Pore-Scale Investigation of the Electrical Property and Saturation Exponent of Archie’s Law in Hydrate-Bearing Sediments

Characterizing the electrical property of hydrate-bearing sediments is essential for hydrate reservoir identification and saturation evaluation. As the major contributor to electrical conductivity, pore water is a key factor in characterizing the electrical properties of hydrate-bearing sediments. The objective of this study is to clarify the effect of hydrates on pore water and the relationship between pore water characteristics and the saturation exponent of Archie’s law in hydrate-bearing sediments. A combination of X-ray computed tomography and resistivity measurement technology is used to derive the three-dimensional spatial structure and resistivity of hydrate-bearing sediments simultaneously, which is helpful to characterize pore water and investigate the saturation exponent of Archie’s law at the micro-scale. The results show that the resistivity of hydrate-bearing sediments is controlled by changes in pore water distribution and connectivity caused by hydrate formation. With the increase of hydrate saturation, pore water connectivity decreases, but the average coordination number and tortuosity increase due to much smaller and more tortuous throats of pore water divided by hydrate particles. It is also found that the saturation exponent of Archie’s law is controlled by the distribution and connectivity of pore water. As the parameters of connected pore water (e.g., porosity, water saturation) decrease, the saturation exponent decreases. At a low hydrate-saturation stage, the saturation exponent of Archie’s law changes obviously due to the complicated pore structure of hydrate-bearing sediments. A new logarithmic relationship between the saturation exponent of Archie’s law and the tortuosity of pore water is proposed which helps to calculate field hydrate saturation using resistivity logging data.

Strain-Softening Characteristics of Hydrate-Bearing Sediments and Modified Duncan–Chang Model

Marine hydrate exploitation may trigger the seabed geological disaster, such as seafloor collapse and landslide. It is critically important to understand the mechanical properties of hydrate-bearing sediment. Strain-softening observation is a typical behavior of hydrate-bearing sediment (HBS) and exhibits more significant at higher hydrate saturation. This paper performed a series of triaxial compression tests on methane hydrate-bearing sand to analyze the influence rule and mechanism of hydrate saturation on the strain-softening characteristic, stiffness, and strength and introduced the strain-softening index to quantificationally characterize the strain-softening behaviors of HBS with different hydrate saturations. Based on the analyses on the mechanical behavior of HBS, the Duncan–Chang model is extended to address the stress-strain curves of HBS. Two empirical formulas with hydrate saturation embedded are used to characterize the enhanced initial modulus and strength for HBS, respectively. To address the strain-softening behavior of HBS, the modified Duncan–Chang model introduced a damage factor into the strength of HBS. To validate the modified Duncan–Chang model, four different triaxial compression tests are simulated. The good consistence between simulated result and experimental data demonstrates that the modified Duncan–Chang model is capable of reflecting the influence of hydrate saturation not only on the stiffness and strength but also on the strain-softening characteristics of HBS.