Reinvestigation of the rotation-tunneling spectrum of the CH2OH radical

Context. The hydroxymethyl radical (CH2OH) is one of two structural isomers, together with the methoxy radical (CH3O), that can be produced by abstraction of a hydrogen atom from methanol (CH3OH). In the interstellar medium (ISM), both CH2OH and CH3O are suspected to be intermediate species in many chemical reactions, including those of formation and destruction of methanol. The determination of the CH3O/CH2OH ratio in the ISM would bring important information concerning the formation processes of these species in the gas and solid phases. Interestingly, only CH3O has been detected in the ISM so far, despite the recent first laboratory measurement of the CH2OH rotation-tunneling spectrum. This lack of detection is possibly due to the non-observation in the laboratory of the most intense rotation-tunneling transitions at low temperatures. Aims. To support further searches for the hydroxymethyl radical in space, we present a thorough spectroscopic study of its rotation-tunneling spectrum, with a particular focus on transitions involving the lowest quantum numbers of the species. Methods. We recorded the rotation-tunneling spectrum of CH2OH at room temperature in the millimeter-wave domain using a frequency multiplication chain spectrometer. A fluorine-induced H-abstraction method from methanol was used to produce the radical. Results. About 180 transitions were observed, including those involving the lowest N and Ka quantum numbers, which are predicted to be intense under cold astrophysical conditions. These transitions were fitted together with available millimeter-wave lines from the literature. A systematic observation of all components of the rotational transitions yields a large improvement of the spectroscopic parameters allowing confident searches of the hydroxymethyl radical in cold to warm environments of the ISM.

Single particle tunneling spectrum of superconducting Nd1-xSrxNiO2 thin films

The pairing mechanism in cuprates remains as one of the most challenging issues in condensed matter physics. Recently, superconductivity was discovered in thin films of the infinite-layer nickelate Nd1-xSrxNiO2 (x = 0.12–0.25) which is believed to have the similar 3d9 orbital electrons as that in cuprates. Here we report single-particle tunneling measurements on the superconducting nickelate thin films. We find predominantly two types of tunneling spectra, one shows a V-shape feature which can be fitted well by a d-wave gap function with gap maximum of about 3.9 meV, another one exhibits a full gap of about 2.35 meV. Some spectra demonstrate mixed contributions of these two components. Combining with theoretical calculations, we attribute the d-wave gap to the pairing potential of the $${\mathrm{Ni - }}3d_{x^2 - y^2}$$ Ni- 3 d x 2 − y 2 orbital. Several possible reasons are given for explaining the full gap feature. Our results indicate both similarities and distinctions between the newly found Ni-based superconductors and cuprates.

Reproducing topological properties with quasi-Majorana states

Andreev bound states in hybrid superconductor-semiconductor devices can have near-zero energy in the topologically trivial regime as long as the confinement potential is sufficiently smooth. These quasi-Majorana states show zero-bias conductance features in a topologically trivial phase, mimicking spatially separated topological Majorana states. We show that in addition to the suppressed coupling between the quasi-Majorana states, also the coupling of these states across a tunnel barrier to the outside is exponentially different for increasing magnetic field. As a consequence, quasi-Majorana states mimic most of the proposed Majorana signatures: quantized zero-bias peaks, the 4\pi4π Josephson effect, and the tunneling spectrum in presence of a normal quantum dot. We identify a quantized conductance dip instead of a peak in the open regime as a distinguishing feature of true Majorana states in addition to having a bulk topological transition. Because braiding schemes rely only on the ability to couple to individual Majorana states, the exponential control over coupling strengths allows to also use quasi-Majorana states for braiding. Therefore, while the appearance of quasi-Majorana states complicates the observation of topological Majorana states, it opens an alternative route towards braiding of non-Abelian anyons and protected quantum computation.

Rotation-tunneling spectrum of the water dimer from instanton theory

A linearly-scaling path-integral method is developed to calculate rotation-tunneling spectra, and is applied to the water dimer.