Relative effect of solder flux chemistry on the humidity related failures in electronics

Purpose – This paper aims to investigate the effect of no-clean flux chemistry with various weak organic acids (WOAs) as activators on the corrosion reliability of electronics with emphasis on the hygroscopic nature of the residue. Design/methodology/approach – The hygroscopicity of flux residue was studied by quartz crystal microbalance, while corrosive effects were studied by leakage current and impedance measurements on standard test boards. The measurements were performed as a function of relative humidity (RH) in the range from 60 to ∼99 per cent at 25°C. The corrosiveness of solder flux systems was visualized by the ex situ analysis using a gel with tin ion indicator. Findings – The results showed that the solder flux residues are characterized by different threshold RH, above which a sudden increase in direct current leakage by 2–4 orders of magnitude and a significant reduction in surface resistance in the impedance measurements were observed. Practical implications – The findings are attributed to the deliquescence RH of the WOA(s) in the flux and chemistry of water-layer formation. The results show the importance of WOA type in relation to its solubility and deliquescence RH on the corrosion reliability of printed circuit boards under humid conditions. Originality/value – The classification of solder flux systems according to IPC J-STD-004 standard does not specify the WOAs in the flux; however, ranking of the flux systems based on the hygroscopic property of activators would be useful information when selecting no-clean flux systems for electronics with applications in humid conditions.

Control of Slag-Dragging Effects at the Metal–Slag Interface through Electromagnetic Brake in a Slab Mold

Turbulent flow when steel is delivered through a nozzle in a slab mold induces dragging forces at the metal–slag interface that entrain slag droplets into the metal bulk. These dragging effects are discontinuous and correspond to the velocity fluctuations of turbulence at that interface which themselves, are dependent on nozzle immersion, nozzle design, mold width and casting speed. Slag viscosity and density, metal viscosity and slag layer thickness are employed to estimate that critical velocity which is embodied in a critical capillary number for some established mold operating conditions. This approach permits the link between all operating variables including flux chemistry and nozzle design with the interface instability. A relationship between the capillary number and the magnetic field strength used to brake the liquid steel is established which is used to assure the interface stability for any operating condition and flux chemistry.

An Experimental Study of Lead-Free Wave Soldering Using SAC 305 and No-Clean Flux

The transition to lead-free assembly will have a significant effect on wave soldering operations. Since the wetting ability of lead-free solder is usually less than that of tin-lead solder, it can result in unacceptable hole fills and inconsistent top side wetting - especially in the case of thick Printed Circuit Boards (PCBs). Presently, there is very little data available on lead-free wave soldering with tin-silver-copper (SnAgCu or SAC) alloy and no-clean flux chemistry. Although some researchers and consortia recommend tin-copper (SnCu) for lead-free wave soldering, demonstrating the feasibility of using the SAC alloy for wave soldering operation can aid manufacturers to use the same alloy for both reflow and wave soldering operations. In this study, SAC 305 alloy and no-clean flux were evaluated in terms of percentage of hole fill and solderability on a 93 mil thick test vehicle with Immersion Silver (ImmAg) surface finish. The evaluation was performed on a nitrogen equipped wave soldering equipment. It has 4 preheating zones (3 convection bottom heaters and 1 infrared top heater) that provides good control to develop the required preheat profile. A partial factorial experiment was conducted to study the main effects of solder pot temperature, topside preheat temperature and conveyor speed on wave soldering performance. Wave soldering was performed after two reflow cycles. A 100% visual inspection was done for all the through hole components using a 10X microscope to determine top side wetting, percentage of hole fill, bridging, flux residue and solder balling. Thickness of the hole fill was also measured using digital X-Ray equipment. The data generated from this experiment was used to determine the 'optimum' lead-free process parameters for wave soldering using a SAC 305 alloy with a no-clean flux chemistry. The 'optimized' process parameters were then used to evaluate boards with Organic Solderability Protective (OSP) and Electroless Nickel Immersion Gold (ENIG) surface finishes. The designed experiments approach adopted to determine the optimum process settings and the research findings are explained in detail.