scholarly journals Ultrasonic Processing of Si and SiGe for Photovoltaic Applications

2021 ◽  
Author(s):  
Andriy Nadtochiy ◽  
Artem Podolian ◽  
Oleg Korotchenkov ◽  
Viktor Schlosser

The usage of power ultrasound for sonochemical processing of Si wafers and thin layers of amorphous Si and SiGe alloys is described. Over the last decade different industries have become increasingly drawn to sonochemistry because it provides a green and clean alternative to conventional technologies, particular in the areas of processing of silicon-based materials for photovoltaic applications. Two techniques related to ultrasonic cleaning of Si wafers and sonochemical modification of Si, SiGe and a-Si/SiGe surfaces in hydrocarbon solutions of chloroform (CHCl3) and dichloromethane (CH2Cl2) are discussed. The occurrence of cavitation and bubble implosion is an indispensable prerequisite for ultrasonic cleaning and surface processing as it is known today. The use of higher ultrasonic frequencies to expand the range of ultrasonic cleaning and processing capabilities is emphasized. Although exact mechanisms of an improved photoelectric behavior of Si-based structures subjected to power ultrasound are not yet clarified in many cases, the likely scenarios behind the observed photovoltaic performances of Si, SiGe and a-Si/SiGe surfaces are proposed to involve the surface chemistry of oxygen and hydrogen molecules as well hydrocarbon chains.

Nano Energy ◽  
2021 ◽  
pp. 106861
Author(s):  
Stuart Ferrie ◽  
Anton P. Le Brun ◽  
Gowri Krishnan ◽  
Gunther Anderson ◽  
Nadim Darwish ◽  
...  

2004 ◽  
Vol 808 ◽  
Author(s):  
Rajeewa R. Arya

ABSTRACTAdvances in amorphous silicon solar cell and module development over the past two decades has led to widespread commercial application in consumer and building integrated photovoltaic applications (BIPV). The technology has taken two pathways: (i) superstrate and (ii) substrate. Both pathways have unique advantages over crystalline modules and have demonstrated promising stability and reliability with continuous improvement in performance. Multi-junction modules with amorphous and microcrystalline silicon have demonstrated initial conversion efficiencies in the range of 13%-13.5%.


1995 ◽  
Vol 414 ◽  
Author(s):  
S. Seal ◽  
S. Krezoski ◽  
T. L. Barr ◽  
D. H. Petering

AbstractSiliceous materials are the principal components of Earth's crust and also have become key ingredients of modem technology. Recently, we have expanded our chemical characterization of complex silicates (e.g., framework [1] and sheet types [2]) to include studies of their interaction with select biocells [3,4]. It is becoming apparent that the surface chemistry of these silicates, and perhaps that of silica itself, plays a key role in the oft resulting cell pathogenesis, thus enhancing the value of further investigations with X-ray photoelectron spectroscopy. The present research describes the unique growth of Ehrlich (murine or rat tumor) cells on Sio and SiO2 wafers, and also on select seaentine silicates (such as chrysotile asbestos). Tbese growth studies were followed by both cell/silicate separations and unique freeze drying [3,4]. XPS examination at select stages discovered cell induced alterations in the Si, O, Mg and particularly Fe chemistry of the silicon based systems as well as corresponding changes in the cell chemistry. Many of these features were confirmed by atomic absorption spectroscopy.


2015 ◽  
Vol 26 (5) ◽  
pp. 3336-3343 ◽  
Author(s):  
H. Mahdhi ◽  
Z. Ben Ayadi ◽  
J. L. Gauffier ◽  
K. Djessas ◽  
S. Alaya

2013 ◽  
Author(s):  
Florian Ruske ◽  
Robert Rößler ◽  
Mark Wimmer ◽  
Steffi Schönau ◽  
Stefan Kämpfer ◽  
...  

2015 ◽  
Vol 17 (15) ◽  
pp. 10004-10013 ◽  
Author(s):  
Maciej Krzywiecki ◽  
Lucyna Grządziel ◽  
Adnan Sarfraz ◽  
Danish Iqbal ◽  
Anna Szwajca ◽  
...  

In the present work we determine the electronic structure and quantify composition of sol–gel synthesized oxygen-deficient ZnO thin layers.


2011 ◽  
Vol 1313 ◽  
Author(s):  
David Munao ◽  
Mario Valvo ◽  
Jan van Erven ◽  
Esteban Garcia-Tamayo ◽  
Erik Kelder

ABSTRACTIn this work novel approaches to fabricate silicon-based electrodes are shown. Starting from silicon nano-particles it is possible to create nano-structured porous thin films. Both the synthesis of the Si nano-particles and the electrode assembly are performed via aerosol routes. This guarantees a very good control on the particle size and the particle size distribution, on the purity of the product and on the morphology and texture of the deposited layers. Particles are produced via Laser assisted Chemical Vapor Pyrolysis whereas electrode thin layers are deposited via Electro Spray method. The range of particle sizes can be tailored according to the selected application. Here, particles of a mean size of about 10 nm have been synthesized. Since Si is well known to forms highly lithiated intermetallic compounds [1], it is regarded as one of the most promising material for energy storage [2], especially looking at high energy density applications, such as hybrid/electric vehicle traction. In this work its promising performance are presented. The role of the additives in the composite formulation is also taken into account for a more clear understanding of the capacity fading mechanism of such electrodes.


Author(s):  
Viet Phuong Pham

The induced contaminations (e.g polymer residues or impurities in air) on nanomaterial surfaces have been a serious problem to probe their intrinsic properties and for unique applications in surface chemistry, electronic, and optoelectronic. The polymer residues still presented on chemical vapor deposited graphene surface after its wet transfer (e.g. poly(methyl methacrylate) (PMMA)) on the arbitrary substrates tends to cause problems such as electrical degradation and unwanted intentional doping. Polymer residues (e.g PMMA), defects, and other contaminations are commonly leaving the thin layers or the particles as residues on nanomaterials.


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