Strain-controlled thermoelectric properties of phosphorene-carbon monosulfide hetero-bilayers

The application of strain to 2D materials allows manipulating the electronic, magnetic, and thermoelectric properties. These physical properties are sensitive to slight variations induced by tensile and compressive strain and the uniaxial strain direction. Herein, we take advantage of the reversible semiconductor-metal transition observed in certain monolayers to propose a hetero-bilayer device. We propose to pill up phosphorene (layered black phosphorus) and carbon monosulfide monolayers. In the first, such transition appears for positive strain, while the second appears for negative strain. Our first-principle calculations show that depending on the direction of the applied uniaxial strain; it is possible to achieve reversible control in the layer that behaves as an electronic conductor while the other layer remains as a thermal conductor. The described strain-controlled selectivity could be used in the design of novel devices.

The use of Ca + Pd + Zr as modifiers in the determination of sulfur by HR-CS GF MAS with solid sampling

This paper proposes a universal combination of chemical modifiers for sulfur determination through carbon monosulfide (CS) monitoring by high-resolution-continuum source graphite furnace molecular absorption spectrometry and solid sampling analysis.

From interstellar carbon monosulfide to methyl mercaptan: paths of least resistance

The 29 reactions linking carbon monosulfide (CS) to methyl mercaptan (CH3SH) via ten intermediate radicals and molecules have been characterized with relevance to surface chemistry in cold interstellar ices. More intermediate species than previously considered are found likely to be present in these ices, such as trans- and cis-HCSH. Both activation and reaction energies have been calculated, along with low-temperature (T > 45 K) rate constants for the radical-neutral reactions. For barrierless radical-radical reactions on the other hand, branching ratios have been determined. The combination of these two sets of information provides, for the first time, quantitative information on the full H + CS reaction network. Early on in this network, that is, early on in the lifetime of an interstellar cloud, HCS is the main radical, while later on this becomes first CH2SH and finally CH3S.

A systematic look at the carbon monosulfide molecule and chemical modifiers for the determination of sulfur by HR-CS GF MAS

This work describes an adequate method for the stabilization of three forms of sulfur (ionic, saturated, and unsaturated), with different chemical modifiers (Zr, Pd and Ca) during sulfur measurement as carbon monosulfide (CS) by high-resolution continuum source graphite furnace molecular absorption spectrometry.