scholarly journals Study of the time-resolved emission spectra of the ejected plume generated by ultrashort laser ablation of graphite

2015 ◽  
Vol 64 (21) ◽  
pp. 214201
Author(s):  
Feng Pei-Pei ◽  
Wu Han ◽  
Zhang Nan
2007 ◽  
Vol 73 (2) ◽  
pp. 231-239 ◽  
Author(s):  
AI HUA LIU

Abstract.A time-resolved diagnostic technique was used to investigate the emission spectra from the plasmas produced by 1.06 μm, 10 ns pulsed laser ablation of semiconductor GaAs. The characteristics of the species in plasma produced at different ambient pressure were analyzed. The full width at half maximum of the spectral line was measured and analyzed according to obtained spectra of the excited atoms; several line broadening factors were estimated according to our experimental conditions and the results indicate that the Stark broadening is the main broadening mechanism. Under the assumption of local thermodynamic equilibrium, the time evolution of electron number density was deduced from the Stark broadening measurements.


2013 ◽  
Vol 31 (3) ◽  
pp. 539-545 ◽  
Author(s):  
Zhandong Chen ◽  
Qiang Wu ◽  
Ming Yang ◽  
Baiquan Tang ◽  
Jianghong Yao ◽  
...  

AbstractGeneration and evolution of plasma during femtosecond laser ablation of silicon are studied by steady-state and time-resolved spectroscopy in air, N2, SF6, and under vacuum. The plasma is generated faster than 200 ps (time resolution of our experiment) after excitation and mainly contains atoms and monovalent ions of silicon. Time-resolved spectra prove that silicon ions are faster than the silicon atoms which may be attributed to Coulomb repulsion and a local electric field when they are ejected from the silicon surface. During plasma evolution, ambient gas causes a confinement effect that enhances the dissociation of ambient gas molecules and the re-deposition of the removed material and leads to higher intensity and longer lifetime of the emission spectra. In SF6, a chemical reaction increases the plasma density and weakens the re-deposition effect. The different processes during plasma evolution strongly influence microstructure formation.


2016 ◽  
Vol 20 (08n11) ◽  
pp. 1173-1181 ◽  
Author(s):  
Narra Vamsi Krishna ◽  
Puliparambil Thilakan Anusha ◽  
S. Venugopal Rao ◽  
L. Giribabu

Zinc phthalocyanine possessing triphenylamine at its peripheral position has been synthesized and its optical, emission, electrochemical and third-order nonlinear optical (NLO) properties were investigated. Soret band was broadened due to the presence of triphenylamine moiety. Electrochemical properties indicated that both oxidation and reduction processes were ring centered. Emission spectra were recorded in different solvents and the fluorescence yields obtained were in the range of 0.02–0.17 while the time-resolved fluorescence data revealed radiative lifetimes of typically few ns. Third-order NLO properties of this molecule have been examined using the Z-scan technique with picosecond (ps) and femtoseocnd (fs) pulses. Closed and open aperture Z-scan data were recorded with 2 ps/1 50 fs laser pulses at a wavelength of 800 nm and NLO coefficients were extracted from both the data. Our data clearly suggests the potential of this molecule for photonics applications.


2004 ◽  
Author(s):  
Hanriete P. de Souza ◽  
Egberto Munin ◽  
Carlos Eduardo de Vilhena Paiva ◽  
Leandro P. Alves ◽  
Marcela L. Redigolo ◽  
...  

2014 ◽  
Vol 115 (24) ◽  
pp. 243301 ◽  
Author(s):  
N. Tsakiris ◽  
K. K. Anoop ◽  
G. Ausanio ◽  
M. Gill-Comeau ◽  
R. Bruzzese ◽  
...  

1999 ◽  
Vol 18 (3) ◽  
pp. 99-109 ◽  
Author(s):  
Yongxin Tang ◽  
Zhenhui Han ◽  
Qizong Qin

Pulsed laser ablation of TiO2 at 355 nm and 532 nm has been investigated using an angleand time-resolved quadrupole mass spectrometric technique. The major ablated species include O (m/e = 16), O2 (m/e = 32), Ti (m/e = 48), TiO (m/e = 64) and TiO2 (m/e = 80). The time-of-flight (TOF) spectra of ablated species are measured for the ionic and neutral ablated species, and they can be fitted by a Maxwell – Boltzmann (M – B) distribution with a center-of-mass velocity. The measured angular distributions of the ionic species (O+ and Ti+) and the neutral species (O and Ti) can be fitted with cos⁡nθ and a cos⁡θ + (1−a)cos⁡nθ, respectively. In addition, a continuous wave oxygen molecular beam is introduced into the ablated plume, and the enhancement of the signal intensities of TiO is observed. It implies that the ablated Ti atoms/ions species can react with ambient oxygen molecules in the gas phase. In the meanwhile, the physicochemical mechanism of pulsed laser ablation of TiO2 is discussed.


Author(s):  
Yasuaki Okano ◽  
Yoichiro Hironaka ◽  
Ken-ichi Kondo ◽  
Kazutaka G. Nakamura

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