scholarly journals Study of PM Removal Through Silent Discharge Type of Electric DPF Without Precious Metal Under the Condition of Room Temperature and Atmospheric Pressure

10.5772/53443 ◽  
2013 ◽  
Author(s):  
Minoru Chuubachi ◽  
Takeshi Nagasaw
Keyword(s):  
Atmospheric Pressure ◽  
Precious Metal ◽  
Room Temperature ◽  
Silent Discharge ◽  
Pm Removal

Arene Dearomatization via Radical Hydroarylation

2019 ◽  
Author(s):  
Autumn Flynn ◽  
Kelly McDaniel ◽  
Meredith Hughes ◽  
David Vogt ◽  
Nathan Jui
Keyword(s):  
Precious Metal ◽  
Room Temperature ◽  
Aryl Halide ◽  
Solvent System ◽  
Benzene Derivatives ◽  
Green Solvent ◽  
Photocatalytic System

A photocatalytic system for the dearomative hydroarylation of benzene derivatives has been developed. Using a combination of an organic photoredox catalyst and an amine reductant, this process operates through a reductive radical-polar crossover mechanism where aryl halide reduction triggers a regioselective cyclization event, giving rise to a range of complex spirocyclic cyclohexadienes. This light-driven protocol functions at room temperature in a green solvent system (aq. MeCN), without the need for precious metal-based catalysts or reagents, or the generation of stoichiometric metal byproducts.

scholarly journals Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jacek Malinowski ◽  
Dagmara Jacewicz ◽  
Artur Sikorski ◽  
Mariusz Urbaniak ◽  
Przemysław Rybiński ◽  
...  
Keyword(s):  
Complex Compound ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Organometallic Compounds ◽  
Ethylene Oligomerization ◽  
High Catalytic Activity ◽  
New Material ◽  
Activity Requirement ◽  
Olefin Oligomerization ◽  
Xrd Method

AbstractThe contemporary search for new catalysts for olefin oligomerization and polymerization is based on the study of coordinating compounds and/or organometallic compounds as post-metallocene catalysts. However known catalysts are suffered by many flaws, among others unsatisfactory activity, requirement of high pressure or instability at high temperatures. In this paper, we present a new catalyst i.e. the crystalline complex compound possesing high catalytic activity in the oligomerization of olefins, such as 2-chloro-2-propen-1-ol and ethylene under very mild conditions (room temperature, 0.12 bar for ethylene oligomerization, atmospheric pressure for 2-chloro-2-propen-1-ol oligomerization). New material—Cat-CrNP ([nitrilotriacetato-1,10-phenanthroline]chromium(III) tetrahydrate) has been obtained as crystalline form of the nitrilotriacetate complex compound of chromium(III) with 1,10-phenanthroline and characterized in terms of its crystal structure by the XRD method and by multi-analytical investigations towards its physicochemical propeties The yield of catalytic oligomerization over Cat-CrNP reached to 213.92 g · mmol−1 · h−1· bar−1 and 3232 g · mmol−1 · h−1 · bar−1 for the 2-chloro-2-propen-1-ol and ethylene, respectively. Furthemore, the synthesis of Cat-CrNP is cheap, easy to perform and solvents used during preparation are environmentally friendly.

Proliferation assay of mouse embryonic stem (ES) cells exposed to atmospheric-pressure plasmas at room temperature

2014 ◽  
Vol 47 (44) ◽  
pp. 445402 ◽  
Author(s):  
Taichi Miura ◽  
Ayumi Ando ◽  
Kazumi Hirano ◽  
Chika Ogura ◽  
Tatsuya Kanazawa ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Room Temperature ◽  
Es Cells ◽  
Embryonic Stem ◽  
Proliferation Assay ◽  
Atmospheric Pressure Plasmas

Apparatus for Measuring Dynamic Bulk Compliance of Time-Dependant Materials

2014 ◽  
Vol 601 ◽  
pp. 3-6
Author(s):  
Alen Oseli ◽  
Igor Emri
Keyword(s):  
Atmospheric Pressure ◽  
Room Temperature ◽  
Polyvinyl Acetate ◽  
Thermoplastic Polyurethane

This paper describes a novel apparatus for measuring dynamic bulk compliance B*(ω) of time-dependant materials. System can measure dynamic bulk compliance at room temperature, at pressures up to 100 ± 1,5 bar and frequencies from 100 Hz to 1000 Hz. Functionality of the apparatus is demonstrated by performing measurements of dynamic bulk compliance for two different materials, i.e., polyvinyl acetate (PVAc) and thermoplastic polyurethane (TPU). Measurements were conducted at room temperature, atmospheric pressure and frequencies from 100 Hz to 1000 Hz.

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