Synthesis and oxidation catalysis of a difluoride-incorporated polyoxovanadate and isolation of active vanadium alkylperoxo species

Elucidation of the correlation between the catalytic performance and the structures of active sites on inorganic materials provides insights into the chemistry of the local structures on metal oxide catalysts....

Identifying Fe3Mn3O8 Phase as the Superior Catalyst for Low-Temperature Catalytic Oxidation of Formaldehyde in Air

This work reports the efficient binary Fe-Mn metal oxide catalysts for low-temperature formaldehyde (HCHO) oxidation in air. The highest catalytic activity was obtained at the molar ratio of Fe/Mn =...

Obtaining cyclopentanone in the presence of metal oxides

The possibility of obtaining cyclopentanone by pyrolysis of calcium adipate at different temperatures was considered. The pyrolysis proceeded with the formation of cyclopentanone and cyclopentene. The use of metal salts and metal oxide catalysts for the dehydrogenation of lower alkanes makes it possible to increase the yields of the target products. The best results were achieved in the presence of a «K-16u» catalyst.