RF Sputter-Etching by Fluoro-Chloro-Hydrocarbon Gases

1974 ◽  
Vol 13 (S1) ◽  
pp. 435 ◽  
Author(s):  
Naokichi Hosokawa ◽  
Reisaku Matsuzaki ◽  
Tatsuo Asamaki
Keyword(s):  
Hydrocarbon Gases ◽  
Sputter Etching

Pyrolytic carbon filaments and associated catalytic particles formed in steel tubes

1984 ◽  
Vol 42 ◽  
pp. 662-663
Author(s):  
Y. L. Chen ◽  
J. R. Bradley
Keyword(s):  
Stainless Steel ◽  
Carbon Steel ◽  
Catalyst Particle ◽  
Pyrolytic Carbon ◽  
Plain Carbon Steel ◽  
304 Stainless Steel ◽  
Hydrocarbon Gases ◽  
Steel Tubes ◽  
Filamentous Carbon ◽  
Carbon Filaments

Considerable effort has been directed toward an improved understanding of the production of the strong and stiff ∼ 1-20 μm diameter pyrolytic carbon fibers of the type reported by Koyama and, more recently, by Tibbetts. These macroscopic fibers are produced when pyrolytic carbon filaments (∼ 0.1 μm or less in diameter) are thickened by deposition of carbon during thermal decomposition of hydrocarbon gases. Each such precursor filament normally lengthens in association with an attached catalyst particle. The subject of filamentous carbon formation and much of the work on characterization of the catalyst particles have been reviewed thoroughly by Baker and Harris. However, identification of the catalyst particles remains a problem of continuing interest. The purpose of this work was to characterize the microstructure of the pyrolytic carbon filaments and the catalyst particles formed inside stainless steel and plain carbon steel tubes. For the present study, natural gas (∼; 97 % methane) was passed through type 304 stainless steel and SAE 1020 plain carbon steel tubes at 1240°K.

Stable isotope characteristics of hydrocarbon gases in the alkaline Ilímaussaq complex, South Greenland

1988 ◽  
Vol 111 (6) ◽  
pp. 567-576 ◽  
Author(s):  
Jens Konnerup-Madsen ◽  
Rob Kreulen ◽  
John Rose-Hansen
Keyword(s):  
Stable Isotope ◽  
Hydrocarbon Gases

A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland

2001 ◽  
pp. 159-166 ◽  
Author(s):  
Jens Konnerup-Madsen
Keyword(s):  
Nepheline Syenite ◽  
Subsequent Development ◽  
High Water ◽  
Vapour Phase ◽  
Low Carbon ◽  
Low Oxygen ◽  
Alkaline Complex ◽  
Hydrocarbon Gases ◽  
Wide Range ◽  
Water Contents

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Konnerup-Madsen, J. (2001). A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 159-166. https://doi.org/10.34194/ggub.v190.5187 _______________ Fluid inclusions in minerals from agpaitic nepheline syenites and hydrothermal veins in the Ilímaussaq complex and in similar agpaitic complexes on the Kola Peninsula, Russia, are dominated by hydrocarbon gases (predominantly methane) and hydrogen. Such volatile compositions differ considerably from those of most other igneous rocks and their formation and entrapment in minerals reflects low oxygen fugacities and a wide range of crystallisation temperatures extending to a low-temperature solidus. Their composition reflects initial low carbon contents and high water contents of the magma resulting in the exsolution of a waterrich CO2–H2O dominated vapour phase. Fractionation of chlorides into the vapour phase results in high salinities and the subsequent development of a heterogeneous vapour phase with a highly saline aqueous-rich fraction and a methane-dominated fraction, with preferential entrapment of the latter, possibly due to different wetting characteristics. The light stable isotope compositions support an abiogenic origin for the hydrocarbons in agpaitic nepheline syenite complexes.

Generation and origin of natural gas in Lower Palaeozoic shales from southern Sweden

1969 ◽  
pp. 37-40
Author(s):  
Niels Hemmingsen Schovsbo ◽  
Arne Thorshøj Nielsen
Keyword(s):  
Source Rocks ◽  
Southern Sweden ◽  
Hydrocarbon Gases ◽  
Biogenic Gas ◽  
South Central ◽  
Alum Shale ◽  
Marine Source ◽  
Lower Palaeozoic ◽  
Background Gas ◽  
Origin Of Natural Gas

The Lower Palaeozoic succession in Scandinavia includes several excellent marine source rocks notably the Alum Shale, the Dicellograptus shale and the Rastrites Shale that have been targets for shale gas exploration since 2008. We here report on samples of these source rocks from cored shallow scientific wells in southern Sweden. The samples contain both free and sorbed hydrocarbon gases with concentrations significantly above the background gas level. The gases consist of a mixture of thermogenic and bacterially derived gas. The latter likely derives from both carbonate reduction and methyl fermentation processes. The presence of both thermogenic and biogenic gas in the Lower Palaeozoic shales is in agreement with results from past and present exploration activities; thermogenic gas is a target in deeply buried, gas-mature shales in southernmost Sweden, Denmark and northern Poland, whereas biogenic gas is a target in shallow, immature-marginally mature shales in south central Sweden. We here document that biogenic gas signatures are present also in gas-mature shallow buried shales in Skåne in southernmost Sweden.

scholarly journals Spatial Relationships between Pockmarks and Sub-Seabed Gas in Fjordic Settings: Evidence from Loch Linnhe, West Scotland

Geosciences ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 283
Author(s):  
Allan Audsley ◽  
Tom Bradwell ◽  
John Howe ◽  
John Baxter
Keyword(s):  
Water Column ◽  
Seismic Reflection ◽  
Hot Spot ◽  
Geophysical Data ◽  
Spatial Relationships ◽  
Hydrocarbon Gases ◽  
Offshore Industry ◽  
Seismic Reflection Profiles ◽  
Spot Analysis ◽  
Sedimentary Carbon

Sub-seabed gas is commonly associated with seabed depressions known as pockmarks—the main venting sites for hydrocarbon gases to enter the water column. Sub-seabed gas accumulations are characterized by acoustically turbid or opaque zones in seismic reflection profiles, taking the form of gas blankets, curtains or plumes. How the migration of sub-seabed gas relates to the origin and distribution of pockmarks in nearshore and fjordic settings is not well understood. Using marine geophysical data from Loch Linnhe, a Scottish fjord, we show that shallow sub-seabed gas occurs predominantly within glaciomarine facies either as widespread blankets in basins or as isolated pockets. We use geospatial ‘hot-spot’ analysis conducted in ArcGIS to identify clusters of pockmarks and acoustic (sub-seabed) profile interpretation to identify the depth to gas front across the fjord. By combining these analyses, we find that the gas below most pockmarks in Loch Linnhe is between 1.4 m and 20 m deep. We anticipate that this work will help to understand the fate and mobility of sedimentary carbon in fjordic (marine) settings and advise offshore industry on the potential hazards posed by pockmarked seafloor regions even in nearshore settings.

Strength and Adhesion of Thin Aluminum Oxide Film Deposited on Iron Surface

1993 ◽  
Vol 115 (4) ◽  
pp. 615-619 ◽  
Author(s):  
M. Nakanishi ◽  
H. Okuya ◽  
K. Nakajima
Keyword(s):  
Oxide Film ◽  
Aluminum Oxide ◽  
Substrate Surface ◽  
Iron Surface ◽  
Indentation Hardness ◽  
Aluminum Oxide Film ◽  
Thin Aluminum ◽  
Atomic Mixing ◽  
Scratch Tests ◽  
Sputter Etching

The strength of deposited film and the adhesion between the film and the substrate were investigated with deposited aluminum oxide film on iron surface by scratching the surface with a diamond cone. Two types of samples were examined, one with oxide film deposited after cleaning the substrate surface by sputter etching, the other with the film deposited without any sputter etching. It was found that a law similar to Meyers’ for indentation hardness holds between the load and scratch width on the sample examined. These results suggest that by analyzing the scratch data the adhesion strength of the film to the substrate can be estimated together with the hardness of the film itself. Analyses by EPMA (electron probe X-ray microanalyzer) and AES (Auger electron spectroscopy) were conducted to correlate the results obtained by the scratch tests and friction experiments, and it was confirmed that (i) adhesion is improved by sputter etching prior to the deposition of the film; (ii) adhesion decreases considerably due to the progress of oxidation in the vicinity of the interface, which depends markedly on the oxygen concentration in the oxide film; and (iii) there is an optimum thickness of the three-component layer (Fe, Al, and O) formed by atomic mixing at the interface for maximizing the adhesion.

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