The photocatalytic activity and degradation mechanism of methylene blue over copper(ii) tetra(4-carboxyphenyl) porphyrin sensitized TiO2under visible light irradiation

RSC Advances ◽  
2014 ◽  
Vol 4 (55) ◽  
pp. 28978-28986 ◽  
Author(s):  
Huigang Wang ◽  
Dongmei Zhou ◽  
Shaosong Shen ◽  
Junmin Wan ◽  
Xuming Zheng ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Catalytic Mechanism ◽  
Degradation Mechanism ◽  
Light Irradiation ◽  
Electronic Relaxation ◽  
Relaxation Dynamics

Copper(ii)tetra(4-carboxyphenyl) porphyrin were chemically sensitized on TiO2, its electronic relaxation dynamics and the visible-light induced catalytic mechanism are discussed.

scholarly journals One-Step Microwave-Assisted Synthesis and Visible-Light Photocatalytic Activity Enhancement of BiOBr/RGO Nanocomposites for Degradation of Methylene Blue

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4577
Author(s):  
Kun-Yauh Shih ◽  
Yen-Ling Kuan ◽  
En-Rui Wang
Keyword(s):  
Electron Microscopy ◽  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Degradation Mechanism ◽  
Photogenerated Electron ◽  
Light Irradiation ◽  
Microwave Assisted ◽  
One Step

In this study, bismuth oxybromide/reduced graphene oxide (BiOBr/RGO), i.e. BiOBr-G nanocomposites, were synthesized using a one-step microwave-assisted method. The structure of the synthesized nanocomposites was characterized using Raman spectroscopy, X-ray diffractometry (XRD), photoluminescence (PL) emission spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), and ultraviolet-visible diffuse reflection spectroscopy (DRS). In addition, the ability of the nanocomposite to degrade methylene blue (MB) under visible light irradiation was investigated. The synthesized nanocomposite achieved an MB degradation rate of above 96% within 75 min of continuous visible light irradiation. In addition, the synthesized BiOBr-G nanocomposite exhibited significantly enhanced photocatalytic activity for the degradation of MB. Furthermore, the results revealed that the separation of the photogenerated electron–hole pairs in the BiOBr-G nanocomposite enhanced the ability of the nanocomposite to absorb visible light, thus improving the photocatalytic properties of the nanocomposites. Lastly, the MB photo-degradation mechanism of BiOBr-G was investigated, and the results revealed that the BiOBr-G nanocomposites exhibited good photocatalytic activity.

Photocatalytic Degradation of Methylene Blue over Co-Ag3VO4 under Visible Light Irradiation

2011 ◽  
Vol 335-336 ◽  
pp. 1385-1390 ◽  
Author(s):  
Shuo Wiei Zhao ◽  
Hui Xu ◽  
Hua Ming Li ◽  
Yuan Guo Xu
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Absorption Edge ◽  
Diffuse Reflectance Spectroscopy ◽  
Dye Degradation ◽  
Light Irradiation ◽  
Experimental Conditions ◽  
X Ray

In order to improve the photocatalytic activity, Co was successfully loaded into Ag3VO4 by using impregnation process. The samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDS) and diffuse reflectance spectroscopy (DRS). The XRD and SEM–EDS analyses revealed that Co ion was dispersed on Ag3VO4. The DRS results indicated that the absorption edge of the Co–Ag3VO4 catalyst shifted to longer wavelength. The enhanced photocatalytic activity of Co–Ag3VO4 for Methylene Blue(MB) dye degradation under visible light irradiation was due to its wider absorption edge and higher separation rate of photo-generated electron and holes. In the experimental conditions, it is demonstrated that the MB was effectively degraded by more than 95% within 40 min when the Co–Ag3VO4 catalyst was calcined at 300°C with 1 wt.% Co content.

scholarly journals Photocatalytic Degradation of Methylene Blue and Methyl Orange by Y-PTC Metal-Organic Framework

2021 ◽  
Vol 7 (2) ◽  
pp. 129-141
Author(s):  
Adawiah Adawiah ◽  
Muhammad Derry Luthfi Yudhi ◽  
Agustino Zulys
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Metal Organic Framework ◽  
Light Irradiation ◽  
Bandgap Energy ◽  
Metal Organic ◽  
Organic Framework

The yttrium based metal-organic framework (MOF) Y-PTC was synthesized by the solvothermal method using perylene as the linker and yttrium as metal ion. This study aims to assess the photocatalytic activity of yttrium-perylenetetracarboxylate (Y-PTC) metal-organic framework (MOF) toward methylene blue and methyl orange under visible light irradiation. The results of the FTIR analysis showed that Y-PTC MOF had a different structure and composition from its precursor (Na4PTC). The Y-PTC MOF has a bandgap energy value of 2.20 eV with a surface area of 47.7487 m2/g. The SEM-EDS analysis showed an elemental composition of yttrium, carbon, and oxygen, were 6.9%, 72.1% and 20.7%, respectively. Furthermore, Y-PTC MOF was able to adsorb dyes at the optimum by 78.10% and 35.57% toward methylene blue (MB) and methyl orange (MO) at the dispersion period of 60 mins. Y-PTC MOF exhibited photocatalytic activity towards the degradation of methylene blue and methyl orange under visible light irradiation. The addition of H2O2 inhibited Y-PTC photocatalytic activity towards MO degradation from 50.89% to 26.38%. In contrast to MO, the addition of H2O2 had a positive effect on MB, which increased the degradation from 87.56% to 91.65%. Therefore, Y-PTC MOF possessed the potential of a photocatalyst material in dyes degradation under visible light irradiation.

scholarly journals Visible-enhanced photocatalytic performance of CuWO4/WO3 hetero-structures: incorporation of plasmonic Ag nanostructures

2018 ◽  
Vol 42 (13) ◽  
pp. 11109-11116 ◽  
Author(s):  
R. Salimi ◽  
A. A. Sabbagh Alvani ◽  
N. Naseri ◽  
S. F. Du ◽  
D. Poelman
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Photocatalytic Performance ◽  
Sol Gel ◽  
Light Irradiation ◽  
Photo Degradation ◽  
Gel Method ◽  
Sol Gel Method

A new plasmonic Ag hybridized CuWO4/WO3 heterostructured nanocomposite was successfully synthesized via a ligand-assisted sol gel method and the photocatalytic activity was evaluated by photo-degradation of methylene blue (MB) under visible light irradiation.

scholarly journals Solvothermal synthesis of pure and Sn-doped Bi2S3 and the evaluation of their photocatalytic activity on the degradation of methylene blue

BMC Chemistry ◽  
2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Violet M. Nkwe ◽  
Damian C. Onwudiwe ◽  
Mayowa A. Azeez
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Recombination Rate ◽  
Equilibrium Concentration ◽  
Light Irradiation ◽  
Complex Nature ◽  
Transition Elements ◽  
Cost Efficient

Abstract Background A large volume of dye molecules finds its way into the environment, accumulates in water bodies, and makes the aquatic system unsafe to human health. Due to the complex nature of these dye materials, most of the conventional techniques are not effective for their removal. Semiconductor photocatalysis has emerged as a promising technique for  the destruction of organic pollutants under UV or visible light irradiation. Among the semiconductors, Bi2S3 is widely employed in photocatalysis due to its non-toxicity and chemical stability. However, one of its problems is the high recombination rate of the charge, and various methods have been employed to enhance the photo-reactivity. One of  these methods is the incorporation of transition elements. Results Herein, a facile solvothermal method was used to prepare Bi2S3 nanorods and needle- shaped Sn doped Bi2S3, using bismuth(III) tris(N-phenyldithiocarbamate) as a single-source precursor. The prepared nanomaterials were characterized, and used as efficient photocatalyst for the photo enhanced degradation of methylene blue (MB) dye under visible light irradiation. The nanomaterials exhibited very good photocatalytic activity towards the photo degradation of MB, showing a degradation rate of up to 83% and 94% within 150 min for the pristine and Sn doped Bi2S3,  respectively. Conclusion The enhancement in the photocatalytic activity of the Sn doped Bi2S3 was attributed to the suppression in the recombination rate of the electron‐hole pairs, due to the formation of new energy level below the CB, that was capable of altering the equilibrium concentration of the carrier. This confirmed that Sn doped Bi2S3 could be utilized as valuable cost-efficient catalysts for eliminating methyl blue from aqueous solutions and also possible candidates in environmental pollution treatment.

The Preparation of InxBi1-xVO4 Photocatalyst Particles and their Photocatalytic Activity

2013 ◽  
Vol 726-731 ◽  
pp. 491-494
Author(s):  
En Guo Wang ◽  
Zhen Qin Zhan
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Sintering Temperature ◽  
Orthorhombic Phase ◽  
Indium Content ◽  
Light Irradiation ◽  
Solid Reaction ◽  
X Ray

InxBi1-xVO4 photocatalyst particles were prepared by low temperature solid reaction using nitrate of indium and bismuth and NH4VO4 as the starting materials, and followed by the sintering at various temperatures. The as-prepared samples were investigated by X-ray powder diffraction (XRD), and the photocatalytic activity was carried out by the concentration change of methylene blue in the solution after visible light irradiation. The experiment results show that the orthorhombic phase InVO4 is dominant in the photocatalyst samples prepared at sintering temperature higher than 600°C. In addition, the increase in indium content in the InxBi1-xVO4 particle has greatly improved the photocatalytic activity for decomposition of aqueous methylene blue under visible light irradiation.

Controlled synthesis of organic ligand passivated ZnO nanostructures and their photocatalytic activity under visible light irradiation

2015 ◽  
Vol 44 (22) ◽  
pp. 10490-10498 ◽  
Author(s):  
S. Harish ◽  
M. Navaneethan ◽  
J. Archana ◽  
A. Silambarasan ◽  
S. Ponnusamy ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Zinc Oxide ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Organic Ligand ◽  
Light Irradiation ◽  
Controlled Synthesis ◽  
Zno Nanostructures

Zinc oxide (ZnO) nanostructures were synthesized and their photocatalytic activity was evaluated using methylene blue (MB) as a model pollutant.

Enhanced Photocatalytic Activity by Silver-Modified Bismuth Vanadate

2017 ◽  
Vol 757 ◽  
pp. 88-92
Author(s):  
Cheewita Suwanchawalit ◽  
Kamonchanok Roongraung ◽  
Supat Buddee ◽  
Sumpun Wongnawa ◽  
Avinash Patil
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Visible Region ◽  
Bismuth Vanadate ◽  
Light Irradiation ◽  
Precipitation Method ◽  
Blue Dye ◽  
Vis Spectroscopy

Silver-modified bismuth vanadate (Ag-BiVO4) photocatalysts were easily prepared via the co-precipitation method. The effects of silver contents on the chemical properties of BiVO4 were evaluated. The prepared Ag-BiVO4 samples were characterized by several techniques such as X-ray diffractometry (XRD), scanning electron microscopy (SEM), and diffused reflectance UV-Vis spectroscopy (DRS). The mixed phase of monoclinic scheetlite structure and characteristic peaks of silver particles were found. Silver contents strongly affect the morphology of the prepared Ag-BiVO4 samples. DRS spectra revealed that the synthesized Ag-BiVO4 samples exhibited strong absorption in the visible region. The absorption in the visible zone is responsible for the high photocatalytic activity of Ag-BiVO4 under visible light irradiation. The photocatalytic degradation of methylene blue under visible light irradiation was studied using the BiVO4 as photocatalysts. The photocatalytic results reveal that the prepared Ag-BiVO4 samples could degrade the methylene blue dye.

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