Enhanced decomposition of laminated ammonium perchlorate composite

In order to improve the thermal decomposition performances of ammonium perchlorate (AP), the laminated AP composite was prepared by ice-template induced self-assembly method. In this study, Iron-Konjac glucomannan (Fe3+-KGM) hydrosol rich in AP was selected as the freezing precursor. Through directional freezing of precursor and recrystallization of AP molecules, the laminated AP composite was obtained. The results showed that the thickness of the lamellar composite structure is about 10 to 30 μm, and the recrystallized AP particles are uniformly dispersed in the gel system. The oxygen bomb test results show that the micro-/nano-layered structure can significantly improve the sample’s combustion heat value. Thermal analyses indicated that with the increasing Fe3+ content, the peak exothermic temperature of lamellar AP composite at different heating rates both showed a decreasing trend. With 10 wt% Fe(NO3)3·9H2O added, the decomposition peak temperature decreased from 433.0 to 336.2 °C at a heating rate of 5 °C/min, and the apparent activation energy (Ea) decreased dramatically from 334.1 kJ/mol to 255.4 kJ/mol. A possible catalytic thermal decomposition mechanism of lamellar AP composite catalyzed by Fe3+ was proposed. This work is beneficial to the structural design of other energetic materials.

Experimental Study on Frost-Heaving Force Development of Tibetan Clay Subjected to One-Directional Freezing in an Open System

Frost heave of soils involves complex coupled interactions among moisture, heat, and stress, which can cause serious damage to cold regions engineering. In this paper, a series of one-directional freezing experiments were implemented for the Tibetan clay with rigid restraint in an open system. The varying characteristics of the temperature, frost-heaving force, and water replenishment during the freezing process were analyzed under different freezing temperatures (−5, −7, and − 9°C), dry densities (1.65, 1.7, and 1.75 g cm−3), and initial moisture contents (11, 14, and 17%) of the soil samples. It was concluded that the freezing of soil samples mainly occurred within 10–25 hours from the beginning of the experiment; hereafter, the soil temperatures tended to be stable. The development of frost-heaving force could be divided into three stages as slow increase, quick increase, and relative stable stages. Low freezing temperature, large dry density, and high moisture content were all the contributors to the frost-heaving process of the soil, which could increase the freezing depth, magnitude of the frost-heaving force, and amount of water replenishment. The variations in water replenishment from the open system corresponded to the three stages of the frost-heaving force but had time lags. The moisture contents at different layers of soil samples were measured after the freezing experiment. The results showed that the freeze part of soil samples experienced a significant wetting, while the unfrozen part experienced drying during the experiment. The degrees of wetting and drying were related to the freezing temperature, dry density, and initial moisture content of the soil samples. The experiment results could provide data support for theoretical study on moisture, heat, and stress coupling in freezing soil.

Unveiling cells’ local environment during cryopreservation by correlative in situ spatial and thermal analyses

Cryopreservation is the only fully established procedure to extend the lifespan of living cells and tissues, a key to activities spanning from fundamental biology to clinical practice. Despite its prevalence and impact, central aspects of cryopreservation, such as the cell’s physico-chemical environment during freezing, remain elusive. Here we address that question by coupling in situ microscopic directional freezing to visualize cells and their surroundings during freezing with the freezing medium phase diagram. We extract the freezing medium spatial distribution in cryopreservation, providing a tool to describe the cell vicinity at any point during freezing. We show that two major events define the cells’ local environment over time: the interaction with the moving ice front and with the vitreous moving front – a term we introduce here. Our correlative strategy may be applied to cells relevant in clinical research and practice, and help designing new cryoprotective media based on local physico-chemical cues.

Compressible AgNWs/Ti3C2Tx MXene aerogel-based highly sensitive piezoresistive pressure sensor as versatile electronic skins

AgNWs/Ti3C2Tx MXene aerogel with well-aligned layer structure was prepared by a directional freezing strategy, and applied to fabricate piezoresistive pressure sensor, which has ultrahigh sensitivity (645.69 kPa−1) and low detection limit (1.25 Pa).