Scalable All-Printed Microwave Microfluidic Sensor for Multi-Liquid Characterization based on a Stub-Loaded Microstrip Line

Microwave microfluidic sensors are typically designed with a channel in vicinity of a resonator's fringing electric (<i>E</i>)-fields, to characterize the material properties of a single fluid. This paper leverages hybrid 3D and dispenser printing to realize a scalable microfluidic sensor utilizing the parallel-plate capacitance of an open-ended microstrip stub, enabling, for the first time, a tunable sensitivity. A stub-loaded microstrip line is then proposed for characterizing multiple microfluidic samples simultaneously using a simple two-port multi-band resonator. The physical constrains which limit the scalability of the proposed sensors have been analyzed analytically and numerically, prior to implementing a three-channel triple-band sensor. The microfluidic channels have been fabricated using stereolithography 3D printing with the microstrip line directly dispenser printed on a conformable polyimide substrate. To accommodate varying channel thicknesses, a tapered microstrip line is proposed to maintain the impedance matching. The fabricated sensor is characterized using binary water-IPA mixtures to evaluate its sensitivity, comparing favorably with reported 3D-printed sensors. The proposed sensor achieves over 90% accuracy in determining the real permittivity following a simple water-based calibration across the different channels, for samples with 16 oC temperature sensitivity across all channels.

Scalable All-Printed Microwave Microfluidic Sensor for Multi-Liquid Characterization based on a Stub-Loaded Microstrip Line

Microwave microfluidic sensors are typically designed with a channel in vicinity of a resonator's fringing electric (<i>E</i>)-fields, to characterize the material properties of a single fluid. This paper leverages hybrid 3D and dispenser printing to realize a scalable microfluidic sensor utilizing the parallel-plate capacitance of an open-ended microstrip stub, enabling, for the first time, a tunable sensitivity. A stub-loaded microstrip line is then proposed for characterizing multiple microfluidic samples simultaneously using a simple two-port multi-band resonator. The physical constrains which limit the scalability of the proposed sensors have been analyzed analytically and numerically, prior to implementing a three-channel triple-band sensor. The microfluidic channels have been fabricated using stereolithography 3D printing with the microstrip line directly dispenser printed on a conformable polyimide substrate. To accommodate varying channel thicknesses, a tapered microstrip line is proposed to maintain the impedance matching. The fabricated sensor is characterized using binary water-IPA mixtures to evaluate its sensitivity, comparing favorably with reported 3D-printed sensors. The proposed sensor achieves over 90% accuracy in determining the real permittivity following a simple water-based calibration across the different channels, for samples with 16 oC temperature sensitivity across all channels.

Investigation of Nozzle Height Control to Improve Dispenser Printing of E-Textiles

Dispenser printing is a versatile way of manufacturing prototype and bespoke e-textiles that uses a robotically actuated nozzle to dispense pastes. Investigation of printing on a flat substrate, however, revealed that the nozzle must be kept between 50 and 200 µm above the material’s surface in order to print effectively. In order to maintain this clearance when printing on uneven materials, the surface topography of the substrate must be measured and compensated for. However, the accuracy of the laser displacement meter used here was reduced when measuring the translucent interface layer necessary when printing on textiles. Adding various concentrations of dye to the interface was explored. A single layer of interface with 20 mg of dye added per gram showed significantly improved results with an average error of 146 µm compared to the 550 µm for the clear interface. Crucially, the standard deviation in the error was only 31 µm, down from 101 µm, meaning that an offset could be applied to get measurements that would keep the nozzle’s clearance within the necessary 150 µm range.

Fully Printed Flexible Chemiresistors with Tunable Selectivity Based on Gold Nanoparticles

This study presents a method for printing flexible chemiresistors comprising thin film transducers based on cross-linked gold nanoparticles (GNPs). First, interdigitated silver paste electrodes are printed onto polyimide (PI) foil via dispenser printing. Second, coatings of GNPs and dithiol/monothiol blends are inkjet-printed onto these electrode structures. 1,9-Nonanedithiol (9DT) is used as cross-linking agent and a variety of monothiols are added to tune the sensors’ chemical selectivity. When dosing these sensors with different analyte vapors (n-octane, toluene, 4-methyl-2-pentanone, 1-butanol, 1-propanol, ethanol, water; concentration range: 25–2000 ppm) they show fully reversible responses with short response and recovery times. The response isotherms follow a first-order Langmuir model, and their initial slopes reveal sensitivities of up to 4.5 × 10−5 ppm−1. Finally, it is demonstrated that arrays of printed sensors can be used to clearly discern analytes of different polarity.

Towards 3D-lithium ion microbatteries based on silicon/graphite blend anodes using a dispenser printing technique

Silicon/carbon–graphite blend slurries designed for 3D-dispenser printed lithium ion microbatteries systematically characterized by rheological and electrochemical methods.

A Printable Paste Based on a Stable n-Type Poly[Ni-tto] Semiconducting Polymer

Polynickeltetrathiooxalate (poly[Ni-tto]) is an n-type semiconducting polymer having outstanding thermoelectric characteristics and exhibiting high stability under ambient conditions. However, its insolubility limits its use in organic electronics. This work is devoted to the production of a printable paste based on a poly[Ni-tto]/PVDF composite by thoroughly grinding the powder in a ball mill. The resulting paste has high homogeneity and is characterized by rheological properties that are well suited to the printing process. High-precision dispenser printing allows one to apply both narrow lines and films of poly[Ni-tto]-composite with a high degree of smoothness. The resulting films have slightly better thermoelectric properties compared to the original polymer powder. A flexible, fully organic double-leg thermoelectric generator with six thermocouples was printed by dispense printing using the poly[Ni-tto]-composite paste as n-type material and a commercial PEDOT-PSS paste as p-type material. A temperature gradient of 100 K produces a power output of about 20 nW.