polysulfide shuttle
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Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8362
Author(s):  
Balram Tripathi ◽  
Rajesh K. Katiyar ◽  
Gerardo Morell ◽  
Ambesh Dixit ◽  
Ram S. Katiyar

We demonstrated the efficient coupling of BiFeO3 (BFO) ferroelectric material within the carbon–sulfur (C-S) composite cathode, where polysulfides are trapped in BFO mesh, reducing the polysulfide shuttle impact, and thus resulting in an improved cyclic performance and an increase in capacity in Li-S batteries. Here, the built-in internal field due to BFO enhances polysulfide trapping. The observation of a difference in the diffusion behavior of polysulfides in BFO-coupled composites suggests more efficient trapping in BFO-modified C-S electrodes compared to pristine C-S composite cathodes. The X-ray diffraction results of BFO–C-S composite cathodes show an orthorhombic structure, while Raman spectra substantiate efficient coupling of BFO in C-S composites, in agreement with SEM images, showing the interconnected network of submicron-size sulfur composites. Two plateaus were observed at 1.75 V and 2.1 V in the charge/discharge characteristics of BFO–C-S composite cathodes. The observed capacity of ~1600 mAh g−1 in a 1.5–2.5 V operating window for BFO30-C10-S60 composite cathodes, and the high cyclic stability substantiate the superior performance of the designed cathode materials due to the efficient reduction in the polysulfide shuttle effect in these composite cathodes.


2021 ◽  
Vol 13 (16) ◽  
pp. 9473
Author(s):  
Salimeh Gohari ◽  
Vaclav Knap ◽  
Mohammad Reza Yaftian

Much attention has been paid to rechargeable lithium-sulfur batteries (Li–SBs) due to their high theoretical specific capacity, high theoretical energy density, and affordable cost. However, their rapid c fading capacity has been one of the key defects in their commercialization. It is believed that sulfuric cathode degradation is driven mainly by passivation of the cathode surface by Li2S at discharge, polysulfide shuttle (reducing the amount of active sulfur at the cathode, passivation of anode surface), and volume changes in the sulfuric cathode. These degradation mechanisms are significant during cycling, and the polysulfide shuttle is strongly present during storage at a high state-of-charge (SOC). Thus, storage at 50% SOC is used to evaluate the effect of the remaining degradation processes on the cell’s performance. In this work, unlike most of the other previous observations that were performed at small-scale cells (coin cells), 3.4 Ah pouch Li–SBs were tested using cycling and calendar aging protocols, and their performance indicators were analyzed. As expected, the fade capacity of the cycling aging cells was greater than that of the calendar aging cells. Additionally, the measurements for the calendar aging cells indicate that, contrary to the expectation of stopping the solubility of long-chain polysulfides and not attending the shuttle effect, these phenomena occur continuously under open-circuit conditions.


2021 ◽  
Vol 39 ◽  
pp. 96-107
Author(s):  
Safa Haghighat-Shishavan ◽  
Masoud Nazarian-Samani ◽  
Mahboobeh Nazarian-Samani ◽  
K.-B. Kim

2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Wenyue Li ◽  
Shiqi Li ◽  
Ayrton A. Bernussi ◽  
Zhaoyang Fan

Polysulfide shuttle effect, causing extremely low Coulombic efficiency and cycling stability, is one of the toughest challenges hindering the development of practical lithium sulfur batteries (LSBs). Introducing catalytic nanostructures to stabilize the otherwise soluble polysulfides and promote their conversion to solids has been proved to be an effective strategy in attacking this problem, but the heavy mass of catalysts often results in a low specific energy of the whole electrode. Herein, by designing and synthesizing a free-standing edge-oriented NiCo2S4/vertical graphene functionalized carbon nanofiber (NCS/EOG/CNF) thin film as a catalytic overlayer incorporated in the sulfur cathode, the polysulfide shuttle effect is largely alleviated, revealed by the enhanced electrochemical performance measurements and the catalytic function demonstration. Different from other reports, the NiCo2S4 nanosheets synthesized here have a 3-D edge-oriented structure with fully exposed edges and easily accessible in-plane surfaces, thus providing a high density of active sites even with a small mass. The EOG/CNF scaffold further renders the high conductivity in the catalytic structure. Combined, this novel structure, with high sulfur loading and high sulfur fraction, leads to high-performance sulfur cathodes toward a practical LSB technology.


2021 ◽  
Vol 4 (3) ◽  
pp. 2914-2921
Author(s):  
Zhenwei Li ◽  
Shaoshao Jiao ◽  
Di Yu ◽  
Qian Zhang ◽  
Kang Liu ◽  
...  

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