Electron spectra for twisted electron collisions

Ionization collisions have important consequences in many physical phenomena, and the mechanism that leads to ionization is not universal. Double differential cross sections (DDCSs) are often used to identify ionization mechanisms because they exhibit features that distinguish close collisions from grazing collisions. In the angular DDCS, a sharp peak indicates ionization through a close binary collision, while a broad angular distribution points to a grazing collision. In the DDCS energy spectrum, electrons ejected through a binary encounter collision result in peak at an energy predicted from momentum conservation. These insights into ionization processes are well-established for plane wave projectiles. However, the recent development of sculpted particle wave packets reopens the question of how ionization occurs for these new particle wave forms. We present theoretical DDCSs for (e,2e) ionization of atomic hydrogen for electron vortex projectiles. Our results predict that the ionization mechanism for vortex projectiles is similar to that of non-vortex projectiles, but that the projectile’s momentum uncertainty causes noticeable changes to the shape and magnitude of the vortex DDCSs. Specifically, there is a broadening and splitting of the angular DDCS peak for vortex projectiles, and an increase in the cross section for high energy ejected electrons.

First observation of radiolytic bubble formation in unstirred nano-powder sludges and a consistent model thereof

Experiments involving the irradiation of water contained within magnesium hydroxide and alumina nanoparticle sludges were conducted and culminated in observations of an increased yield of molecular hydrogen when compared to the yield from the irradiation of bulk water. We show that there is a relationship linking this increased yield to the direct nanoscale ionization mechanism in the nanoparticles, indicating that electron emission from the nanoparticles drives new radiative pathways in the water. Because the chemical changes in these sludges are introduced by irradiation only, we have a genuinely unstirred system. This feature allows us to determine the diffusivity of the dissolved gas. Using the measured gas production rate, we have developed a method for modelling when hydrogen bubble formation will occur within the nanoparticle sludges. This model facilitates the determination of a consistent radiolytic consumption rate coinciding with the observations of bubble formation. Thus, we demonstrate a nanoscale radiation effect directly influencing the formation of molecular hydrogen.

Atmospheric Photoionization Detector with Improved Photon Efficiency: A Proof of Concept for Application of a Nanolayer Thin-Film Electrode

Atmospheric photoionization is a widely applied soft ionization mechanism in gas sensing devices for the detection of volatile organic compounds in ambient air. Photoionization is typically induced by low-pressure Vacuum Ultraviolet (VUV) lamps with MgF2 or LiF lamp surface windows depending on the gas fill and the required wavelength transmission window. These lamps are known to exhibit gradually reduced VUV transmission due to hydrocarbon contamination. LiF surface windows are known to be especially problematic due to their hygroscopic nature, reducing VUV lamp lifetime to a mere 100 h, approximately. Here, we present a new design for the electrode of a photoionization detector based on thin-film technology. By replacing the commonplace metal grid electrode’s VUV lamp surface window with a chromium/gold thin film we obtain a doubling of photon efficiency for photoionization. Replacing the hygroscopic LiF lamp window surface with a metallic layer additionally offers the possibility to vastly increase operational lifetime of low-pressure Argon VUV lamps.

Surface acoustic wave nebulization improves compound selectivity of low-temperature plasma ionization for mass spectrometry

Mass spectrometry coupled to low-temperature plasma ionization (LTPI) allows for immediate and easy analysis of compounds from the surface of a sample at ambient conditions. The efficiency of this process, however, strongly depends on the successful desorption of the analyte from the surface to the gas phase. Whilst conventional sample heating can improve analyte desorption, heating is not desirable with respect to the stability of thermally labile analytes. In this study using aromatic amines as model compounds, we demonstrate that (1) surface acoustic wave nebulization (SAWN) can significantly improve compound desorption for LTPI without heating the sample. Furthermore, (2) SAWN-assisted LTPI shows a response enhancement up to a factor of 8 for polar compounds such as aminophenols and phenylenediamines suggesting a paradigm shift in the ionization mechanism. Additional assets of the new technique demonstrated here are (3) a reduced analyte selectivity (the interquartile range of the response decreased by a factor of 7)—a significant benefit in non-targeted analysis of complex samples—and (4) the possibility for automated online monitoring using an autosampler. Finally, (5) the small size of the microfluidic SAWN-chip enables the implementation of the method into miniaturized, mobile LTPI probes.

Exploring the AGN-merger connection in Arp 245 I: Nuclear star formation and gas outflow in NGC 2992

ABSTRACT Galaxy mergers are central to our understanding of galaxy formation, especially within the context of hierarchical models. Besides having a large impact on the star formation history, mergers are also able to influence gas motions at the centre of galaxies and trigger an active galactic nucleus (AGN). In this paper, we present a case study of the Seyfert galaxy NGC 2992, which together with NGC 2993 forms the early-stage merger system Arp 245. Using Gemini Multi-Object Spectrograph integral field unit data from the inner 1.1 kpc of the galaxy, we were able to spatially resolve the stellar populations, the ionization mechanism, and kinematics of ionized gas. From full spectral synthesis, we found that the stellar population is primarily composed by old metal-rich stars (t ≥ 1.4 Gyr, Z ≥ 2.0 Z⊙), with a contribution of at most 30 per cent of the light from a young and metal-poor population (t ≤ 100 Myr, Z ≤ 1.0 Z⊙). We detect H α and H β emission from the broad-line region with a full width at half-maximum of ∼2000 $\rm km\, s^{-1}$. The narrow-line region kinematics presents two main components: one from gas orbiting the galaxy disc and a blueshifted (velocity ≈ −200 $\rm km\, s^{-1}$) outflow, possibly correlated with the radio emission, with mass outflow rate of ∼2 M⊙ yr−1 and a kinematic power of ∼2 × 1040 erg s−1 ($\dot{E}_{\mathrm{ out}}$/Lbol ≈ 0.2 per cent). We also show even though the main ionization mechanism is the AGN radiation, ionization by young stars and shocks may also contribute to the emission line ratios presented in the innermost region of the galaxy.

Systems Theory: Simulation Analysis of Space Charge Generation Mechanisms in Transformer Oil under High Electric Field

Simulation analysis plays an important role in Systems Theory nowadays. In order to reveal the mechanism of space charge injection and generation in the process of liquid dielectric breakdown, the discharge of transformer oil between needle-plane electrodes under high electric field is studied. Based on the 2-D hydrodynamic model and Poisson equation of electric field, the system simulation model of oil discharge by different charge generation mechanism is established, based on which the inception and propagation process of discharge is simulated by COMSOL. By system simulation, the temporal and spatial distribution of the electric field intensity, space charge density, electric potential and temperature of transformer oil is obtained and deeply analyzed. The simulation results prove that the space charge generated by metal field emission and ionic disassociation are neither of the major factor for streamer formation in transformer oil, while the Zener molecular ionization and impact ionization are the major factors. Our research improves the understanding of the inception, propagation and breakdown process for discharge in transformer oil, and also the ionization mechanism in the liquid dielectric

OVI Traces Photoionized Streams With Collisionally Ionized Boundaries in Cosmological Simulations of z ∼ 1 Massive Galaxies

We analyse the distribution and origin of OVI in the Circumgalactic Medium (CGM) of dark-matter haloes of ∼1012 M⊙ at z ∼ 1 in the VELA cosmological zoom-in simulations. We find that the OVI in the inflowing cold streams is primarily photoionized, while in the bulk volume it is primarily collisionally ionized. The photoionized component dominates the observed column density at large impact parameters (≳ 0.3Rvir), while the collisionally ionized component dominates closer in. We find that most of the collisional OVI, by mass, resides in the relatively thin boundaries of the photoionized streams. Thus, we predict that a reason previous work has found the ionization mechanism of OVI so difficult to determine is because the distinction between the two methods coincides with the distinction between two significant phases of the CGM. We discuss how the results are in agreement with analytic predictions of stream and boundary properties, and their compatibility with observations. This allows us to predict the profiles of OVI and other ions in future CGM observations and provides a toy model for interpreting them.