Defect Structures of Magnetic Nanoparticles in Smectic A Liquid Crystals

Topological defects in anisotropic fluids like liquid crystals serve as a playground for the research of various effects. In this study, we concentrated on a hybrid system of chiral rod-like molecules doped by magnetic nanoparticles. In textures of the smectic A phase, we observed linear defects and found that clusters of nanoparticles promote nucleation of smectic layer defects just at the phase transition from the isotropic to the smectic A (SmA) phase. In different geometries, we studied and analysed creation of defects which can be explained by attractive elastic forces between nanoparticles in the SmA phase. On cooling the studied hybrid system, clusters grow up to the critical dimension, and the smectic texture is stabilised. The presented effects are theoretically described and explained if we consider the elastic interaction of two point defects and stabilisation of prismatic dislocation loops due to the presence of nanoparticles.

A self-healing ferroelectric liquid crystal electro-optic shutter based on vertical surface-relief grating alignment

Ferroelectric liquid crystals remain of interest for display and spatial light modulators because they exhibit significantly faster optical response times than nematics. However, smectic layers are sensitive to shock-induced flow and are usually permanently displaced once a well-aligned sample is disrupted, rendering such devices inoperable. We introduce a vertical alignment geometry combined with a surface-relief grating to control both the smectic layer and director orientations. This mode undergoes “self-healing” of the smectic layers after disruption by shock-induced flow. Sub-millisecond switching between optically distinct states is demonstrated using in-plane electric fields. Self-healing occurs within a second after being disrupted by shock, wherein both the layer and director realign without additional external stimulus. The route to material improvements for optimised devices is discussed, promising faster spatial light modulators for high-speed adaptive optics, micro-displays for virtual/augmented reality and telecommunications with inherent shock stability.

Mono- and bilayer smectic liquid crystal ordering in dense solutions of “gapped” DNA duplexes

Although its mesomorphic properties have been studied for many years, only recently has the molecule of life begun to reveal the true range of its rich liquid crystalline behavior. End-to-end interactions between concentrated, ultrashort DNA duplexes—driving the self-assembly of aggregates that organize into liquid crystal phases—and the incorporation of flexible single-stranded “gaps” in otherwise fully paired duplexes—producing clear evidence of an elementary lamellar (smectic-A) phase in DNA solutions—are two exciting developments that have opened avenues for discovery. Here, we report on a wider investigation of the nature and temperature dependence of smectic ordering in concentrated solutions of various “gapped” DNA (GDNA) constructs. We examine symmetric GDNA constructs consisting of two 48-base pair duplex segments bridged by a single-stranded sequence of 2 to 20 thymine bases. Two distinct smectic layer structures are observed for DNA concentration in the range ∼230to∼280 mg/mL. One exhibits an interlayer periodicity comparable with two-duplex lengths (“bilayer” structure), and the other has a period similar to a single-duplex length (“monolayer” structure). The bilayer structure is observed for gap length ≳10 bases and melts into the cholesteric phase at a temperature between 30 °C and 35 °C. The monolayer structure predominates for gap length ≲10 bases and persists to >40 °C. We discuss models for the two layer structures and mechanisms for their stability. We also report results for asymmetric gapped constructs and for constructs with terminal overhangs, which further support the model layer structures.

Single crystal X-ray structure determination and temperature-dependent structural studies of the smectogenic compound 7OS5

Structural characteristics of solid and liquid crystalline phases of 7OS5 (4-n-pentylphenyl-4′-n-heptyloxythiobenzoate), the achiral smectogenic mesogen with the shortest terminal carbon chain in the nOS5 homologous series, are studied by complementary methods. Simultaneously perfomed X-ray diffraction and differential scanning calorimetry occur to be a powerful tool to study metastable phases. The single crystal structure of a high-temperature phase, supercooled from the room temperature down to −183°C [orthorhombic crystal system; space group Pca21; a = 54.285 (5) Å, b = 5.5843 (3) Å, c = 14.841 (1) Å, Z = 8] is determined. Lamellar ordering of elongated molecules is stabilized by hydrogen bonds . Temperature dependence of unit-cell parameters in two crystal phases as well as structural parameters of liquid crystalline phases (smectic layer spacing, tilt angle, average distance between the long axes of molecules and correlation lengths) are determined by X-ray diffraction. The obtained results are compared with the data available for other compounds in the nOS5 homologous series.

Molecular–Statistical Theory for the Description of Re-Entrant Ferroelectric Phase

The re-entrant ferroelectric phase (Sm- C re * ) is investigated in the framework of a molecular–statistical approach. It was found that anticlinic synpolar along the smectic layer normal phase can arise below the antiferroelectric phase (Sm- C A * ) in the temperature scale, and we suggest this phase to be Sm- C re * . We have shown that in the vicinity of Sm- C A * –Sm- C re * phase transition temperature, a very small electric field can cause a transition into the bidomain synclinic phase, where the helical pitch is unwound and the tilt planes have contributions either along or against the electric field. The helical rotation, elasticity and deformation of the Sm- C * , Sm- C A * and Sm- C re * structures without electric field or in the presence of electric field, as well as the dielectric response, are investigated. It is shown that Sm- C re * can arise solely due to the dipole–dipole interaction, and thus, in contrast to the conventional (improper) ferroelectric Sm- C * , appears to be the proper ferroelectric phase.

NMR Spectroscopic Study of Orientational Order in Imidazolium-Based Ionic Liquid Crystals

We report on molecular and local orientational order of a series of imidazolium-based ionic liquid crystals exhibiting layered smectic A mesophase. Materials constituting of 1-dodecyl-3-methylimidazolium cation, and different counter-ions, were investigated. We apply two-dimensional 13C-1H dipolar NMR spectroscopy to quantify orientational order of C-H bonds of the organic cation. The experimental data supported the structural model of the interdigitated chains aligned with the smectic layer normal. Molecular order parameter S was found to increase in the anion sequence BF4− < I− < Br− < Cl−. This trend correlates well with ionic radius, negative charge delocalization, and hydrogen-bonding properties of the anions.

Nonlinear Optical Phenomena in a Silicon-Smectic A Liquid Crystal (SALC) Waveguide

Liquid crystals (LCs) are organic materials characterized by the intermediate properties between those of an isotropic liquid and a crystal with a long range order. The LCs possess strong anisotropy of their optical and electro-optical properties. In particular, LCs possess strong optical nonlinearity. LCs are compatible with silicon-based technologies. Due to these unique properties, LCs are promising candidates for the development of novel integrated devices for telecommunications and sensing. Nematic liquid crystals (NLCs) are mostly used and studied. Smectic A liquid crystals (SALCs) have a higher degree of long range order forming a layered structure. As a result, they have lower scattering losses, specific mechanisms of optical nonlinearity related to the smectic layer displacement without the mass density change, and they can be used in nonlinear optical applications. We theoretically studied the nonlinear optical phenomena in a silicon-SALC waveguide. We have shown theoretically that the stimulated light scattering (SLS) and cross-phase modulation (XPM) caused by SALC nonlinearity can occur in the silicon-SALC waveguide. We evaluated the smectic layer displacement, the SALC hydrodynamic velocity, and the slowly varying amplitudes (SVAs) of the interfering optical waves.