Spark Plasma Synthesis and Sintering of Superconducting MgB2-Based Materials

Superconducting (SC) and mechanical properties of spark plasma (or SPS) produced MgB2 –based materials allow their efficient applications in fault current limiters, superconducting electromotors, pumps, generators, magnetic bearings, etc. The synthesized from Mg and B at 50 MPa, 1050 °C for 30 min material has a density of 2.52 g/cm3, critical current density, jc = 7.1•105 A/cm2 at 10 K , 5.4 •105 A/cm2 at 20 K, and 9•104 A/cm2 at 35 K in zero magnetic field; at 20 K its field of irreversibility Birr(20)=7 T and upper critical field Bc2(20)=11 T; microhardness HV=10.5 GPa and fracture toughness K1C =1.7 MPa•m1/2 at 4.9 N-load. SPS-manufactured in- situ MgB2-based materials usually have somewhat higher jc than sintered ex-situ. The pressure variations from 16 to 96 MPa during the SPS-process did not affect material SC characteristics significantly; the jc at 10-20 K was slightly higher and the material density was higher by 11%, when pressures of 50-96 MPa were used. The structure of SPS-produced MgB2 material contains Mg-B-O inclusions and inclusions of higher borides (of compositions near MgB4, MgB7, MgB12, MgB17, MgB20), which can be pinning centers. The presence of higher borides in the MgB2 structure can be revealed by the SEM and Raman spectroscopy.

Preparation of Dense Ultrafine TiAl Alloys by Spark Plasma Synthesis from Mechanically Activated Powders

Powder of Ti-46at%Al alloy was synthesized through mechanical activation (MA) and then sintered and concurrently consolidated in a short sintering time of 900 s by using spark plasma sintering (SPS) process. The XRD and SEM profiles show that the microstructures of TiAl alloys contained γ TiAl and small amount α-2 Ti3Al phase, whose amount can be controlled by the sintering temperature. The compacts retained the original fine-grained fully densified bodies by avoiding an excessively high sintering temperature. The alloys sintered at higher temperature with this process showed a coarser microstructure. So it is possible to produce dense nanostructured TiAl alloys by mechanically activated spark plasma sintering (MASPS) within a very short period of time.