THEORETICAL SUBSTANTIATION OF THE PHYSICAL MECHANISM OF ULTRASONIC CAVITATION DESTRUCTION OF MACROMOLECULES

Многообещающее направление исследований, которое потенциально может служить базой для создания эффективной технологии управления свойствами полимеров – воздействие механическими колебательными возмущениями на высокомолекулярную среду. В реальных неотверждённых полимерах механические колебательные возмущения, как правило, представляют собой кавитационно-акустическое воздействие, т.е. линейные синусоидальные колебания, создаваемые в среде, инициируют вторичное явление – кавитационные пузырьки. Пузырьки при кавитационно-акустическом воздействии периодически расширяются и схлопываются, формируя микроударные волны. Таким образом, механические колебательные возмущения имеют две составляющие – линейная синусоидальная и нелинейная ударно-волновая. Основное воздействие на структуру полимеров оказывает ударно-волновая составляющая. Для реализации данного процесса с максимальной энергетической эффективностью необходимо выявить оптимальные режимы воздействия. Для выявления оптимальных режимов воздействия в статье теоретически обоснован физический механизм разрушения макромолекул, основанный на их соударении со скоростью, превышающей критическую за счёт формирования экстремальных условий по температуре и давлению в окрестности схлопывающегося кавитационного пузырька. A promising area of research that can potentially serve as a basis for creating an effective technology for controlling the properties of polymers is the effect of mechanical oscillatory disturbances on a high–molecular medium. In real uncured polymers, mechanical oscillatory disturbances, as a rule, represent a cavitation-acoustic effect, i.e. linear sinusoidal vibrations created in the medium initiate a secondary phenomenon - cavitation bubbles. Bubbles under cavitation-acoustic action periodically expand and collapse, forming micro-shock waves. Thus, mechanical oscillatory disturbances have two components – linear sinusoidal and nonlinear shock wave. The main effect on the structure of polymers has a shock-wave component. To implement this process with maximum energy efficiency, it is necessary to identify optimal exposure modes. In order to identify optimal exposure modes, the article theoretically substantiates the physical mechanism of destruction of macromolecules based on their collision with a velocity exceeding the critical one due to the formation of extreme conditions for temperature and pressure in the vicinity of a collapsing cavitation bubble.

SIGNIFICANCE OF DX-CENTERS FOR ACOUSTIC INDUCED RECONSTRUCTION PROCESSES OF DEFECTS IN GaN/AlGaN

The experimental results of amplitude effects are compared (from an ultrasonic wave deformation amplitude – a tension τUS) for electron concentration and changes of the lattice parameter on the same sample GaN/Al0.2Ga0.8N/GaN/AlN. It has been experimentally established that at ultrasonic loading (frequency 5–10 MHz, amplitude – towards 2·104 W/m2) there is a nonlinear increase in the effective electron concentration and an increase in the lattice parameter; at the same time, the mobility of electrons decreases and μН(τUS) ~ |τUS|. The energy parameters of the acoustic activation charge carriers process are calculated from the approximation of experimental amplitude changes – Еа ≈ 50 meV and γn(300 K) ≈ 2,5·10-27 m3. The amplitude dependences (increase) of the relative lattice parameter change (ΔС/С) from the tension τUS have been investigated experimentally at different frequencies. The energy of DX-center transition UDX ≈ 108 meV and the activation volume of this transition γDX ≈ 6,6·10-27 m3 are calculated from the approximation of the experimental amplitude changes. The revealed correlation of the magnitude of acoustic induced effects in different experiments allows to build a quantitative energy model of the acoustic action process based on the properties of metastable DX centers. It is shown that the acoustic induced process occurs due to the dimensional displacement of the DX-center atom (a background impurity of silicon atoms) from the non-central position to the centrally symmetric one; herewith DX-center is ionized, one goes into the d0-state. It is believed that the changes are most likely to occur near penetrating dislocations in the barrier layer Al0.2Ga0.8N – acoustic modulated oscillations of the distance between the possible positions of the donor atom lead to a decrease in the barrier to the displacement of the defect.

Quantification of the Absorption and Scattering Effects of Diffusers in a Room with Absorbent Ceiling

In ordinary public rooms, such as classrooms and offices, an absorbent ceiling is the typical first acoustic action. This treatment provides a good acoustic baseline. However, an improvement of specific room acoustic parameters, operating for specific frequencies, can be needed. It has been seen that diffusing elements can be effective additional treatment. In order to choose the right design, placement, and quantity of diffusers, a model to estimate the effect on the acoustics is necessary. This study evaluated whether an SEA model could be used for that purpose, particularly for the cases where diffusers are used in combination with an absorbent ceiling. It was investigated whether the model could handle different quantities of diffusing elements, varied diffusion characteristics, and varied installation patterns. It was found that the model was sensitive to these changes, given that the output from the model in terms of acoustic properties will be reflected by the change of diffuser configuration design. It was also seen that the absorption and scattering of the diffusers could be quantified in a laboratory environment: a reverberation chamber. Through the SEA model, these quantities could be transformed to a full-scale room for estimation of the room acoustic parameters.

Influence of an electric field on flexopolarization induced by acoustic action on a liquid crystal

The work experimentally investigated the influence of an electric field on the direct flexoelectric effect that occurs under the influence of an acoustic field in liquid crystals. Thin layers of nematics 10-100 μm thick were studied. In this case, the liquid crystal sample was exposed to the piston method with an acoustic wave with a frequency of 1 kHz. The dependences of the first and second harmonics for different NLCs on the bias voltage value, shear amplitude, and crystal thickness were obtained. It was revealed that the flexosignal harmonics depend on the direction of the electric field; when a positive potential is applied to the movable plate, they take on smaller values than when negative. It was found that in low fields the magnitude of the flexosignal increases due to an increase in the amplitude of the director deviation, but at a critical value of the field it is suppressed, since the layer is stabilized by a constant electric field.

Model of Electro-Pulse Processing of Metals Melts

Questions of influence of nanosecond electromagnetic impulses on melts of metals are considered in the article. The analysis of action of impulses on electromagnetic hashing and thermal conditions of a melt showed their small influence. Mechanical (acoustic) action is chosen as the main one. Formulas and values for coefficients of transformation of electromagnetic field to the acoustic one for a number of metals are given. The transformation model in the form of the wave of current running on the radiator is offered. Comparison of action of electromagnetic impulses on melts showed that emergence of acoustic vibrations is the main thing. The theory of contactless transformation of electromagnetic waves in acoustic ones is considered. Comparison with experiments is given. The model of contact electro-pulse processing of metal melts in the form of transition of an electromagnetic wave to acoustic is offered. Acoustic waves change structure of a melt, condition of a crystallization of a melt and improve properties of the hardened metal.