ChemInform Abstract: Heterogeneously Catalysed Synthesis of Ammonia at Room Temperature and Atmospheric Pressure.

1986 ◽  
Vol 17 (39) ◽  
Author(s):  
K. AIKA
Keyword(s):  
Atmospheric Pressure ◽  
Room Temperature

scholarly journals Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jacek Malinowski ◽  
Dagmara Jacewicz ◽  
Artur Sikorski ◽  
Mariusz Urbaniak ◽  
Przemysław Rybiński ◽  
...  
Keyword(s):  
Complex Compound ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Organometallic Compounds ◽  
Ethylene Oligomerization ◽  
High Catalytic Activity ◽  
New Material ◽  
Activity Requirement ◽  
Olefin Oligomerization ◽  
Xrd Method

AbstractThe contemporary search for new catalysts for olefin oligomerization and polymerization is based on the study of coordinating compounds and/or organometallic compounds as post-metallocene catalysts. However known catalysts are suffered by many flaws, among others unsatisfactory activity, requirement of high pressure or instability at high temperatures. In this paper, we present a new catalyst i.e. the crystalline complex compound possesing high catalytic activity in the oligomerization of olefins, such as 2-chloro-2-propen-1-ol and ethylene under very mild conditions (room temperature, 0.12 bar for ethylene oligomerization, atmospheric pressure for 2-chloro-2-propen-1-ol oligomerization). New material—Cat-CrNP ([nitrilotriacetato-1,10-phenanthroline]chromium(III) tetrahydrate) has been obtained as crystalline form of the nitrilotriacetate complex compound of chromium(III) with 1,10-phenanthroline and characterized in terms of its crystal structure by the XRD method and by multi-analytical investigations towards its physicochemical propeties The yield of catalytic oligomerization over Cat-CrNP reached to 213.92 g · mmol−1 · h−1· bar−1 and 3232 g · mmol−1 · h−1 · bar−1 for the 2-chloro-2-propen-1-ol and ethylene, respectively. Furthemore, the synthesis of Cat-CrNP is cheap, easy to perform and solvents used during preparation are environmentally friendly.

Proliferation assay of mouse embryonic stem (ES) cells exposed to atmospheric-pressure plasmas at room temperature

2014 ◽  
Vol 47 (44) ◽  
pp. 445402 ◽  
Author(s):  
Taichi Miura ◽  
Ayumi Ando ◽  
Kazumi Hirano ◽  
Chika Ogura ◽  
Tatsuya Kanazawa ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Room Temperature ◽  
Es Cells ◽  
Embryonic Stem ◽  
Proliferation Assay ◽  
Atmospheric Pressure Plasmas

Apparatus for Measuring Dynamic Bulk Compliance of Time-Dependant Materials

2014 ◽  
Vol 601 ◽  
pp. 3-6
Author(s):  
Alen Oseli ◽  
Igor Emri
Keyword(s):  
Atmospheric Pressure ◽  
Room Temperature ◽  
Polyvinyl Acetate ◽  
Thermoplastic Polyurethane

This paper describes a novel apparatus for measuring dynamic bulk compliance B*(ω) of time-dependant materials. System can measure dynamic bulk compliance at room temperature, at pressures up to 100 ± 1,5 bar and frequencies from 100 Hz to 1000 Hz. Functionality of the apparatus is demonstrated by performing measurements of dynamic bulk compliance for two different materials, i.e., polyvinyl acetate (PVAc) and thermoplastic polyurethane (TPU). Measurements were conducted at room temperature, atmospheric pressure and frequencies from 100 Hz to 1000 Hz.

l-Asparagine-assisted synthesis of flower-like β-Bi2O3 and its photocatalytic performance for the degradation of 4-phenylphenol under visible-light irradiation

RSC Advances ◽  
2015 ◽  
Vol 5 (91) ◽  
pp. 74977-74985 ◽  
Author(s):  
Xin Xiao ◽  
Shunheng Tu ◽  
Chunxia Zheng ◽  
Huan Zhong ◽  
Xiaoxi Zuo ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Photocatalytic Performance ◽  
Light Irradiation ◽  
Temperature Range

By introducing l-asparagine as a ligand, a flower-like precursor of Bi2O3 was prepared by a simple reflux process under atmospheric pressure. β-Bi2O3 was then conveniently obtained by decomposing the precursor and stabilized in a temperature range from room temperature to 420 °C due to the surface-coordination effects of CO32− derived from l-asparagine.

scholarly journals Utilizing of 1-Hexyl-1-Methyl-Pyrrolidinium Bis (Trifluoromethyl-Sulfonyl) Imide as Medium for Electrochemical Generation of Superoxide Ion-Radical

1970 ◽  
Vol 12 (4) ◽  
Author(s):  
Maan Hayyan ◽  
Farouq S. Mjalli ◽  
Mohd Ali Hashim ◽  
And Inas M. AlNashef
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Superoxide Ion ◽  
Electrochemical Generation

The superoxide ion-radical was generated and analysed electrochemically using cyclic voltammetry (CV) technique from oxygen dissolved in a room-temperature ionic liquid, 1-Hexyl-1-methyl-pyrrolidinium bis (trifluoromethylsulfonyl) imide, at atmospheric pressure. It was found that the generated superoxide ion was stable which indicates its possible use for further useful applications.ABSTRAK: Ion radikal superoksida dihasil dan dianalisa secara elektrokimia menggunakan teknik voltammetri berkitar (cyclic voltammetry (CV)) daripada oksigen yang dilarutkan dalam larutan ionik pada suhu bilik, 1-Hexyl-1-methyl-pyrrolidinium bis (trifluoromethylsulfonyl) imida, pada tekanan atmosfera. Didapati bahawa ion superoksida yang terhasil adalah stabil. Ini menunjukkan ia berkemungkinan berguna dalam aplikasi lain.

Wall Normal Jet Produced by DBD Plasma Actuator With Doughnut-Shaped Electrode

2008 ◽  
Author(s):  
Takehiko Segawa ◽  
Hiro Yoshida ◽  
Shinya Takekawa ◽  
Timothy Jukes ◽  
Kwing-So Choi
Keyword(s):  
Atmospheric Pressure ◽  
Room Temperature ◽  
Particle Image ◽  
Barrier Discharge ◽  
Plasma Actuator ◽  
Dbd Plasma ◽  
Annular Jet ◽  
Image Velocimetry ◽  
Inner Diameter ◽  
Annular Jets

Properties of coaxial annular jets produced by a dielectric barrier discharge (DBD) plasma actuator with a doughnut shaped electrodes were investigated under atmospheric pressure and room temperature. The actuator consists of two circular electrodes sandwiching a thin dielectric layer. By applying 0 – ±3.3 kV between the electrodes at radio frequencies, the plasma jet is formed near the inner edge of the top electrode. The radial jet runs toward the center of the electrode and then impinges at the center to generate a wall normal annular jet. The evolution of the wall normal jet was observed precisely using particle image velocimetry (PIV) system. It was found that characteristic velocities increase in proportion to the bursting frequency and inversely proportional to the inner diameter of the electrode at the surging time of the voltage at 5.0 × 10−6sec.

Graftfast©: Towards the Control of Surface Properties of any Type of Materials by the Grafting of Polymers

2012 ◽  
Vol 445 ◽  
pp. 797-802 ◽  
Author(s):  
Alice Mesnage ◽  
Pardis Simon ◽  
Guy Deniau ◽  
Nathalie Herlin-Boime ◽  
Serge Palacin
Keyword(s):  
Surface Properties ◽  
Polymer Films ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Diazonium Salts ◽  
Green Process ◽  
Graft Polymer ◽  
Grafted Polymer ◽  
Aryl Radicals ◽  
One Step

This document aims at presenting and explaining the mechanism of a simple green process, called Graftfast©, recently developed in order to graft polymer films onto any type of materials. This process is of great interest as it works in a short one step reaction at room temperature, atmospheric pressure in water. Particularly since this method is a redoxinduced process consisting in the reduction of diazonium salts into aryl radicals in presence of vinylic monomer, the involvement of such radicals was investigated. Moreover, this work demonstrates the efficiency of such process for the preparation of functionalized TiO2 nanoparticles. The composition and the grafted polymer quantities were investigated showing the successful grafting of the polymer onto the nanoparticles while conserving their morphology.

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