Comment on the Determination of the Polar Anchoring Energy by Capacitance Measurements in Nematic Liquid Crystals

Capacitance measurements have been extensively used to measure the anchoring extrapolation length L at a nematic–substrate interface. These measurements are extremely delicate because the value found for L often critically depends on the sample thickness and the voltage range chosen to perform the measurements. Several reasons have been proposed to explain this observation, such as the presence of inhomogeneities in the director distribution on the bounding plates or the variation with the electric field of the dielectric constants. In this paper, I propose a new method to measure L that takes into account this second effect. This method is more general than the one proposed in Murauski et al. Phys. Rev. E 71, 061707 (2005) because it does not assume that the anchoring angle is small and that the anchoring energy is of the Rapini–Papoular form. This method is applied to a cell of 8CB that is treated for planar unidirectional anchoring by photoalignment with the azobenzene dye Brilliant Yellow. The role of flexoelectric effects and the shape of the anchoring potential are discussed.

Comment on the Determination of the Polar Anchoring Energy by Capacitance Measurements in Nematic Liquid Crystals

Capacitance measurements have been extensively used to measure the anchoring extrapolation length L at a nematic-substrate interface. These measurements are extremely delicate because the value found for L often critically depends on the sample thickness and the voltage range chosen to perform the measurements. Several reasons have been proposed to explain this observation, such as the presence of inhomogeneities in the director distribution on the bounding plates or the variation with the electric field of the dielectric constants. In this paper I propose a new method to measure Lp that takes into account this second effect. This method is more general than that proposed in Murauski et al. Phys. Rev. E 71, 061707 (2005) because it does not assume that the anchoring angle is small and that the anchoring energy is of the Rapini-Papoular form. This method is applied to a cell of 8CB treated for planar unidirectional anchoring by photoalignment with the azobenzene dye Brilliant Yellow. The role of flexoelectric effects and the shape of the anchoring potential are discussed.

Greener approach to substitute chemical reduction clearing process for fabric dyed with Foron Blue E-BL 150, Foron Rubine RD-GFL and Foron Brilliant Yellow S-6GL using indigenous resources

Fabric dyed with disperse dyes followed a reduction clearing process (RCP)/chemical clearing process (CCP) to remove the unfixed dye from the fabric. In the clearing process, unfixed dyes and chemicals are discharged into streams. To combat this issue, an environment friendly approaches is explored that is a biological clearing using indigenous fungal strains of white-rot fungi (Pleurotus ostreatus and Ganoderma lucidum). In this context, fabrics dyed with three disperse dyes (Foron Blue E-BL 150, Foron Rubine RD-GFL and Foron Brilliant Yellow S-6GL) were considered. The fabric cleared with biological clearing process improved the quality of fabric versus chemically cleared fabric and among the tested strains, G. lucidum showed higher efficiency for color strength improvement. However, no significant difference in tensile and tear strength of all fabric samples was observed. The quality of effluents in clearing reduction process for three dyes was assessed and it was observed that water quality parameters including chemical oxygen demand (COD), total organic carbon (TOC), biological oxygen demand (BOD), total suspended solids (TSS), pH, dissolved oxygen (DO) and total dissolved solids (TDS) improved significantly and results revealed that the biological clearing approach can substitute chemical reduction clearing process for fabric dyed with dyes, which is greener and eco-friendly versus conventional processes to avoid unfixed dyes discharge in to water bodies.