scholarly journals Self-Organized Three-Dimensional Optical Circuits and Molecular Layer Deposition for Optical Interconnects, Solar Cells, and Cancer Therapy

Author(s):  
Tetsuzo Yoshimura
2014 ◽  
Vol 5 ◽  
pp. 1104-1136 ◽  
Author(s):  
Pia Sundberg ◽  
Maarit Karppinen

The possibility to deposit purely organic and hybrid inorganic–organic materials in a way parallel to the state-of-the-art gas-phase deposition method of inorganic thin films, i.e., atomic layer deposition (ALD), is currently experiencing a strongly growing interest. Like ALD in case of the inorganics, the emerging molecular layer deposition (MLD) technique for organic constituents can be employed to fabricate high-quality thin films and coatings with thickness and composition control on the molecular scale, even on complex three-dimensional structures. Moreover, by combining the two techniques, ALD and MLD, fundamentally new types of inorganic–organic hybrid materials can be produced. In this review article, we first describe the basic concepts regarding the MLD and ALD/MLD processes, followed by a comprehensive review of the various precursors and precursor pairs so far employed in these processes. Finally, we discuss the first proof-of-concept experiments in which the newly developed MLD and ALD/MLD processes are exploited to fabricate novel multilayer and nanostructure architectures by combining different inorganic, organic and hybrid material layers into on-demand designed mixtures, superlattices and nanolaminates, and employing new innovative nanotemplates or post-deposition treatments to, e.g., selectively decompose parts of the structure. Such layer-engineered and/or nanostructured hybrid materials with exciting combinations of functional properties hold great promise for high-end technological applications.


2021 ◽  
Author(s):  
Yang Zhao ◽  
Lei Zhang ◽  
Jian Liu ◽  
Keegan Adair ◽  
Feipeng Zhao ◽  
...  

This review summarizes the achievements of atomic/molecular layer deposition for batteries, supercapacitors, fuel cells, solar cells, and photoelectrochemical water splitting.


2020 ◽  
Author(s):  
Eyal Wormser ◽  
Oded Nir ◽  
Eran Edri

<div> <div> <div> <p>The desalination of brackish water provides water to tens of millions of people around the world, but current technologies deplete much needed nutrients from the water, which is detrimental to both public health and agriculture. A selective method for brackish water desalination, which retains the needed nutrients, is electrodialysis (ED) using monovalent-selective cation exchange membranes (MVS-CEMs). However, due to the trade-off between membrane selectivity and resistance, most MVS-CEMs demonstrate either high transport resistance or low selectivity, which increase energy consumption and hinder the use of such membranes for brackish water desalination by ED. Here, we used molecular layer deposition (MLD) to uniformly coat CEMs with ultrathin layers of alucone. The positive surface charge of the alucone instills monovalent selectivity in the CEM. Using MLD enabled us to precisely control and minimize the selective layer thickness, while the flexibility and nanoporosity of the alucone prevent cracking and delamination. Under conditions simulating brackish water desalination, this compound provides monovalent selectivity with negligible added resistance—the smallest reported resistance for a monovalent-selective layer, to date—thereby alleviating the selectivity–resistance trade-off. Addressing the water–energy nexus, we show that using these membranes in ED will cut at least half of the energy required for selective brackish water desalination with current MVS-CEMs. </p> </div> </div> </div>


2017 ◽  
Vol 426 ◽  
pp. 133-147
Author(s):  
Frank Fug ◽  
Adrien Petry ◽  
Hendrik Jost ◽  
Aisha Ahmed ◽  
Mohammad Zamanzade ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 2427-2436
Author(s):  
Eyal Merary Wormser ◽  
Oded Nir ◽  
Eran Edri

The desalination of brackish water provides water to tens of millions of people around the world, but current technologies deplete much needed nutrients from the water, which is determinantal to both public health and agriculture.


2021 ◽  
Author(s):  
Nathaniel E. Richey ◽  
Shirin Borhan ◽  
Stacey Bent

Coordination polymers deposited by hybrid molecular layer deposition (MLD) techniques are of interest as highly conformal, functional materials. Addition of a second metal into these coordination polymers can result in...


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