Intrinsic properties of conservation-dissipation formalism of irreversible thermodynamics

This paper proposes four fundamental requirements for establishing PDEs (partial differential equations) modelling irreversible processes. We show that the PDEs derived via the CDF (conservation-dissipation formalism) meet all the requirements. In doing so, we find useful constraints on the freedoms of CDF and point out that a shortcoming of the formalism can be remedied with the help of the Maxwell iteration. It is proved that the iteration preserves the gradient structure and strong dissipativeness of the CDF-based PDEs. A refined formulation of the second law of thermodynamics is given to characterize the strong dissipativeness, while the gradient structure corresponds to nonlinear Onsager relations. Further advantages and limitations of CDF will also be presented. This article is part of the theme issue ‘Fundamental aspects of nonequilibrium thermodynamics’.

A panoply of Schwinger-Keldysh transport

We classify all possible allowed constitutive relations of relativistic fluids in a statistical mechanical limit using the Schwinger-Keldysh effective action for hydrodynamics. We find that microscopic unitarity enforces genuinely new constraints on the allowed transport coefficients that are invisible in the classical hydrodynamic description; they are not implied by the second law or the Onsager relations. We term these conditions Schwinger-Keldysh positivity and provide explicit examples of the various allowed terms.

Ergodicity, Maximum Entropy Production, and Steepest Entropy Ascent in the Proofs of Onsager’s Reciprocal Relations

We show that to prove the Onsager relations using the microscopic time reversibility one necessarily has to make an ergodic hypothesis, or a hypothesis closely linked to that. This is true in all the proofs of the Onsager relations in the literature: from the original proof by Onsager, to more advanced proofs in the context of linear response theory and the theory of Markov processes, to the proof in the context of the kinetic theory of gases. The only three proofs that do not require any kind of ergodic hypothesis are based on additional hypotheses on the macroscopic evolution: Ziegler’s maximum entropy production principle (MEPP), the principle of time reversal invariance of the entropy production, or the steepest entropy ascent principle (SEAP).