Hydrogenation of CO/CO2 mixtures under unsteady-state conditions: Effect of the carbon oxides on the dynamic methanation process

The Power-to-Gas (PtG) process offers the opportunity to store fluctuating renewable energy in form of chemical energy by hydrogenating carbon oxides into methane. In addition, potential carbon point sources often consist of CO/CO2 (COx) mixtures. Hence, reactor design requires kinetic models valid for unsteady-state operation and a broad spectrum of feed gas compositions. In order to provide the required experimental data basis for derivation of kinetic expressions valid under transient conditions, the dynamic response of a continuously operated fixed-bed methanation reactor is studied by applying periodic step-changes in the feed composition. The obtained results are evaluated based on a simple reactor model, providing the molar flow rate exchanged between the gas bulk and the solid surface for CO, CO2, CH4, and H2O. The results further reveal that the transient kinetic processes at the catalyst surface strongly affect the reactor response under reaction conditions of technical relevance.

Thermochemistry of Combustion in Polyvinyl Alcohol + Hydroxylammonium Nitrate

A mixture of polyvinyl alcohol (PVA) and hydroxylammoniun nitrate (HAN) forms a gummy solid known as a plastisol, which is ionically conducting. When an electrostatic potential of 200 V DC is applied across the plastisol, it ignites. Combustion ceases upon removal of the applied voltage. The products of PVA + HAN combustion are known to include the molecular gases carbon monoxide, carbon dioxide, water, nitrogen, and hydrogen. When the electric field within the plastisol is spatially uniform, combustion occurs preferentially at the anode. The fact that HAN is an ionic conductor suggests that the mechanism of combustion is electrolytic in origin. Consistent with the preference for combustion at the anode and the known gaseous products, we consider two reaction mechanisms. One involves atomic oxygen as the oxidizing agent at the anode and hydroxyl radical as the oxidizing agent at the cathode. The other involves ozone as the oxidizing agent at the anode and hydrogen peroxide as the oxidizing agent at the cathode. Each mechanism is applied to a scenario where the products are rich in the carbon oxides and to a second scenario where the products are poor in the carbon oxides. In the rich case, the heat of the overall reaction is −808.33 kJ per mole of HAN consumed and the electrical energy is converted to thermal energy with an efficiency of 4.2%. In the poor case, the corresponding figures are −567 kJ per mole of HAN and efficiency is 2.9%. The combustion reactions at the electrodes are uniformly exothermic with the exception of the reaction involving hydrogen peroxide at the cathode. When the products are poor in the carbon oxides, this reaction is actually endothermic.

Assessment of Petrol and Natural Gas Vehicle Carbon Oxides Emissions in the Laboratory and On-Road Tests

The problem of global warming and the related climate change requires solutions to reduce greenhouse gas emissions, in particular CO2. As a result, newly manufactured cars consume less fuel and emit lower amounts of CO2. In terms of exhaust emissions and fuel consumption, old cars are significantly inferior to the more recent models. In Poland, for instance, the average age of passenger cars is approximately 13 years. Therefore, apart from developing new solutions in the cars produced today, it is important to focus on measures that enable the reduction in CO2 emissions in older vehicles. These methods include the adaptation of used cars to run on gaseous fuels. Natural gas is a hydrocarbon fuel that is particularly preferred in terms of CO2 emissions. The article presents the results of research of carbon oxides emission (CO, CO2) in the exhaust gas of a passenger car fueled by petrol and natural gas. The emissions were measured under the conditions of the New European Driving Cycle (NEDC) test and in real road tests. The test results confirm that compared to petrol, a CNG vehicle allows for a significant reduction in CO2 and CO emissions in a car that is several years old, especially in urban traffic conditions.