scholarly journals Photocatalytic activity of tungsten trioxide/silver oxide composite under visible light irradiation for methylene blue degradation

2018 ◽  
Vol 67 (16) ◽  
pp. 167802
Author(s):  
Shao Zi-Qiao ◽  
Bi Heng-Chang ◽  
Xie Xiao ◽  
Wan Neng ◽  
Sun Li-Tao
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Tungsten Trioxide ◽  
Silver Oxide ◽  
Light Irradiation ◽  
Methylene Blue Degradation ◽  
Oxide Composite

Photocatalytic Degradation of Methylene Blue over Co-Ag3VO4 under Visible Light Irradiation

2011 ◽  
Vol 335-336 ◽  
pp. 1385-1390 ◽  
Author(s):  
Shuo Wiei Zhao ◽  
Hui Xu ◽  
Hua Ming Li ◽  
Yuan Guo Xu
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Absorption Edge ◽  
Diffuse Reflectance Spectroscopy ◽  
Dye Degradation ◽  
Light Irradiation ◽  
Experimental Conditions ◽  
X Ray

In order to improve the photocatalytic activity, Co was successfully loaded into Ag3VO4 by using impregnation process. The samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDS) and diffuse reflectance spectroscopy (DRS). The XRD and SEM–EDS analyses revealed that Co ion was dispersed on Ag3VO4. The DRS results indicated that the absorption edge of the Co–Ag3VO4 catalyst shifted to longer wavelength. The enhanced photocatalytic activity of Co–Ag3VO4 for Methylene Blue(MB) dye degradation under visible light irradiation was due to its wider absorption edge and higher separation rate of photo-generated electron and holes. In the experimental conditions, it is demonstrated that the MB was effectively degraded by more than 95% within 40 min when the Co–Ag3VO4 catalyst was calcined at 300°C with 1 wt.% Co content.

scholarly journals Photocatalytic Degradation of Methylene Blue and Methyl Orange by Y-PTC Metal-Organic Framework

2021 ◽  
Vol 7 (2) ◽  
pp. 129-141
Author(s):  
Adawiah Adawiah ◽  
Muhammad Derry Luthfi Yudhi ◽  
Agustino Zulys
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Metal Organic Framework ◽  
Light Irradiation ◽  
Bandgap Energy ◽  
Metal Organic ◽  
Organic Framework

The yttrium based metal-organic framework (MOF) Y-PTC was synthesized by the solvothermal method using perylene as the linker and yttrium as metal ion. This study aims to assess the photocatalytic activity of yttrium-perylenetetracarboxylate (Y-PTC) metal-organic framework (MOF) toward methylene blue and methyl orange under visible light irradiation. The results of the FTIR analysis showed that Y-PTC MOF had a different structure and composition from its precursor (Na4PTC). The Y-PTC MOF has a bandgap energy value of 2.20 eV with a surface area of 47.7487 m2/g. The SEM-EDS analysis showed an elemental composition of yttrium, carbon, and oxygen, were 6.9%, 72.1% and 20.7%, respectively. Furthermore, Y-PTC MOF was able to adsorb dyes at the optimum by 78.10% and 35.57% toward methylene blue (MB) and methyl orange (MO) at the dispersion period of 60 mins. Y-PTC MOF exhibited photocatalytic activity towards the degradation of methylene blue and methyl orange under visible light irradiation. The addition of H2O2 inhibited Y-PTC photocatalytic activity towards MO degradation from 50.89% to 26.38%. In contrast to MO, the addition of H2O2 had a positive effect on MB, which increased the degradation from 87.56% to 91.65%. Therefore, Y-PTC MOF possessed the potential of a photocatalyst material in dyes degradation under visible light irradiation.

scholarly journals Visible-enhanced photocatalytic performance of CuWO4/WO3 hetero-structures: incorporation of plasmonic Ag nanostructures

2018 ◽  
Vol 42 (13) ◽  
pp. 11109-11116 ◽  
Author(s):  
R. Salimi ◽  
A. A. Sabbagh Alvani ◽  
N. Naseri ◽  
S. F. Du ◽  
D. Poelman
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Photocatalytic Performance ◽  
Sol Gel ◽  
Light Irradiation ◽  
Photo Degradation ◽  
Gel Method ◽  
Sol Gel Method

A new plasmonic Ag hybridized CuWO4/WO3 heterostructured nanocomposite was successfully synthesized via a ligand-assisted sol gel method and the photocatalytic activity was evaluated by photo-degradation of methylene blue (MB) under visible light irradiation.

The photocatalytic activity and degradation mechanism of methylene blue over copper(ii) tetra(4-carboxyphenyl) porphyrin sensitized TiO2under visible light irradiation

RSC Advances ◽  
2014 ◽  
Vol 4 (55) ◽  
pp. 28978-28986 ◽  
Author(s):  
Huigang Wang ◽  
Dongmei Zhou ◽  
Shaosong Shen ◽  
Junmin Wan ◽  
Xuming Zheng ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Catalytic Mechanism ◽  
Degradation Mechanism ◽  
Light Irradiation ◽  
Electronic Relaxation ◽  
Relaxation Dynamics

Copper(ii)tetra(4-carboxyphenyl) porphyrin were chemically sensitized on TiO2, its electronic relaxation dynamics and the visible-light induced catalytic mechanism are discussed.

scholarly journals Solvothermal synthesis of pure and Sn-doped Bi2S3 and the evaluation of their photocatalytic activity on the degradation of methylene blue

BMC Chemistry ◽  
2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Violet M. Nkwe ◽  
Damian C. Onwudiwe ◽  
Mayowa A. Azeez
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Recombination Rate ◽  
Equilibrium Concentration ◽  
Light Irradiation ◽  
Complex Nature ◽  
Transition Elements ◽  
Cost Efficient

Abstract Background A large volume of dye molecules finds its way into the environment, accumulates in water bodies, and makes the aquatic system unsafe to human health. Due to the complex nature of these dye materials, most of the conventional techniques are not effective for their removal. Semiconductor photocatalysis has emerged as a promising technique for  the destruction of organic pollutants under UV or visible light irradiation. Among the semiconductors, Bi2S3 is widely employed in photocatalysis due to its non-toxicity and chemical stability. However, one of its problems is the high recombination rate of the charge, and various methods have been employed to enhance the photo-reactivity. One of  these methods is the incorporation of transition elements. Results Herein, a facile solvothermal method was used to prepare Bi2S3 nanorods and needle- shaped Sn doped Bi2S3, using bismuth(III) tris(N-phenyldithiocarbamate) as a single-source precursor. The prepared nanomaterials were characterized, and used as efficient photocatalyst for the photo enhanced degradation of methylene blue (MB) dye under visible light irradiation. The nanomaterials exhibited very good photocatalytic activity towards the photo degradation of MB, showing a degradation rate of up to 83% and 94% within 150 min for the pristine and Sn doped Bi2S3,  respectively. Conclusion The enhancement in the photocatalytic activity of the Sn doped Bi2S3 was attributed to the suppression in the recombination rate of the electron‐hole pairs, due to the formation of new energy level below the CB, that was capable of altering the equilibrium concentration of the carrier. This confirmed that Sn doped Bi2S3 could be utilized as valuable cost-efficient catalysts for eliminating methyl blue from aqueous solutions and also possible candidates in environmental pollution treatment.

The Preparation of InxBi1-xVO4 Photocatalyst Particles and their Photocatalytic Activity

2013 ◽  
Vol 726-731 ◽  
pp. 491-494
Author(s):  
En Guo Wang ◽  
Zhen Qin Zhan
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Sintering Temperature ◽  
Orthorhombic Phase ◽  
Indium Content ◽  
Light Irradiation ◽  
Solid Reaction ◽  
X Ray

InxBi1-xVO4 photocatalyst particles were prepared by low temperature solid reaction using nitrate of indium and bismuth and NH4VO4 as the starting materials, and followed by the sintering at various temperatures. The as-prepared samples were investigated by X-ray powder diffraction (XRD), and the photocatalytic activity was carried out by the concentration change of methylene blue in the solution after visible light irradiation. The experiment results show that the orthorhombic phase InVO4 is dominant in the photocatalyst samples prepared at sintering temperature higher than 600°C. In addition, the increase in indium content in the InxBi1-xVO4 particle has greatly improved the photocatalytic activity for decomposition of aqueous methylene blue under visible light irradiation.

scholarly journals Hydrothermal Synthesis and Enhanced Photocatalytic Activity of TiO\(_{2}\)-Fe@CNTs Nanocomposite for Methylene Blue Degradation under Visible Light Irradiation

2015 ◽  
Vol 24 (4) ◽  
pp. 363
Author(s):  
Le Ha Chi ◽  
Pham Duy Long ◽  
Nguyen Van Chuc ◽  
Le Van Hong
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Tio2 Nanoparticles ◽  
Uv Light ◽  
Band Gap Energy ◽  
Nanocomposite Materials ◽  
Light Irradiation ◽  
Hydrothermal Route ◽  
Methylene Blue Degradation

TiO2 is one of the most attractive metal oxides because of the excellent chemical and photocatalytic properties. However, a problem in the application of TiO2 is the large band gap energy of 3.2 eV, corresponding to its photocatalytic activity under UV-light irradiation of wavelengths <387 nm. In this work, TiO2 nanoparticles doped with iron were grown on the surface of functionalized carbon nanotubes (TiO2-Fe@CNTs) to expand the photoabsorbance of the nanocomposite materials in the visible light region and improve their photocatalytic activity. TiO2-Fe@CNTs nanocomposite materials were synthesized by hydrothermal route in Teflon-sealed autoclave at 180oC for 10h. The FE-SEM and X-Ray diffraction measurements were taken for morphology and structural analysis of TiO2 nanoparticles doped with Fe coating on CNTs. The effects of the iron and CNTs on the enhanced photocatalytic activity for methylene blue degradation under AM 1.5 illumination of 100 mW.cm−2 were investigated.

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