended period of overlap of SABER and ground-based spectrometer measurements of OH(6-2) IER during the 2003–2004 winter season allowed us to express ground-based IER values in terms of their satellite equivalents. The combination of these two formulae provided a method for inferring an altitude of the OH emission layer over Longyearbyen from ground-based measurements alone. Such a method is required when SABER is in a southward looking yaw cycle. In the SABER data for the period 2002–2008, the peak altitude of the OH layer ranged from a minimum near 76 km to a maximum near 90 km. The uncertainty in the inferred altitude of the peak emission, which includes a contribution for atmospheric extinction, was estimated to be ±2.7 km and is comparable with the ±2.6 km value quoted for the nominal altitude (87 km) of the OH layer. Longer periods of overlap of satellite and ground-based measurements together with simultaneous on-site measurements of atmospheric extinction could reduce the uncertainty to approximately 2 km.

Mechanism of the hydrogen-oxygen reaction on platinum films from surface potential measurements

The surface-potential changes that occur during the reaction of hydrogen and oxygen on an evaporated platinum film have been recorded by means of the static capacitor method. A sequence of reaction steps has been proposed for the reactions of hydrogen gas with an oxygen-adatom monolayer, and oxygen gas with a hydrogen-adatom layer. The chemisorption of water vapour, by both a clean film and one covered with an oxygen or hydrogen monolayer, has also been investigated. From separate measurements of the s.p. of monolayers of oxygen, hydrogen and water, that of a hydroxyl layer has been calculated; from these values and the measured uptakes of oxygen and hydrogen, the complete s.p. plots have been calculated with consistent agreement with the experimental values. The presence of groups of surface sites of different reactivity previously suggested is confirmed. Explanations for the lack of stoichiometry of the hydrogen titration results reported in the literature and for lack of agreement with infrared results on oxide-supported metal are outlined.