scholarly journals Experimental and Theoretical Study of the Adsorption Behavior of Nitrate Ions by Layered Double Hydroxide Using Impedance Spectroscopy

2020 ◽  
Author(s):  
Abderrahmane Elmelouky ◽  
Abdelhadi Mortadi ◽  
Elghaouti Chahid ◽  
Reddad Elmoznine
Keyword(s):  
Experimental Data ◽  
Impedance Spectroscopy ◽  
Layered Double Hydroxide ◽  
Electrochemical Impedance ◽  
Electrical Response ◽  
Second Order ◽  
Nitrate Ions ◽  
Pseudo Second Order ◽  
Highly Correlated ◽  
Double Hydroxide

This chapter analyzes the experimental data using impedance spectroscopy to reduce water pollution by nitrate ions. The adsorption is through a synthesized layered double hydroxide (Zn3-Al-Cl-LDH). The kinetic study data analysis by pseudo-first-order and pseudo-second-order models is highly correlated they were found to fit very well the pseudo-second-order. This is confirmed by fast kinetic modeling of experimental data according to the pseudo-second-order. Furthermore, the Nyquist plots suggest that the grains and grain boundaries have contributed to the conduction mechanism of the material at different adsorption times and monitoring of the adsorption phenomenon. The investigation by impedance spectroscopy was used for modeling by an equivalent circuit. The real and imaginary functions of impedance complex are analyzed by modifying Cole-Cole relaxation. Revel most changes in the structure of the manifestation of the grains and the grains boundaries. The alternative current (AC) conductivity was investigated using the double power law of Jonscher. More importantly, the calculated value and the percentage of efficiency are evaluated in the adsorption. The water molecules and nitrate ions in the adsorbed were favored for the generation of the electrical response. The electrochemical impedance spectroscopy data are often interpreted by using electrical equivalent circuits.

scholarly journals Itaconic acid-modified layered double hydroxide as a ‎novel adsorbent for effective removal of Congo red from aqueous solutions

2021 ◽  
Author(s):  
Mohammad Dinari ◽  
Shirin Shabani
Keyword(s):  
Layered Double Hydroxide ◽  
Itaconic Acid ◽  
Congo Red ◽  
Aqueous Media ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Order Kinetic ◽  
Solution Ph ◽  
Pseudo Second Order ◽  
Double Hydroxide

Abstract Herein, we report the synthesis of Cu-Ca-Al/NO3-based layered double hydroxide through co-precipitation methodology. The prepared layered double hydroxide was then modified with itaconic acid. The physicochemical properties of the prepared materials were studied using Fourier transform-infrared spectroscopy, scanning electron microscopy, X-ray diffraction analysis, thermogravimetric analysis, and nitrogen adsorption/desorption technique. The prepared materials were then applied as novel adsorbents for the removal of Congo red as a model of an anionic dye from aqueous media. To reach maximum adsorption, the effect of parameters including sample solution pH, adsorbent amount, contact time, and initial concentration of Congo red on the adsorption process was investigated. Kinetic studies were also conducted to study the mechanism of adsorption. In this regard, the kinetic models of pseudo-first-order, pseudo-second-order, Elovich, and intra-particle diffusion were studied. The results showed that the adsorption of Congo red onto Cu-Ca-Al-LDH and LDH-ITA adsorbents followed the pseudo-second-order kinetic model. To evaluate the equilibrium adsorption data, different isotherms including Langmuir, Freundlich, and Dubinin-Radushkevich were also applied. The data revealed that the Freundlich isotherm provided the best fit with the equilibrium data of both adsorbents. Maximum adsorption capacities of 81 and 84 mg g− 1 were obtained using Cu-Ca-Al-LDH and LDH-ITA adsorbents, respectively.

scholarly journals Photodegradation of Rhodamine B using Cd-Al/C double layered hydroxide catalyst

2020 ◽  
Vol 12 (1) ◽  
pp. 24-30
Author(s):  
A.S. Muhammad ◽  
F.A. Garzali
Keyword(s):  
Visible Light ◽  
Layered Double Hydroxide ◽  
Rhodamine B ◽  
Second Order ◽  
Aluminium Chloride ◽  
Order Kinetic ◽  
Pseudo Second Order ◽  
Good Catalytic Activity ◽  
Double Hydroxide ◽  
Double Layered Hydroxide

This paper presents the degradation of Rhodamine B using cadmium aluminium carbon (Cd-Al/C) catalyst under visible light. The layered double hydroxide was successfully prepared from cadmium fluoride (CdF2), aluminium chloride (AlCl3), and rice husks activated carbon, and then characterized by X-ray Diffaraction (XRD) Scaning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) methods. The peaks at 2Ө 23.4 and 35.5 in the XRD result confirmed the presences of LDH. The effect of contact time, catalyst dosage, pH and initial concentration, on the photo degradiation of Rhodamine B were investigated. The experimental results showed that after 100min visible light irradiation, the percentage degradation using 200mg Cd-Al/C, pH 7 and 3ppm Rhodamine B concentration reached to 76.22%.  For kinetics studies the data obtained were analysed using pseudo first order and pseudo second order kinetic models. From the linear regression coefficient values the data were found to be best fitted to pseudo second order kinetics. The results revealed that the Cd-Al/C show good catalytic activity. Key words: Layered Double Hydroxide (LDH) Cadnium fluoride, Aluminium Chloride and Rhodamine B.

scholarly journals Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto Fe3O4@Mg2Al-NO3 Layered Double Hydroxide in aqueous solution

2017 ◽  
Vol 36 (1-2) ◽  
pp. 669-683 ◽  
Author(s):  
Ling-Xi Zhao ◽  
Ming-Chao Jiang ◽  
Ling-Yu Luan ◽  
Qing Li ◽  
Jing Zhang
Keyword(s):  
Experimental Data ◽  
Power Function ◽  
Layered Double Hydroxide ◽  
Equilibrium Adsorption ◽  
Metastable Equilibrium ◽  
Function Model ◽  
Adsorption Models ◽  
Surface Component ◽  
Double Hydroxide ◽  
Activity Equation

The adsorption of Pb(II) and Cu(II) onto Fe3O4@Mg2Al-NO3 Layered Double Hydroxide (LDH) as a function of Fe3O4@Mg2Al-NO3 LDH concentration was studied. An adsorbent concentration effect ( Cs effect), namely adsorption isotherm declines as adsorbent concentration ( Cs) increases, was observed. The experimental data were fitted to the adsorption models including the classic Freundlich model, the metastable-equilibrium adsorption theory, the flocculation model, the power function model, and the surface component activity model. The results show that the Freundlich-type metastable-equilibrium adsorption equation, the power function model, and the Freundlich-surface component activity equation can adequately describe the Cs effect observed in the batch adsorption tests as all the correlation coefficients ( R2) of the nonlinear plots are higher than 0.96. In other words, their intrinsic parameters simulated from the experimental data are independent of Cs value. It is considered that the Freundlich-surface component activity equation is the best model to describe the Cs effect of the studied adsorption systems by Akaike Information Criterion evaluation criterion.

scholarly journals Harnessing of Newly Tailored Poly (Acrylonitrile)-Starch Nanoparticle Graft Copolymer for Copper Ion Removal via Oximation Reaction

2021 ◽  
Author(s):  
khaled Mostafa ◽  
H. Ameen ◽  
A. Ebessy ◽  
A. El-Sanabary
Keyword(s):  
Experimental Data ◽  
Adsorption Capacity ◽  
Graft Copolymer ◽  
Adsorption Kinetics ◽  
Copper Ions ◽  
Copper Ion ◽  
Second Order ◽  
First Order ◽  
Pseudo Second Order ◽  
Pseudo First Order

Abstract Our recently tailored and fully characterized poly (AN)-starch nanoparticle graft copolymer having 60.1 G.Y. % was used as a starting substrate for copper ions removal from waste water effluent after chemical modification with hydroxyl amine via oximation reaction. This was done to change the abundant nitrile groups in the above copolymer into amidoxime one and the resultant poly (amidoxime) resin was used as adsorbent for copper ions. The resin was characterized qualitatively via rapid vanadium ion test and instrumentally by FT-IR spectra and SEM morphological analysis to confirm the presence of amidoxime groups. The adsorption capacity of the resin was done using the batch technique, whereas the residual copper ions content in the filtrate before and after adsorption was measured using atomic adsorption spectrometry. It was found that the maximum adsorption capacity of poly (amidoxime) resin was 115.2 mg/g at pH 7, 400ppm copper ions concentration and 0.25 g adsorbent at room temperature. The adsorption, kinetics and isothermal study of the process is scrutinized using different variables, such as pH, contact time, copper ion concentration and adsorbent dosage. Different kinetics models comprising the pseudo-first-order and pseudo-second-order have been applied to the experimental data to envisage the adsorption kinetics. It was found from kinetic study that pseudo-second-order rate equation was better than pseudo-first-order supporting the formation of chemisorption process. While, in case of isothermal study, the examination of calculated correlation coefficient (R2) values showed that the Langmuir model provide the best fit to experimental data than Freundlich one.

scholarly journals Characterization of Glass-Ceramic Sealant for Solid Oxide Fuel Cells at Operating Conditions by Electrochemical Impedance Spectroscopy

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4702
Author(s):  
Roberto Spotorno ◽  
Marlena Ostrowska ◽  
Simona Delsante ◽  
Ulf Dahlmann ◽  
Paolo Piccardo
Keyword(s):  
Fuel Cells ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Solid Oxide Fuel Cells ◽  
Glass Ceramic ◽  
Electrochemical Impedance ◽  
Electrical Response ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
X Ray

A commercially available glass-ceramic composition is applied on a ferritic stainless steel (FSS) substrate reproducing a type of interface present in solid oxide fuel cells (SOFCs) stacks. Electrochemical impedance spectroscopy (EIS) is used to study the electrical response of the assembly in the temperature range of 380–780 °C and during aging for 250 h at 780 °C. Post-experiment analyses, performed by means of X-ray diffraction (XRD), and along cross-sections by scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis, highlight the microstructural changes promoted by aging conditions over time. In particular, progressive crystallization of the glass-ceramic, high temperature corrosion of the substrate and diffusion of Fe and Cr ions from the FSS substrate into the sealant influence the electrical response of the system under investigation. The electrical measurements show an increase in conductivity to 5 × 10−6 S∙cm−1, more than one order of magnitude below the maximum recommended value.

scholarly journals Ion Exchange of Benzoate in Ni-Al-Benzoate Layered Double Hydroxide by Amoxicillin

2019 ◽  
Vol 17 (1) ◽  
pp. 1043-1049
Author(s):  
Dian Windy Dwiasi ◽  
Mudasir Mudasir ◽  
Roto Roto
Keyword(s):  
Ion Exchange ◽  
Anion Exchange ◽  
Layered Double Hydroxide ◽  
Exchange Process ◽  
X Ray ◽  
Batch Technique ◽  
Pseudo Second Order ◽  
Ft Ir ◽  
Double Hydroxide ◽  
Benzoate Anion

AbstractThe Ni-Al-NO3 layered double hydroxide (LDH) compound has been intercalated with benzoate anion through an anion exchange process for amoxicillin drug adsorption. The purpose of this research is to synthesize Ni-Al-NO3, ion exchange with benzoate anion to form Ni-Al-Benzoate, and then applying it as an adsorbent of amoxicillin. The adsorption process was carried out using the batch technique. The materials synthesized in this study were characterized by Fourier Transform Infrared Spectroscopy (FT-IR), X-ray ray diffraction (XRD), and Thermogravimetric Analysis/Differential Thermal Analysis (TGA/DTA). The exchange of benzoate in Ni-Al-Benzoate LDH by amoxicillin was followed by UV-Vis spectrophotometry. The pH, LDH amount, and contact time are optimized. The adsorption of amoxicillin by Ni-Al-Benzoate is fit to the pseudo-second-order kinetics model, with an adsorption capacity of 40 mg/ g. The results showed that anion exchange was successfully carried out between benzoate anion and amoxicillin.

Kinetics of Glyphosate Adsorption on Composite Resin from Aqueous Solution

2013 ◽  
Vol 803 ◽  
pp. 157-160
Author(s):  
Zhen Zhen Kong ◽  
Dong Mei Jia ◽  
Su Wen Cui
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Composite Resin ◽  
Order Equation ◽  
Second Order ◽  
First Order ◽  
Basic Resin ◽  
Pseudo Second Order ◽  
Kinetics Of ◽  
Best Fit

The composite weakly basic resin (D301Fe) was prepared and examined using scanning electron microscopy and Fourier transform infrared spectroscopy. The adsorption kinetics of glyphosate from aqueous solution onto composite weakly basic resin (D301Fe) were investigated under different conditions. The experimental data was analyzed using various adsorption kinetic models like pseudo-first order, the pseudo-second order, the Elovich and the parabolic diffusion models to determine the best-fit equation for the adsorption of glyphosate onto D301Fe. The results show that the pseudo-second order equation fitted the experimental data well and its adsorption was chemisorption-controlled.

scholarly journals Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium Studies

2011 ◽  
Vol 8 (s1) ◽  
pp. S363-S371 ◽  
Author(s):  
C. Theivarasu ◽  
S. Mylsamy
Keyword(s):  
Experimental Data ◽  
Activated Carbon ◽  
Malachite Green ◽  
Kinetic Models ◽  
Theobroma Cacao ◽  
Second Order ◽  
Order Kinetic ◽  
Equilibrium Studies ◽  
Initial Ph ◽  
Pseudo Second Order

The removal of malachite green (MG) by cocoa (Theobroma cacao) shell activated carbon (CSAC) was investigated in present study. Adsorption studies were performed by batch experiments as a function of process parameters such as initial pH, contact time, initial concentration and adsorbent dose. A comparison of kinetic models applied to the adsorption of MG on CSAC was evaluated for the pseudo-first order and pseudo-second order kinetic models. Results showed that the pseudo-second order kinetic model was found to correlate the experimental data well. The experimental equilibrium adsorption data was represented with Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich and Flory-Huggins isotherms. The experimental data obtained in the present study indicated that activated carbon developed from cocoa shell can be attractive options for dye removal from waste water.

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