scholarly journals Green Glauconitic Marl Bed As A Sequence Stratigraphical Key For Interpretation Of Contact Between Qamchuqa And Bekhme Formations In Bekhal Area, Kurdistan Region, NE Iraq

2020 ◽  
Vol 70 (1) ◽  
pp. 29-38
Author(s):  
Mohammad Sadi Nourmohamadi ◽  
◽  
Rzger A. Abdula ◽  
Fawzi Albeyati ◽  
Arkan O. Sharezwri ◽  
...  

This study incorporates a study of stratigraphy and sedimentology of the green glauconitic marl bed between Qamchuqa and Bekhme Formations in selected section of the Iraqi Kurdistan region. The studied area is located in Gali Garukaju near Rwanduz in Erbil Governorate, northeastern Iraq. Instead of Basal Conglomerate bed, the thin beds of green glauconitic marl occurs along the contact between Qamchuqa and Bekhme Formations in the studied section. Six samples were collected from this section, two samples for XRD and four samples for petrography analysis. Samples for XRD and petrographic analysis were taken from green glauconitic marl beds at the contact between two formations and from upper contact of Qamchuqa Formation and lower contact of Bekhme Formation. XRD analysis data proved the presence of glauconite in green marl bed. General petrographic observations of other remaining four samples in thin sections reveal that the upper contact of Qamchuqa Formation and lower contact of Bekhme Formation are dolomite and dolomitic limestone. The dolomite bed represents type 1 or type 2 depending on the thickness and extension of dolomite bed. Color, morphology, maturity and abundance of glauconite grain were the dominant factors used in the determination of the surface between the two formations. The result emphasizes that the surface was not a gradational surface consisting of low stand and condensed system tract (LST/CS). Two factors, color and morphology, of glauconite grains were analyzed by binocular microscope under reflected light. The morphology of most glauconite grains in this section is ovoidal and tabular with green to dark green in color. Based on these two factors the glauconite grains were within stages 3 and 4 of McCracken et al. (1996) classification and can be interpreted as evolved and high evolved in view of maturity. The presence, increase in concentration and mature grains of glauconite (evolved and high evolved) in marl beds at lower part of Bekhme Formation indicate transgressive or maximum flooding surfaces.

2021 ◽  
Author(s):  
Irfan Sh. Asaad ◽  

Lithostratigraphy and microfacies analysis of the Avanah Formation (Middle Eocene) were studied in the Gomaspan section in the Bina Bawi anticline, northeast of Erbil city, Kurdistan Region, Iraq. The field observations refer that the formation attains 56 m of medium to thick bedded yellow limestone, grey dolomitic limestone and blue marly dolomitic limestone interbedded with thin beds of blue marl and dark grey shale with an interval of sandy limestone in the middle part and thin to medium bedded limestone interbedded with red mudstone. The petrographic study of 29 thin sections of Avanah carbonates revealed that the majority of the matrix is carbonate mud (micrite) with few microspar. The skeletal grains include benthic foraminifera, dasycladacean green algae, ostracods, calcispheres, pelecypods, rare planktonic foraminifera and bryozoa in addition to bioclasts. Non-skeletal grains encompass peloids, oncoids, intraclasts and extraclasts with common monocrystalline quartz. Based on the field observation and petrographic analysis, three different lithostratigraphic units were identified. They are in ascending order: A-Thick bedded dolomitic marly limestone interbedded with shale. B- Bedded dolomitic limestone interbedded with shale and marl. C- Thin to medium bedded limestone interbedded with red mudstone. Depending on detailed microfacies analysis of carbonate rocks, three main microfacies and 12 submicrofacies are recognized. From the sum of all petrographic, facies, textural analyses, it is concluded that Avanah Formation in Gomaspan section, was deposited in shallow marine environment, semi restricted lagoon, in lower and upper parts and open lagoon environment in the middle part interval.


2021 ◽  
Author(s):  
Irfan Sh. Asaad ◽  

Lithostratigraphy and microfacies analysis of the Avanah Formation (Middle Eocene) were studied in the Gomaspan section in the Bina Bawi anticline, northeast of Erbil city, Kurdistan Region, Iraq. The field observations refer that the formation attains 56 m of medium to thick bedded yellow limestone, grey dolomitic limestone and blue marly dolomitic limestone interbedded with thin beds of blue marl and dark grey shale with an interval of sandy limestone in the middle part and thin to medium bedded limestone interbedded with red mudstone. The petrographic study of 29 thin sections of Avanah carbonates revealed that the majority of the matrix is carbonate mud (micrite) with few microspar. The skeletal grains include benthic foraminifera, dasycladacean green algae, ostracods, calcispheres, pelecypods, rare planktonic foraminifera and bryozoa in addition to bioclasts. Non-skeletal grains encompass peloids, oncoids, intraclasts and extraclasts with common monocrystalline quartz. Based on the field observation and petrographic analysis, three different lithostratigraphic units were identified. They are in ascending order: A-Thick bedded dolomitic marly limestone interbedded with shale. B- Bedded interbedded with red mudstone. Depending on detailed microfacies analysis of carbonate rocks, three main microfacies and 12 submicrofacies are recognized. From the sum of all petrographic, facies, textural analyses, it is concluded that Avanah Formation in Gomaspan section, was deposited in shallow marine environment, semi restricted lagoon, in lower and upper parts and open lagoon environment in the middle part interval.


Geosciences ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 36
Author(s):  
Vayia Xanthopoulou ◽  
Ioannis Iliopoulos ◽  
Ioannis Liritzis

The present study deals with the characterization of a ceramic assemblage from the Late Mycenaean (Late Helladic III) settlement of Kastrouli, at Desfina near Delphi, Central Greece using various analytical techniques. Kastrouli is located in a strategic position supervising the Mesokampos plateau and the entire peninsula and is related to other nearby coeval settlements. In total 40 ceramic sherds and 8 clay raw materials were analyzed through mineralogical, petrographic and microstructural techniques. Experimental briquettes (DS) made from clayey raw materials collected in the vicinity of Kastrouli, were fired under temperatures (900 and 1050 °C) in oxidizing conditions for comparison with the ancient ceramics. The petrographic analysis performed on thin sections prepared from the sherds has permitted the identification of six main fabric groups and a couple of loners. The aplastic inclusions recognized in all fabric groups but one confirmed the local provenance since they are related to the local geology. Fresh fractures of representative sherds were further examined under a scanning electron microscope (SEM/EDS) helping us to classify them into calcareous (CaO > 6%) and non-calcareous (CaO < 6%) samples (low and high calcium was noted in earlier pXRF data). Here, the ceramic sherds with broad calcium separation are explored on a one-to-one comparison on the basis of detailed mineralogical microstructure. Moreover, their microstructure was studied, aiming to estimate their vitrification stage. The mineralogy of all studied samples was determined by means of X-ray powder diffraction (XRPD), permitting us to test the validity of the firing temperatures revealed by the SEM analysis. The results obtained through the various analytical techniques employed are jointly assessed in order to reveal potters’ technological choices.


2005 ◽  
Vol 903 ◽  
Author(s):  
Victor A. Golubev ◽  
Andrey V. Strikanov ◽  
Grigory A. Potemkin ◽  
Ludmila V. Zueva ◽  
Aleksey V. Golubev ◽  
...  

AbstractThe Dynamic Compacting (DC) method is promising method to produce considerable-size nonporous wares. The phenomenon is based on the impact of shock wave on the initial powders of amorphous alloys. Every time when the shock wave propagates through the bulk of substance then the temperature rises substantially. Therefore there is a need of study of the DC’s effect on the structure and properties of the amorphous alloys. The results of the thermal analysis (in particular, Differential Scanning Calorimetry) of the samples of the soft magnetic alloys are presented in the report. These results concern with amorphous alloys of 5BDSR, GM414, 10NSR trademarks before DC and after DC, respectively. It is shown there is single low-temperature endothermic peak (near 300C) and there are several high temperature exothermic peaks (near 540C, 650C, and 700C). The first peak is related to glass-transition, the following peaks are related to formation of nano-crystalline phases. It was proved by XRD analysis data. The optimal regimes of the thermal processing of final wares were chosen on the base of thermal- and XRD-analysis. The study of the effects of these regimes on the properties (magnetic conductivity, specific losses etc.) of the circular magnetic conductors was executed. In particular, thermal- as well as thermo-magnetic processing of magnetic conductors based on 5BDSR amorphous alloy (after DC) essentially improves their magnetic properties. For example, magnetic conductivity fÝ increases approximately by factor 17 with respect to the magnitude before DC.


2018 ◽  
Vol 484 (1) ◽  
pp. 189-204 ◽  
Author(s):  
R. H. Worden ◽  
James E. P. Utley ◽  
Alan R. Butcher ◽  
J. Griffiths ◽  
L. J. Wooldridge ◽  
...  

AbstractChlorite is a key mineral in the control of reservoir quality in many siliciclastic rocks. In deeply buried reservoirs, chlorite coats on sand grains prevent the growth of quartz cements and lead to anomalously good reservoir quality. By contrast, an excess of chlorite – for example, in clay-rich siltstone and sandstone – leads to blocked pore throats and very low permeability. Determining which compositional type is present, how it occurs spatially, and quantifying the many and varied habits of chlorite that are of commercial importance remains a challenge. With the advent of automated techniques based on scanning electron microscopy (SEM), it is possible to provide instant phase identification and mapping of entire thin sections of rock. The resulting quantitative mineralogy and rock fabric data can be compared with well logs and core analysis data. We present here a completely novel Quantitative Evaluation of Minerals by SCANning electron microscopy (QEMSCAN®) SEM–energy-dispersive spectrometry (EDS) methodology to differentiate, quantify and image 11 different compositional types of chlorite based on Fe : Mg ratios using thin sections of rocks and grain mounts of cuttings or loose sediment. No other analytical technique, or combination of techniques, is capable of easily quantifying and imaging different compositional types of chlorite. Here we present examples of chlorite from seven different geological settings analysed using QEMSCAN® SEM–EDS. By illustrating the reliability of identification under automated analysis, and the ability to capture realistic textures in a fully digital format, we can clearly visualize the various forms of chlorite. This new approach has led to the creation of a digital chlorite library, in which we have co-registered optical and SEM-based images, and validated the mineral identification with complimentary techniques such as X-ray diffraction. This new methodology will be of interest and use to all those concerned with the identification and formation of chlorite in sandstones and the effects that diagenetic chlorite growth may have had on reservoir quality. The same approach may be adopted for other minerals (e.g. carbonates) with major element compositional variability that may influence the porosity and permeability of sandstone reservoirs.


2017 ◽  
Vol 14 (6) ◽  
pp. 1721-1737 ◽  
Author(s):  
Liza M. Roger ◽  
Annette D. George ◽  
Jeremy Shaw ◽  
Robert D. Hart ◽  
Malcolm Roberts ◽  
...  

Abstract. The shells of two marine bivalve species (Fulvia tenuicostata and Soletellina biradiata) endemic to south Western Australia have been characterised using a combined crystallographic, spectroscopic and geochemical approach. Both species have been described previously as purely aragonitic; however, this study identified the presence of three phases, namely aragonite, calcite and Mg-calcite, using XRD analysis. Data obtained via confocal Raman spectroscopy, electron probe microanalysis and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) show correlations between Mg ∕ S and Mg ∕ P in F. tenuicostata and between Sr ∕ S and S ∕ Ba in S. biradiata. The composition of the organic macromolecules that constitute the shell organic matrix (i.e. the soluble phosphorus-dominated and/or insoluble sulfur-dominated fraction) influences the incorporation of Mg, Sr and Ba into the crystal lattice. Ionic substitution, particularly Ca2+ by Mg2+ in calcite in F. tenuicostata, appears to have been promoted by the combination of both S- and P-dominated organic macromolecules. The elemental composition of these two marine bivalve shells is species specific and influenced by many factors, such as crystallographic structure, organic macromolecule composition and environmental setting. In order to reliably use bivalve shells as proxies for paleoenvironmental reconstructions, both the organic and inorganic crystalline material need to be characterised to account for all influencing factors and accurately describe the vital effect.


2020 ◽  
pp. 003329412095030
Author(s):  
Jui-Chen Peng ◽  
Shou-Wei Chen

This study proposes and tests a multilevel mediation framework to explicate the processes that link servant leadership to frontline employees’ service performance at both the employee and the branch levels of analysis. Data were obtained from 58 branch managers and 324 branch frontline employees of a chain restaurant in Taiwan. The results of hierarchical linear modelling indicate that two factors, concern climate and work engagement, mediate the relationship between branch managers’ servant leadership and frontline employees’ service performance; and that work engagement mediates the relationship between concern climate and such service performance. The theoretical and practical implications of these findings are considered, along with future research directions and the study’s limitations.


1992 ◽  
Vol 6 ◽  
pp. 269-269
Author(s):  
William J. Showers ◽  
Bernard Genna ◽  
Reese E. Barrick ◽  
Alfred G. Fischer

A new method for the preparation of bone samples for δ18O-PO4 analysis has been developed. The phosphate from bone samples is separated and purified using ion exchange chromatography, and then precipitated as silver phosphate using the Firsching method. O2 is then extracted by reaction with bromine pentafluoride and converted to CO2 for isotopic analysis. Advantages of the silver phosphate technique over the bismuth phosphate technique are (1) the simplicity of the method, (2) silver phosphate is not hygroscopic so atmospheric water is not an oxygen contaminate, and (3) very small samples (2 mg to 10 mg) can be analyzed with an increase of precision compared to previous techniques. Iron and silica oxides added to Ag3PO4 standards produce no offset, which suggests that this new technique is not sensitive to interferences from cements commonly found in fossil bone material. Analyses have been performed on standards ranging in size from 30 mg to 2 mg with a σ1 of ± 0.05 per mil.The δ18O-PO4 compositional pattern of the bones of modern vertebrates have been analyzed to provide a base for the interpretation of the δ18O-PO4 pattern of fossil vertebrates. The average %PO4 in modern mammals and reptiles is approximately 15% with a σ1 of 2-3 %. The average %PO4 of fossil reptiles range from 10 to 25% with σ1 variations of up to 10%. The %PO4 variation can be related to cementation of void spaces in the bone material. XRD analysis reveals that calcite, dolomite, ankerite, and silica cements are commonly present. FTIR (Fourier Transform Infrared Spectroscopy) yields low indices calculated according to the formula of Shemesh, 1990 [GCA 54(9):2433]. Thin sections of the fossil bone material show detailed structures. All this evidence suggests that the fossil bone δ18O-PO4 composition is pristine and not altered by diagenesis. The total δ18O-PO4 σ1 variation of 10 or more skeletal elements analyzed for each individual specimen varies from 0.1 per mil for a domestic cow (Bos) to 0.8 per mil for a Komodo dragon (Varanus). Variations in between appear to be related to thermal physiology and variations in drinking water δ18O due to seasonality or migration.


2018 ◽  
Vol 6 (3) ◽  
pp. T723-T737
Author(s):  
Tao Nian ◽  
Zaixing Jiang ◽  
Hongyu Song

Electrical borehole image logs have the potential for direct interpretation of lithofacies characteristics. The challenge is to establish a set of reliable diagnostic criteria with which electrical images can be correlated to lithofacies features such as lithology, sedimentary structures, and bedding sequences. We used the “behind-outcrop” logging procedure that can link borehole images to actual rocks and also reduce errors that are associated with core-shift process. To better reveal the correlation between borehole images and carbonate lithofacies for subsurface reservoir applications, and also make a comparative petrographic analysis with the aim of establishing diagnostic criteria for borehole images, a 200 m well was drilled in the Tarim Ordovician outcrop. A full set of borehole image data and cores with approximately 100% coring recovery rate was acquired at the same depth interval, and more than 100 stained thin sections were prepared. Electrical borehole images in wells adjacent to the outcrop were further interpreted to validate the proposed criteria. Borehole image electrofacies were established according to the image elements, such as stacked mode, bed thickness, conglomerate diameter, rim characteristics, and internal structure of bed/conglomerate, to interpret depositional/diagenetic textures and platform-slope associations. Nine image electrofacies types, corresponding to mud/wacke/pack/grain/bindstone texture, were identified and interpreted in detail. Our method reveals a set of diagnostic criteria for borehole image interpretation in carbonate platform slope, and it finally provides a powerful tool for direct interpretation of electrical images in similar reservoir environment.


2005 ◽  
Vol 96 (3) ◽  
pp. 595-602 ◽  
Author(s):  
Jo Ann Lee ◽  
Chulguen Yang

The current study compared the factor structures of the construct of organizational commitment between two samples of financial employees, one from the U.S. ( n = 103) and one from South Korea ( n = 109). Participants completed a 26-item questionnaire. Two factors (an affective component and a normative component) emerged for the U.S. sample; only one factor for the Koreans. Results suggest that culture should be considered when trying to assess organizational commitment.


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