Biopolymer Degradation Analysis: Accelerated Life Testing Study to Characterize Polylactic Acid Durability

While the degradation of Polylactic Acid (PLA) has been studied for several years, results regarding the mechanism for determining degradation are not completely understood. Through accelerated degradation testing, data can be extrapolated and modeled to test parameters such as temperature, voltage, time, and humidity. Accelerated lifetime testing is used as an alternative to experimentation under normal conditions. The methodology to create this model consisted of fabricating series of ASTM specimens using extrusion and injection molding. These specimens were tested through accelerated degradation; tensile and flexural testing were conducted at different points of time. Nonparametric inference tests for multivariate data are presented. The results indicate that the effect of the independent variable or treatment effect (time) is highly significant. This research intends to provide a better understanding of biopolymer degradation. The findings indicated that the proposed statistical models can be used as a tool for characterization of the material regarding the durability of the biopolymer as an engineering material. Having multiple models, one for each individual accelerating variable, allow deciding which parameter is critical in the characterization of the material.

Triangular cyclic accelerated degradation zero-failure test plan

Purpose Zero-failure reliability testing aims at demonstrating whether the product has achieved the desired reliability target with zero failure and high confidence level at a given time. Incorporating accelerated degradation testing in zero-failure reliability demonstration test (RDT) facilitates early failure in high reliability items developed within short period of time to be able to survive in fiercely competitive market. The paper aims to discuss these issues. Design/methodology/approach The triangular cyclic stress uses one test chamber thus saving experimental cost. The parameters in model are estimated using maximum likelihood methods. The optimum plan consists in finding out optimum number of cycles, optimum specimens, optimum stress change point(s) and optimum stress rates. Findings The optimum plan consists in finding out optimum number of cycles, optimum specimens, optimum stress change point(s) and optimum stress rates by minimizing asymptotic variance of estimate of quantile of the lifetime distribution at use condition subject to the constraint that total testing or experimental cost does not exceed a pre-specified budget. Confidence intervals of the design parameters have been obtained and sensitivity analysis carried out. The results of sensitivity analysis show that the plan is robust to small deviations from the true values of baseline parameters. Originality/value For some highly reliable products, even accelerated life testing yields little failure data of units in a feasible amount of time. In such cases accelerated degradation testing is carried out, wherein the failure termed as soft failure is defined in terms of performance characteristic of the product exceeding its critical (threshold) value.