Controlling Toughness of Polymer-grafted Nanoparticle Composites for Impact Mitigation

Toughness in an entangled polymer network is typically controlled by the number of load-bearing topological constraints per unit volume. In this work, we demonstrate a new paradigm for controlling toughness...

DNA-Grafted 3D Superlattice Self-Assembly

The exploitation of new methods to control material structure has historically been dominating the material science. The bottom-up self-assembly strategy by taking atom/molecule/ensembles in nanoscale as building blocks and crystallization as a driving force bring hope for material fabrication. DNA-grafted nanoparticle has emerged as a “programmable atom equivalent” and was employed for the assembly of hierarchically ordered three-dimensional superlattice with novel properties and studying the unknown assembly mechanism due to its programmability and versatility in the binding capabilities. In this review, we highlight the assembly strategies and rules of DNA-grafted three-dimensional superlattice, dynamic assembly by different driving factors, and discuss their future applications.

Viscosity of polyelectrolyte-grafted nanoparticle solutions

The effect of charges and hydrogen bonding on viscosity in solutions containing polyelectrolyte-grafted nanoparticles (PENP) has been investigated using molecular dynamics (MD) simulations.