Resource-saving processing of technological solutions and wastewater by electrochemical method (methods overview)

The paper summarizes the data on the wastewater formation from a number of plants of chemical, engineering, energy and leather industries and its processing in electrolyzers of various designs to obtain the substances that can be used in various production processes. In the ethylenediamine production, wastewater occurs at the stages of amines rectification and of ethylenediamine dihydrochloride neutralization. Recycling of effluents generated during the amine rectification in a two-chamber electrolysis cell allows the ethylenediamine and ammonia to be returned to the production process. The processing of ethylenediamine dihydrochloride solution in the membrane electrolyzers saves alkali for the neutralization process. Electrochemical processing of distilled liquid in soda production makes possible to obtain calcium hydroxide, sodium hydroxide and hydrochloric acid or chlorine, which can be used in various industrial processes. Wastewater generated during the demineralized water production contains a significant amounts of sodium sulfates and chlorides. The processing of these effluents in a membrane electrolyzer yields sulfuric acid and alkali, which are suitable for the regeneration of ion-exchange filters. After processing in an electrodialysis apparatus the wastewater generated during the chromium and nickel coatings, is concentrated to values that allow them to be used to prepare an electrolyte adjustment. The leather industry effluents contains an amount of trivalent chromium and sulphides. Electrochemical processing of these effluents leads to almost complete extraction of chromium and sulfides.

Obtaining Caustic Soda and Burkeite by Caustification of Mixture of Corbonate and Sodium Sulphate

The optimal technological parameters for the production of caustic soda from sodium carbonate and sulfate and calcium hydroxide have been established. The influence of the concentration of lime milk on the rate of filtration by sediment and filtrate has been studied. Purpose of the Work: The purpose of this work is to determine the physicochemical basis for the production of sodium hydroxide and burkeite by causticization of sodium carbonate and sulfate. Scientific Novelty: In comparison with the known works, a theoretical profoanalytical analysis of the one-cation of four-component system and its constituents was carried out for the first time, and also determined the optimal technological parameters of causticization of solutions for local carbonates and sodium sulfates. Features of the Work: - the influence of the main technological parameters on the processes of causticization, filtration, evaporation; - research of intermediate and finished products by modern physicochemical methods; - study of the rheological properties of the solution depending on the temperature and concentration of the resulting solutions.

Assessment of Validity of Ground Water for Drinking Purposes in the Almarqab Region in Libya

"In this study, Analysis of 12 samples of ground water were carried out belong four locations within the area of Almarqab in Libya and physical, chemical and biological analyzes were performed for samples which are pH, electrical conductivity, total dissolved solids, total hardness, taste and Odor, sodium, sulfates, nitrates, chloride, magnesium, calcium, and the bacteriological examination represented by the total number of coliform. The physico chemical analyzes for Zliten and Alkhoms locations have shown that the parameters of total dissolved solids, total hardness, chlorine, sodium, nitrate (TDS, TH, Cl, Na, No3) respectively, taste and smell had exceeded the limits of the specification, Whereas the samples of Meslatah and Tarhonah locations were within the specifications, While the bacteriological analysis showed that all study samples have been contaminated by bacteria colon. Study also demonstrated that there is an overlap for the sea water in Zliten and Alkhoms samples, As well as The study revealed that the source of contamination for Zliten and Alkhoms samples were sewage, agricultural activities and seawater, While the contamination source in Mesalatah and Tarhonah samples was sewage. This confirms the inevitability of the transformation immediately to the treatment to make the water in Zliten and Alkhoms suitable for drinking, And the necessity of transformation to water treatment of Meslatah, Tarhonah in the near future"

Icy Moon Ice-Salt Measurements for Dielectric and Thermal Properties

<p>The REASON ground penetrating radar (GPR) on Europa Clipper and the RIME GPR on JUICE will produce radargrams for Europa to determine the nature and depth of the ice overlying a putative ocean. The REASON radar is dual frequency, 9 MHz and 60 MHz, and the RIME frequency is 9 MHz. The surface temperature of Europa is between 50 and 100 Kelvin. At 9 MHz, the REASON GPR could map relative permittivity to about 30 km with a resolution of 150 m. These two GPRs may be able to spot pockets of water within the ice shell that could serve as a passageway for chemicals between the surface and the ocean below. The upper ice crust is expected to contain magnesium and sodium sulfates, and perhaps calcium sulfate [J. Moore, 1999].</p><p>To fill this gap in knowledge about the properties of the ice crust on Europa, we will make laboratory measurements of the relative permittivity (complex dielectric coefficient using impedance spectroscopy) and thermal properties (thermal conductivity and specific heat) of ice-salt mixtures at 9 and 60 MHz, over the temperature range 50 to 100 Kelvin, for the ice-salt mixtures given in Table X. This Table was provided by Kevin Collins (UCF). We do not plan to include any dust content in these ice-salt mixtures. These laboratory data may assist in the interpretation of future radargrams from RESSON and RIME</p><p> </p><p>   TABLE 1, Europan ice-salt specimens for electrical and thermal property measurements.</p><div><strong>Experiment Number</strong><strong>Salt Species</strong><strong>Salt Concentration (wt. %)</strong><strong>Physical Texture</strong>1Sulfuric acid hydrate5Dispersed in particulate ice2Magnesium sulfate5Dispersed in particulate ice3Magnesium chloride5Dispersed in particulate ice4Sodium chloride5Dispersed in particulate ice5Magnesium sulfate1Dispersed in particulate ice6Magnesium sulfate10Dispersed in particulate ice7Magnesium sulfate25Dispersed in particulate ice8Magnesium sulfate + sulfuric acid hydrate5 (each)Dispersed in particulate ice9Magnesium sulfate5Solid block10Magnesium sulfate5Layered structure</div><p> </p><p>We are planning also to make similar measurements of the electrical and thermal properties of ice on Titania (moon of Uramus), over temperature range of 60 to 90 Kelvin, and at 9 MHz. The surface of Titania is mainly water ice, with some frozen carbon dioxide and possibly salts. We will devise a table of salt-ice mixtures that is appropriate for Titania, based on available information on surface content.</p>

Resistance of Recycled Aggregate Concrete (RAC) Subjected to Drying-Wetting Cycles to Attack of Magnesium and Sodium Sulfates

Recycled aggregates were widely used in the concrete industry as a replacement of natural aggregates in the last two decades. In this study, the resistance of concrete mixtures having various levels of recycled aggregate as a replacement of natural coarse aggregate to the attack of magnesium and sodium sulfates was investigated. Five mixtures made with 0%, 25%, 50%, 75%, and 100% recycled aggregate were partially immersed in magnesium and sodium sulfate solutions having concentrations of 2.5%, 4.5%, and 6.5% and subjected to drying-wetting cycles for a total of 10 weeks. Mass losses of concrete specimens owing to the attack of sulfate solutions and the effect of drying-wetting cycles were recorded weekly. Results show that the incorporation of recycled aggregate decreased the compressive strength of concrete at ages of 7 and 28 days. The decline in the compressive strength was more significant when the replacement percentage exceeds 50%. Mass losses of concrete specimens were found to be increased as the level of recycled aggregate increased. Mass losses of concrete specimens having 100% recycled aggregate were approximately as twice as those of concrete specimens having 0% recycled aggregate owing to 10 weeks of partial immersion in magnesium sulfate solutions of concentrations of 2.5%, 4.5%, and 6.5%. The attack of sodium sulfates was less aggressive than that of the magnesium sulfates. Results also show that the reduction in the compressive strength is directly proportional to the mass loss following a linear equation of R-squared value of 0.937.

Short-Term Performance of Sustainable Silica Fume Mortars Exposed to Sulfate Attack

Nowadays, the reuse of wastes is essential in order to reach a more sustainable environment. The cement production results in CO2 emissions which significantly contribute to anthropogenic greenhouse gas emissions. One way to reduce them is by partially replacing clinker by additions, such as silica fumes or other wastes. On the other hand, the pore structure of cementitious materials has a direct influence on their service properties. One of the most popular techniques for characterizing the microstructure of those materials is mercury intrusion porosimetry. In this work, this technique has been used for studying the evolution of the pore network of mortars with different percentages of silica fume (until 10%), which were exposed to aggressive sodium and magnesium sulfate solutions up to 90 days. Between the results of this technique, intrusion-extrusion curves and logarithms of differential intrusion volume versus pore size curves were studied. This characterization of the pore network of mortars has been complemented with the study of their compressive strength and their steady-state ionic diffusion coefficient obtained from samples’ resistivity. Generally, silica fume mortars showed different performance depending on the aggressive condition, although the greatest deleterious effects were observed in the medium with presence of both magnesium and sodium sulfates.

Effect of aggregates with high gypsum content on the performance of concrete

Sulfates in fine aggregate are a major problem when it exists in excessive amount especially in the Middle East and Iraq. Most of sulfate salts in fine aggregate are composed of calcium, magnesium, potassium and sodium sulfates. Calcium sulfates is the most common salt present in fine aggregate. It is usually finding as gypsum. It is difficult to obtain the specific sulfates content in fine aggregate within standard specifications. This research was conducted to investigate the effect of adding different contents of gypsum to fine aggregate as a replacement by weight on some properties of two types of concrete {self-compacted concrete (SCC) and high strength concrete (HSC)}. In these work three bases mixes of each type of concrete are used: mixes with different contents of metakaolin, mixes with different contents of gypsum and mixes incorporating different contents of metakaolin and gypsum. This study is devoted to determine the allowable content of sulfates in fine aggregate. Three levels of gypsum were tested (0.5, 1, 1.5) % by weight of fine aggregate and three levels of metakaolin were tested (5, 10, 15) % by the weight of cement. The experimental program is devoted to produce concrete with different levels of metakaolin and gypsum and determine its mechanical properties such as compressive strength and splitting tensile strength. The results arrived from this work show that the optimum gypsum content was 1.5% by weight of fine aggregates for mixes of SCC which gives increases in compressive strength and tensile strength, and 1% gypsum for mixes of HSC, results showed also that the metakaolin improved the properties of the two types of concrete and increased the loss which caused by sulfates. The best mix ever in SCC is 1% gypsum with 5% metakaolin, and 1% gypsum with 10% metakaolin for HSC.