scholarly journals X-ray absorption near-edge structure spectroscopy research on electronic structures and magnetic properties of (Fe1-xNix)2P

2008 ◽  
Vol 57 (6) ◽  
pp. 3868
Author(s):  
Ma Chen-Yan ◽  
Cui Ming-Qi ◽  
Zhang Ling-Yun ◽  
Wu Xiang ◽  
Zhou Ke-Jin ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Electronic Structures ◽  
Edge Structure ◽  
X Ray ◽  
X Ray Absorption ◽  
Spectroscopy Research

scholarly journals Effect of thickness and Si substrate morphology in La0.7Sr0.3MnO3/Si thin films

2014 ◽  
Vol 70 (a1) ◽  
pp. C1532-C1532
Author(s):  
Hsiao-Tsu Wang ◽  
Mau- Kuen Wu ◽  
Yu-Cheng Shao ◽  
Yu-Fu Wang ◽  
Shang-Hsien Hsieh ◽  
...  
Keyword(s):  
Thin Films ◽  
Magnetic Properties ◽  
Electronic Structures ◽  
Magnetic Circular Dichroism ◽  
Magnetic Behavior ◽  
Si Substrate ◽  
Edge Structure ◽  
X Ray ◽  
X Ray Absorption ◽  
Different Thickness

Investigation has been made on atomic, electronic structures and magnetic properties of La0.7Sr0.3MnO3 (LSMO) on Si substrate. The effect of different thickness of LSMO and different morphological [flat and nano-pyramid (NP)] of Si substrate are studied in present work. The result of Mn K-edge extended x-ray absorption fine structure indicates the more disorder of local atomic structure of first shell (Mn-O bound) in the thinner LSMO/Si film. The Mn L3,2-edge x-ray absorption near-edge structure shows the presence of Mn2+ ion on the sample. Furthermore, the Mn L3,2-edge x-ray magnetic circular dichroism reveals that the thinner film (LSMO/Si) has highest magnetic moment, in comparison to that of thick LSMO/Si and LSMO/Si-NP samples. This finding suggests that the appearance Mn2+ may play an important role in magnetic behavior of hetero-junction LSMnO/Si and Si-NP.

Electronic structures of CdSe nanocrystals — An X-ray absorption near-edge structure (XANES) investigation

2007 ◽  
Vol 85 (10) ◽  
pp. 756-760 ◽  
Author(s):  
Jigang Zhou ◽  
Xingtai Zhou ◽  
Xuhui Sun ◽  
Michael Murphy ◽  
Franziskus Heigl ◽  
...  
Keyword(s):  
Electronic Structures ◽  
Quantum Confinement Effect ◽  
Chemical Properties ◽  
Trioctylphosphine Oxide ◽  
Cdse Nanocrystals ◽  
Edge Structure ◽  
X Ray ◽  
Vis Spectroscopy ◽  
Capping Ligands ◽  
X Ray Absorption

CdSe nanocrystals (NCs), capped with trioctylphosphine oxide and 1-octadecanamine, have been synthesized with colloidal methods. Both UV–vis absorption and photoluminescence spectra show that the prepared nanostructures exhibit a quantum confinement effect. X-ray absorption near–edge structure (XANES) at Se K-edge recorded in fluorescence yield mode have been carried out on these NCs, with different size and capping ligands to gain insight into how their electronic structures are affected by the NC size and chemical properties of the ligands. The results indicate that XANES are sensitive to both the NC size and the nature of the capping ligands. The whiteline intensity in XANES spectra can be related to the photoluminescence properties of these NCs.Key words: CdSe nanocrystals, capping ligands, X-ray absorption near-edge structure, UV–vis spectroscopy, photoluminescence.

Crystalline Phases and Electronic Structures in Superconducting Bi – Sr – Ca – Cu Oxides

1997 ◽  
Vol 12 (8) ◽  
pp. 2009-2013
Author(s):  
M. D. Giardina ◽  
R. Feduzi ◽  
D. Inzaghi ◽  
A. Manara ◽  
C. Giori ◽  
...  
Keyword(s):  
Microwave Absorption ◽  
Photoelectron Spectroscopy ◽  
Electronic Structures ◽  
Theoretical Interpretation ◽  
Nominal Composition ◽  
X Ray Diffraction ◽  
Edge Structure ◽  
X Ray ◽  
Quantum Percolation ◽  
X Ray Absorption

Two classes of samples, designated A and B, of layered Bi–Sr–Ca–Cu oxides having the same nominal composition 4 : 3 : 3 : 4, but different thermal histories, were investigated by using field modulated microwave absorption (ESR), powder x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), and x-ray absorption near the edge structure (XANES). Previous electrical resistivity measurements showed that the B samples presented only two superconducting phases with midpoints of the transition temperatures at ∼80 K and ∼105 K. The microwave absorption technique indicated instead the presence of islands which became superconducting at the above-mentioned temperatures also in the A samples. The crystalline and electronic structures of the two types of samples are illustrated and discussed. A plausible theoretical interpretation of the experimental results, based on a quantum percolation model with Coulomb interaction, is also given.

Ab Initio Study of Electronic and Magnetic Properties of GaSb/Mn and GaAs/Mn Digital Ferromagnetic Heterostructures

2009 ◽  
Vol 152-153 ◽  
pp. 533-536
Author(s):  
A. Titov ◽  
E.T. Kulatov ◽  
Y.A. Uspenskii ◽  
V.V. Tugushev ◽  
F. Michelini ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Electronic Structures ◽  
Wave Method ◽  
Ab Initio Study ◽  
Augmented Plane Wave ◽  
X Ray ◽  
Plane Wave Method ◽  
Electronic And Magnetic Properties ◽  
Augmented Plane Wave Method ◽  
X Ray Absorption

Electronic and magnetic properties of GaSb/Mn and GaAs/Mn digital heterostructures were studied using the augmented plane wave method. The calculated electronic structures of GaSb/Mn and GaAs/Mn are similar. A pre-edge absorption line at 6541 eV should be observed in Mn K-edge x-ray absorption spectra of the heterostructures. This line can be used to study the spatial distribution of Mn in layers. The energy of exchange interaction between two Mn layers was calculated as a function of interlayer separation. Different dependencies of the exchange energy are found for GaSb/Mn and GaAs/Mn heterostructures.

ELECTRONIC STRUCTURES OF La0.7Ca0.3MnO3 AND La0.7Ce0.3MnO3 BY X-RAY ABSORPTION SPECTROSCOPY

2002 ◽  
Vol 09 (02) ◽  
pp. 1053-1057 ◽  
Author(s):  
K. ASOKAN ◽  
K. V. R. RAO ◽  
J. C. JAN ◽  
J. W. CHIOU ◽  
W. F. PONG ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Electronic Structures ◽  
Spectral Features ◽  
Electron Hole ◽  
Edge Structure ◽  
X Ray ◽  
Strong Hybridization ◽  
Doped Manganites ◽  
X Ray Absorption ◽  
Tetravalent State

Electronic structures of hole-doped and electron hole-doped manganites, La 0.7 Ca 0.3 MnO 3 and La 0.7 Ce 0.3 MnO 3, have been elucidated by X-ray absorption near-edge structure (XANES) spectra of O K- and Mn L3,2-edges. In the electron-doped system, La 0.7 Ce 0.3 MnO 3, the spectral features of O K-edge spectra are shifted by ~ 1 eV towards the higher energy side and reduction of Mn valency from 4+ and 3+ to 3+ and 2+ is expected when compared to hole-doped manganite. The XANES of Ce M5,4-edges indicates a tetravalent state for Ce, similar to that in CeO 2. Ce 4+ is incorporated into the lattice of LaMnO 3, resulting in the modification of MnO 6 octahedra and also indicating strong hybridization of Ce 5d and/or Ce 4f states with O 2p states.

Study of MgXZn1-XO Alloys (0

2013 ◽  
Vol 663 ◽  
pp. 361-365 ◽  
Author(s):  
Wei Zheng ◽  
Zhe Chuan Feng ◽  
Fan Hsiu Chang ◽  
Jyh Fu Lee ◽  
Rui Sheng Zheng ◽  
...  
Keyword(s):  
Fine Structure ◽  
High Resolution ◽  
Detailed Analysis ◽  
Absorption Spectroscopy ◽  
Electronic Structures ◽  
Chemical Bonds ◽  
Absorption Data ◽  
Edge Structure ◽  
X Ray ◽  
X Ray Absorption

High-resolution K-edge x-ray absorption data are presented for Mg, Zn and O of Mg1-xZnxO films. A detailed analysis of the extended x-ray absorption fine structure by using the IFEFFIT program is given, and the Zn form chemical bonds with O are obtained. The x-ray absorption near-edge structure of Mg, Zn and O K-edge are investigated, and the electronic structures of Mg1-xZnxO with various compositions are studied.

Magnetic Circular Dichroism And X-Ray Absorption Near Edge Structure Studies Of Magnetoresistive Oxides

1996 ◽  
Vol 437 ◽  
Author(s):  
S. M. Mini ◽  
John Mitchell ◽  
D. G. Hinks ◽  
C. W. Kimball ◽  
P. A. Montano ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Circular Dichroism ◽  
Magnetic Circular Dichroism ◽  
Oxide Systems ◽  
Edge Structure ◽  
X Ray ◽  
Mn Oxide ◽  
X Ray Absorption ◽  
Circular Dichroïsm ◽  
Electronic And Structural Properties

AbstractWe report the results of temperature dependent, Mn K-edge X-ray Absorption measurements: Magnetic X-ray Circular Dichroism (MXCD) for local magnetic properties and X-ray Absorption Near Edge (XANES) for electronic and structural properties of Mn-based oxide magnetoresistive compounds La1−xSrxMnO3. This is the first report of an MXCD signal of the Mn K-edge in Mn oxide systems. By studying the integrated peak intensity of the first peak in the MXCD signal, it can be determined that the magnetic properties of the system are independent of temperature in the range 94 to 223K.

Determination of Bond Lengths and Electronic Structure of Cd1-xZnxTe Ternary Alloys by Synchrotron Radiation

2013 ◽  
Vol 706-708 ◽  
pp. 56-59 ◽  
Author(s):  
Wei Zheng ◽  
Yu Li Wu ◽  
Yen Ting Chen ◽  
Zhe Chuan Feng ◽  
Jyh Fu Lee ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Fine Structure ◽  
Synchrotron Radiation ◽  
Electronic Structures ◽  
Ternary Alloys ◽  
Chemical Bonds ◽  
Edge Structure ◽  
X Ray ◽  
X Ray Absorption

High-resolution synchrotron radiation x-ray absorption spectroscopy on Zn K-, Cd L3- and Te L3-edges for Cd1-xZnxTe ternary alloys with x = 0.10, 0.30, 0.50 and 0.90 are presented. A detailed analysis of the extended x-ray absorption fine structure using the IFEFFIT program, and the chemical bonds of Zn-Te are obtained, suggesting distortion of the Te sub-lattice. The x-ray absorption near-edge structure of the Zn K-, Cd L3- and Te L3-edge are investigated, and the electronic structures of Cd1-xZnxTe with various compositions are studied.

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