Degradation of Hexacyanoferrate (III) from Gold Mining Wastewaters via UV-A/LED Photocatalysis Using Modified TiO2 P25

The photocatalytic degradation of potassium hexacyanoferrate (III) was assessed in a bench-scale compound parabolic collectors (CPC) reactor assisted with a light-emitting diode (LED) UV-A source emitting at 365 nm, and using a modified TiO2 as a catalyst via the hydrothermal treatment of commercial Aeroxide P25. The experiments were performed under oxic and anoxic conditions in order to observe a possible reduction of the iron. The modified TiO2 showed a specific surface area 2.5 times greater than the original Aeroxide P25 and its isotherm and hysteresis indicated that the modified catalyst is mesoporous. The bandgap energy (Eg) of the modified TiO2 increased (3.34 eV) compared to the P25 TiO2 band gap (3.20 eV). A specific reaction rate constant of 0.1977 min−1 and an electrical oxidation efficiency of 7.77 kWh/m3 were obtained in the photocatalytic degradation. Although the TiO2 P25 yields a photocatalytic degradation 9.5% higher than that obtained one with the modified catalyst (hydrothermal), this catalyst showed better performance in terms of free cyanide release. This last aspect is a significant benefit since this can help to avoid the pollution of fresh water by reusing the treated wastewater for gold extraction. A photocatalytic degradation of the cyanocomplex of 93% was achieved when the process occurred under oxic conditions, which favored the removal. Summarizing, the hydrothermal method could be a promising treatment to obtain TiO2-based catalysts with larger specific areas.

Wastewater containing Cr(VI) treatment using solar tubular reactor

The hexavalent chromium, Cr(VI), which is generated in the electroplating process, is toxic to most organisms and potentially harmful to human health. The method generally used for remediation of wastewater containing Cr(VI) employs chemicals with high toxicity. This work proposes an alternative technology for the treatment of these wastewaters, based on photochemical reduction of Cr(VI) by alcohols under radiation, which is environmentally sustainable and economically viable. Initially, a batch reactor in laboratory scale was used to determine the best experimental conditions and its specific reaction rate was calculated. Based on these results, a tubular reactor (artificial radiation and sunlight) was designed and built in semi-pilot scale. Tests were carried out with real wastewater from an electroplating industry containing Cr(VI). Tests conducted under sunlight showed a higher total Cr(VI) reduction than the tests with artificial radiation. The remediation of Cr(VI) from wastewater was 86.7% after 6 h of reaction under sunlight, indicating the high efficiency of the developed process.

On the existence of and mechanism for microwave-specific reaction rate enhancement

Microwave-specific chemical rate enhancement originates from the selective heating and accumulation of energy by solvated dipolar molecules in solution.