Geomorphological context of Quaternary desert loess - from dust sink to dust source

<p>Quaternary loess covers desert margins and vast areas of the Negev, southern Israel. The Negev loess is among the best-studied desert loess, with research going back to the early 20<sup>th</sup> century. The contrast between carbonate rocks of the Negev and its silicate-rich coarse-silt loess allows determining the loess sources, learning the synoptic-scale paleoclimatology, and exploring processes of coarse silt formation. Here, we present an overview of new perspectives on the origins and climatic significance of the Negev loess, expand on how (a) coarse silts affected soils farther downwind, and (b) how the loess has now turned into an active dust source.</p><p>The sources of the Negev loess are the (a) distal Sahara and Arabia delivering fine silts and clays, transported over thousands of kilometers, and (b) proximal sand dunes in Sinai and Negev, advancing and concurrently supplying the coarse silts to the loess accretion through eolian abrasion of sand grains. It was found that the coarse silts which compose the majority of the loess, commenced during the late middle Pleistocene – early late Pleistocene, coeval with the appearance of the advancing Sinai/Negev sand dunes and the first coarse silt accretion in regional soils; The main loess formation episode is ~95-10 ka, when the dunes appeared in the Negev. Within the loess, the dust mass accumulations rates (MAR), and consequently, soil formation rates, spatiotemporally vary according to specific site location and distance relative to the proximal sources. With increasing distance beyond the loess zone, both dust MARs and grain size gradually decrease; thus, whereas Mediterranean mountains located in central Israel, tens of kilometers downwind the loess, exhibit thick soils on top of the carbonate bedrock, the even wetter regions in northern Israel, located hundreds kilometers away from the loess, exhibit only thin soils. Thus, in Mediterranean regions located at the desert fringe, coarse silt influx is one of the main factors in determining the environmental sustainability, rather than only the precipitation amount.</p><p>During the Holocene, dust MARs in the Negev were much lower than late Pleistocene ones, and loess was not formed. Recently, the Negev loess became a prime source of dust mainly due to anthropogenic interferences, contributing to the regional dust cycle, and thus, at present the loess zone is a dust source rather than a dust sink. Today, the Negev loess is a non-replenishable natural resource that is slowly eroding and disappearing from the landscape.</p>

Dust Particle Size and Statistical Parameters

Grain ‘size’ can be specified and measured in several different ways. All methods of grain size determination have blemishes, and the choice of the most appropriate method is governed by the nature of the sample and the use to which the data are placed. Four main methods are currently used for size analysis of sands: (a) sieving; (b) settling tube analysis; (c) electro-optical methods, including Coulter Counter analysis and laser granulometry; and (d) computerized image analysis. The classification of the particle size distribution of Kuwait dust was mapped according to the parameters proposed by Folk And Ward (1957) which were widely used for quantitative comparisons between natural grain size distribution and the lognormal distribution that shows better sorted sediments have lower values of σ1. Maps of the distribution of dust in Kuwait were obtained that included: fine sand (F.S.), Coarse sand (C.S), Medium Sand (M.S), Very Fine Sane (V.F.S), Very Coarse Silt (V.C.Silt), Coarse Silt (C.Silt), Medium Silt (M.Silt), Fine Silt (F.Silt), Very Fine Silt (V.F.Silt), in addition to that, the deposition percentage of Clay, Sand, mud (silt plus clay) and silt were provided.

SEDIMENT GRAIN-SIZE COMPOSITION IN LAKE ANASHKINO (SOUTH-WESTERN ONEGO AREA)

The lithostratigraphy and grain-size composition of sediments in Lake Anashkino (south-western Onego area) are described. The younger, upper sediment layers showed a prevalence of very fine sand. Further down the sediment, there dominate coarse and medium silt fractions, and down from the depth of 10.03–10.16 m — medium and fine silt. The oldest sediments (at 10.19–10.20 m) feature a prevalence of very coarse and coarse silt, and further below (10.30–10.31 m) there prevail very fine sand and very coarse silt fractions. The prevalent activity in the palaeo-hydrodynamic environments in which the ancient sediments (9.96–10.31 m) were deposited was turbidite flows. Younger sediments (9.32–9.92 m) were deposited in the environment of low-velocity flows. The sediment formation pattern in Lake Anashkino during the change from a nival to a humid climate suggests there happened five shifts in dynamic water regimes.

Major Characteristics of Surface Sediments Within the Shallow Water of the Cat Ba Island, North Vietnam

The Cat Ba is one of the largest Islands offshore North Vietnam, which is characterized by an abundance of coral reefs in the East and Southeast of the island. The surface sediments are considered the basic elements for the coral ecosystem development. In this study, the authors present some new results studying pH, Eh, mineral composition, and grain size as the basic information for environmental assessment of this area. The results show that the pH value of the surface sediment varies from 6.90 to 8.09, with an average of 7.24 while the Eh value of the sediment ranges from -121.10 to -48.20mV, an average of -68.39mV, demonstrating a reducing environment. The surface sediments have been classified into 8 size classes: the coarse silt > very coarse silt > medium sand, very fine sand > very coarse sand, fine sand > coarse sand, very fine gravel. Most of the sediments are poorly sorted - very poorly sorted, only a few sedimentary samples are well sorted, moderately sorted, and moderately well sorted. The average mineral composition of the surface sediments consists of: 25% quartz, 17% illite, 16% aragonite, 13% kaolinite, 10% calcite, 5% chlorite, 4% gothite, 3% halite, 2% feldspar and less montmorillonite, and dolomite. These results allowed the researcher to interpret that the sediments have been deposited in a relatively calm environment and the terrigenous sediment sources are dominant over the marine sources. Source marine sediment groups are characterized by coarse grains, high pH, and are rich in carbonate minerals, which have been produced by biological materials. In contrast, the terrigenous sediment group is dominated by fine-grained sediments, rich clay minerals, quartz, and gothite. These fine-grained sediments are commonly distributed in the area and are favorable places for pollutant accumulation.

The cryostratigraphy of the Yedoma cliff of Sobo-Sise Island (Lena delta) reveals permafrost dynamics in the central Laptev Sea coastal region during the last 52 kyr

The present study examines the formation history and cryolithological properties of the late-Pleistocene Yedoma Ice Complex (IC) and its Holocene cover in the eastern Lena delta on Sobo-Sise Island. The sedimentary sequence was continuously sampled at 0.5 m resolution at a vertical Yedoma cliff starting from 24.2 m above river level (a.r.l.). The sequence differentiates into three cryostratigraphic units: Unit A, dated from ca. 52 to 28 cal kyr BP; Unit B, dated from ca. 28 to 15 cal kyr BP; Unit C, dated from ca. 7 to 0 cal kyr BP. Three chronologic gaps in the record are striking. The hiatus during the interstadial marine isotope stage (MIS) 3 (36–29 cal kyr BP) as well as during stadial MIS 2 (20–17 cal kyr BP) might be related to fluvial erosion and/or changed discharge patterns of the Lena river caused by repeated outburst floods from the glacial Lake Vitim in southern Siberia along the Lena river valley towards the Arctic Ocean. The hiatus during the MIS 2–1 transition (15–7 cal kyr BP) is a commonly observed feature in permafrost chronologies due to intense thermokarst activity of the deglacial period. The chronologic gaps of the Sobo-Sise Yedoma record are similarly found at two neighbouring Yedoma IC sites on Bykovsky Peninsula and Kurungnakh-Sise Island and are most likely of regional importance. The three cryostratigraphic units of the Sobo-Sise Yedoma exhibit distinct signatures in properties of their clastic, organic, and ice components. Higher permafrost aggradation rates of 1 m kyr−1 with higher organic-matter (OM) stocks (29 ± 15 kg C m−3, 2.2 ± 1.0 kg N m−3; Unit A) and mainly coarse silt are found for the interstadial MIS 3 if compared to the stadial MIS 2 with 0.7 m kyr−1 permafrost aggradation, lower OM stocks (14 ± 8 kg C m−3, 1.4 ± 0.4 kg N m−3; Unit B), and pronounced peaks in the coarse-silt and medium-sand fractions. Geochemical signatures of intra-sedimental ice reflect the differences in summer evaporation and moisture regime by higher ion content and less depleted ratios of stable δ18O and stable δD isotopes but lower deuterium excess (d) values during interstadial MIS 3 if compared to stadial MIS 2. The δ18O and δD composition of MIS 3 and MIS 2 ice wedges shows characteristic well-depleted values and low d values, while MIS 1 ice wedges have elevated mean d values between 11 ‰ and 15 ‰ and surprisingly low δ18O and δD values. Hence, the isotopic difference between late-Pleistocene and Holocene ice wedges is more pronounced in d than in δ values. The present study of the permafrost exposed at the Sobo-Sise Yedoma cliff provides a comprehensive cryostratigraphic inventory, insights into permafrost aggradation, and degradation over the last approximately 52 kyr as well as their climatic and morphodynamic controls on the regional scale of the central Laptev Sea coastal region in NE Siberia.

Quaternary influx of proximal coarse-grained dust altered circum-Mediterranean soil productivity and impacted early human culture

The carbonate mountainous landscape around most of the Mediterranean is karstic, is almost barren, and has thin soils. Erosion of preexisting thicker soils is a common hypothesis used to explain this bare terrain. An alternative hypothesis is that in the Mediterranean region, thin soils are attributed to long-distance transport of very fine, silty clay dust, resulting in low mass accumulation rates. Even if accreted over millennia, such dust cannot produce thick, highly productive soils. A pronounced anomaly in the Mediterranean is the thick, more productive soil of the semiarid southern Levant (SL). These soils contain order-of-magnitude coarser grains than the characteristic thin soils in the Mediterranean and a high proportion (>70%) of coarse silt quartz sourced from the nearby Sinai-Negev erg, the primary contributor of the Negev loess. This proximal intense dust supply produced greatly thicker soils. However, influx of coarse silt quartz loess is a geologically recent phenomenon in the SL. Pre-loess (i.e., older than 200 ka, pre-coarse-silt influx) SL soils are much finer and were generated by long-distance dust from the Sahara and Arabia like most other Mediterranean soils. Thus, we hypothesize that the geologically recent Negev Desert loess interval caused a drastic change in mountainous soil properties within the SL, enriching the Levant’s ecology and affecting early human development. The high amounts of coarse silt deposited on the landscape have contributed to the unique sustainable agriculture in the SL, which assisted in transforming the Levant into “the land of milk and honey” and a cradle of civilizations.

The cryostratigraphy of the Yedoma cliff of Sobo-Sise Island (Lena Delta) reveals permafrost dynamics in the Central Laptev Sea coastal region during the last about 52 ka

The present study examines the formation history and cryolithological properties of late Pleistocene Yedoma Ice Complex (IC) and its Holocene cover in the eastern Lena Delta on Sobo-Sise Island. The sedimentary sequence was continuously sampled in 0.5 m resolution at a vertical Yedoma cliff starting from 24.2 m above rivel level (arl). The sequence differentiates into three cryostratigraphic units; unit A: dated from ca. 52 to 28 cal ka BP; unit B: dated from ca. 28 to 15 cal ka BP; unit C: dated from ca. 7 to 0 cal ka BP. Three chronologic gaps in the record are striking. The hiatus during the interstadial MIS 3 (36–29 cal ka BP) as well as during stadial MIS 2 (20–17 cal ka BP) might be related to fluvial erosion and/or changed discharge patterns of the Lena River caused by repeated outburst floods from the glacial Lake Vitim in Southern Siberia along the Lena River valley towards the Arctic Ocean. The hiatus during the MIS 2-1 transition (15–7 cal ka BP) is a commonly observed feature in permafrost chronologies due to intense thermokarst activity of the deglacial period. The chronologic gaps of the Sobo-Sise Yedoma record are similarly found at two neighbouring Yedoma IC sites on Bykovsky Peninsula and Kurungnakh-Sise Island, and most likely of regional importance. The three cryostratigraphic units of the Sobo-Sise Yedoma exhibit distinct signatures in properties of their clastic, organic and ice components. Higher permafrost aggradation rates of 1 m ka-1 with higher organic matter (OM) stocks (29±15 kg C m-3, 2.2±1.0 kg N m-3) and mainly coarse silt are found for the interstadial MIS 3 unit A if compared to the stadial MIS 2 unit B with 0.7 m ka-1 permafrost aggradation, lower OM stocks (14±8 kg C m-3, 1.4±0.4 kg N m-3 in unit B) and pronounced peaks in the coarse silt and medium sand fractions. Geochemical signatures of intrasedimental ice reflect the differences in summer evaporation and moisture regime by higher ion contents and less depleted stable δ18O and δD isotope ratios but lower deuterium excess (d) values during interstadial MIS 3 if compared to stadial MIS 2. The δ18O and δD composition of MIS 3 and MIS 2 ice wedges shows characteristic well-depleted values and low d values, while MIS 1 ice wedges have elevated mean d values between 11‰ and 15‰ and surprisingly low δ18O and δD values. Hence, the isotopic difference between late Pleistocene and Holocene ice wedges is more pronounced in d than in δ values. The present study of the permafrost exposed at the Sobo-Sise Yedoma cliff provides a comprehensive cryostratigraphic inventory, insights into permafrost aggradation and degradation over the last about 52 thousand years, and their climatic and morphodynamic controls on the regional scale of the Central Laptev Sea coastal region in NE Siberia.

On the formation of desert loess

Sequences of quartz-rich coarse (20−63 μm) silt occur in many low- and midlatitude unglaciated arid and semiarid areas and have been termed “desert loess.” The processes by which these deposits are generated have been debated for decades. All hypotheses to explain their origin seek to provide mechanisms for the generation of silt-sized material without glacial grinding, which is the main process involved in the production of coarse silt at high latitudes. Possible mechanisms for the formation of coarse silt in arid regions include derivation from preexisting siltstones, mechanical weathering of silicate rocks, and abrasion of sand grains in active dune environments during intense transport events. Examination of the characteristics of desert loess and field and laboratory experiments to assess the role of dune areas as a source of coarse silt by abrasion and/or resuspension of residual fines suggests that many loess sequences are dominated by locally derived coarse silt. Improvements in the characterization of desert loess particle size, mineralogy, and geochemistry are needed, however, to identify sources and sinks of coarse silt, especially when combined with climatic back-trajectory analysis. Properly scaled experiments and modeling of particle collisions will also help to better quantify the effectiveness of abrasion in the generation of coarse silt in support of field observations.

Particle size partitioning of metals in humus horizons of two small erosional landforms in the middle Protva basin – a comparative study

Partitioning of metals in soil particles of various size classes has been receiving greater significance due to the necessity to predict the behaviour and pathways of the potentially toxic elements in the environment. In this study the analysis of metals’ distribution in various particle size fractions was performed to characterize and compare geochemical features of the topsoil horizons of two small erosional landforms located in uncontaminated area of the central part of European Russia (the Middle Protva basin, mixed forest zone). The landforms represent two typical lithological types of gullies in the study area. Soil samples were fractionated and the concentrations of Fe, Mn, Ti, Zr, Ni, Co, Cr, Zn, Cu, Pb were determined in five particle size fractions: 1–0.25, 0.25-0.05, 0.05−0.01, 0.01–0.001 and <0.001 mm. The metals’ concentrations and their distribution in various particle sizes were found to be related to gully litho-type. The contribution of the clay to the total amount of metals was the greatest for Mn, Zn, Ni and Co in both systems. The highest mass loading for Ti, Zr and Cr came from the coarse silt, while for Cu and Pb it was made by different particle size fractions: the medium and fine silt or the coarse silt. The highest contribution of Fe also came from different fractions, either from the coarse sand or the clay depending on the system.

Granulometric composition and magnetic susceptibility of the Late Pleistocene loess-soil sequence of the stratotype section (Alexandrovsky quarry, Kursk, Russia)

&lt;p&gt;Granulometric composition and magnetic susceptibility are important indicators of the genesis of paleosols, loesses and other newest sediments. Along with other characteristics, they make it possible to reconstruct evolution, surrounding landscapes and climatic changes in the past. The stratotypic section &quot;Alexandrovsky quarry&quot; (natural monument in Kursk, 51&amp;#176;35&amp;#8242;31&amp;#8243;N, 36&amp;#176;3&amp;#8242;21&amp;#8243;E) reveals the most complete structure of the Late Pleistocene for the periglacial zone of the East European Plain. Soil-sediment stratum with a thickness of more than 10 m represents the filling of a small buried valley. The formation of the stratum took place practically without interruptions during the last 130 thousand years. It includes two interglacial paleosols: Holocene (Marine Isotope Stage 1) and Ryshkovo (MIS 5&amp;#1077;); four interstadial paleosols: Kukuevka (MIS 5&amp;#1089;), Streletsa (MIS 5&amp;#1072;), Alexandrovka (MIS 3.1), Bryansk (MIS 3.2), and also loess, pedo-sediment and other deposits that have periodically experienced exposuring to cryogenesis [Sycheva, 2012]. The particle size distribution and the magnitude of the magnetic susceptibility reflect the complex history of the stratum formation and reveal detailed climate changes in the Late Pleistocene. The particle size distribution was determined with fractionation method by Kaczynski and by instrumental laser-diffractometry method on a &quot;Malvern Mastersizer 3000&quot; particle size analyzer. The magnetic susceptibility was determined by a SatisGeo KM-7m field capameter with triplicate measurements for every 6 cm.&lt;br&gt;A change in the granulometric composition from Ryshkovo (MIS 5e) medium loamy deposits to heavy loamy soils and loess belonging to MIS 3.1 was established. The largest value of the clay fraction (&lt;0.001 mm) is characteristic of the MIS 3 paleosols. Significant values of this fraction are also characteristic of the humus horizons of paleosols and Bt horizon Ryshkovo paleosol (MIS 5e). The lowest clay content is observed in loess, especially in their upper parts and in the eluvial horizon of the Rushkovo paleosol (MIS 5&amp;#1077;). The data gained by instrumental method of particle size determination is different from such as data gained by the Kaczynski method for the upper heavy loam stratum (MIS 3-1). The predominant fraction is fine dust, in contrast to the lower sediments MIS 5-4, where the coarse silt fraction prevails. Whereas according to data gained by Kaczynski method, the coarse silt fraction prevails in the entire studied thickness of the loess-soil sequence.&lt;br&gt;Magnetic susceptibility (MS) depends on the content of superparamagnetic mineral in each of the samples and represents levels of pedogenesis in loess deposits. The highest MS values are characteristic of the humus horizon of the interglacial Ryshkovo paleosol (MIS 5e). Followed by Ah horizon of the Streletsa paleosol (MIS 5a) and underlying loess. Smaller values are characteristic of the Kukuevka (MIS 5c) paleosol. But they are more eroded and represented by transitional AB horizons. Loess is characterized by the lowest values of magnetic susceptibility.&lt;br&gt;The study was funded by RFBR according to the research project &amp;#8470; 19-29-05024.&lt;/p&gt;