classical equilibrium
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2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Andy M. Reynolds

AbstractSinhuber et al. (Sci Rep 11:3773, 2021) formulated an equation of state for laboratory swarms of the non-biting midge Chironomus riparius that holds true when the swarms are driven through thermodynamic cycles by the application external perturbations. The findings are significant because they demonstrate the surprising efficacy of classical equilibrium thermodynamics for quantitatively characterizing and predicting collective behaviour in biology. Nonetheless, the equation of state obtained by Sinhuber et al. (2021) is anomalous, lacking a physical analogue, making its’ interpretation problematic. Moreover, the dynamical processes underlying the thermodynamic cycling were not identified. Here I show that insect swarms are equally well represented as van der Waals gases and I attribute the possibility of thermodynamic cycling to insect swarms consisting of several overlapping sublayers. This brings about a profound change in the understanding of laboratory swarms which until now have been regarded as consisting of non-interacting individuals and lacking any internal structure. I show how the effective interactions can be attributed to the swarms’ internal structure, the external perturbations and to the presence of intrinsic noise. I thereby show that intrinsic noise which is known to be crucial for the emergence of the macroscopic mechanical properties of insect swarms is also crucial for the emergence of their thermodynamic properties as encapsulated by their equation of state.


Entropy ◽  
2021 ◽  
Vol 23 (2) ◽  
pp. 165
Author(s):  
Miroslav Grmela

Multiscale thermodynamics is a theory of the relations among the levels of investigation of complex systems. It includes the classical equilibrium thermodynamics as a special case, but it is applicable to both static and time evolving processes in externally and internally driven macroscopic systems that are far from equilibrium and are investigated at the microscopic, mesoscopic, and macroscopic levels. In this paper we formulate multiscale thermodynamics, explain its origin, and illustrate it in mesoscopic dynamics that combines levels.


Metals ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 74
Author(s):  
Chunping Zhang ◽  
Mohammad Jahazi ◽  
Paloma Isabel Gallego

The impact of microsegregation models on thermophysical properties and solidification behaviors of a high strength steel was investigated. The examined microsegregation models include the classical equilibrium Lever rule, the extreme non-equilibrium Scheil-Gulliver, as well as other treatments in the intermediate regime proposed by Brody and Flemings, Clyne and Kurz, Kobayashi and Ohnaka. Based on the comparative analyses performed on three representative regions with varied secondary dendrite arm spacing sizes, the classical equilibrium Lever rule and non-equilibrium Scheil scheme were employed to determine the thermophysical features of the studied steel, using the experimentally verified models from literature. The evaluated thermophysical properties include effective thermal conductivity, specific heat capacity and density. The calculated thermophysical data were used for three-dimensional simulation of the casting and solidification process of a 40 metric ton steel ingot, using FEM code Thercast®. The simulations captured the full filling, the thermo-mechanical phenomena and macro-scale solute transport in the cast ingot. The results demonstrated that Lever rule turned out to be the most reasonable depiction of the physical behavior of steel in study in large-size cast ingot and appropriate for the relevant macrosegregation simulation study. The determination of the model was validated using the experimentally measured top cavity dimension, the thermal profiles on the mold outside surface by means of thermocouples, and the carbon distribution patterns via mass spectrometer analysis.


Quantum ◽  
2019 ◽  
Vol 3 ◽  
pp. 185 ◽  
Author(s):  
Manik Banik ◽  
Some Sankar Bhattacharya ◽  
Nirman Ganguly ◽  
Tamal Guha ◽  
Amit Mukherjee ◽  
...  

Entanglement is of paramount importance in quantum information theory. Its supremacy over classical correlations has been demonstrated in a numerous information theoretic protocols. Here we study possible adequacy of quantum entanglement in Bayesian game theory, particularly in social welfare solution (SWS), a strategy which the players follow to maximize sum of their payoffs. Given a multi-partite quantum state as an advice, players can come up with several correlated strategies by performing local measurements on their parts of the quantum state. A quantum strategy is called quantum-SWS if it is advantageous over a classical equilibrium (CE) strategy in the sense that none of the players has to sacrifice their CE-payoff rather some have incentive and at the same time it maximizes sum of all players' payoffs over all possible quantum advantageous strategies. Quantum state yielding such a quantum-SWS is called a quantum social welfare advice (SWA). We show that any two-qubit pure entangled state, even if it is arbitrarily close to a product state, can serve as quantum-SWA in some Bayesian game. Our result, thus, gives cognizance to the fact that every two-qubit pure entanglement is the best resource for some operational task.


Author(s):  
M. Motoe

Several simulations of evaporation and combustion of a fuel droplet are performed as preliminary stage for the combustion simulation in the chamber of bipropellant thrusters. First, the evaporation simulation without chemical reaction for single droplets of water and n-heptane are performed. Two evaporation models such as classical equilibrium and nonequilibrium Langmuir–Knudsen models are used for the simulation, and their characteristics are studied in order to investigate the difference between the two models. Then, the accuracy of the numerical code using this study is confirmed by means of comparison with existing experimental results. Next, the evaporation simulation with chemical reaction for single droplets of hydrazine is performed and the accuracy of the numerical code is confirmed by the same way. From these simulations, it is considered that the code and the scheme using this simulation have reasonable accuracy for droplet simulation with evaporation and combustion.


2015 ◽  
Vol 142 (22) ◽  
pp. 224102 ◽  
Author(s):  
Andrew E. Sifain ◽  
Linjun Wang ◽  
Oleg V. Prezhdo

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