scholarly journals Detect Structure Features of Asymmetric and Symmetric CH2 and CH3 Functional Groups and Their Ratio of Biopolymers within Intact Tissue in Complex Plant System Using Synchrotron FTIRM and DRIFT Molecular Spectroscopy

Biopolymers ◽  
10.5772/10277 ◽  
2010 ◽  
Author(s):  
Peiqiang Yu
Keyword(s):  
Functional Groups ◽  
Molecular Spectroscopy ◽  
Plant System ◽  
Intact Tissue

Solutochromic Molecular Spectroscopy with a Reference Hydrogen-Bond Acid Dendrimer

2012 ◽  
Vol 1403 ◽  
Author(s):  
R. Andrew McGill ◽  
Duane Simonson ◽  
Julie H. Ta ◽  
Viet Nguyen ◽  
Yasar Ozten ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Functional Groups ◽  
Molecular Spectroscopy ◽  
Spectroscopic Techniques ◽  
Hazardous Chemicals ◽  
Zeroth Order ◽  
Molecular Sensing ◽  
Molecular Binding ◽  
Selective Sorbent ◽  
Ir Spectroscopic

A zeroth order dendritic carbosilane structure, SiFA4H with four hexafluoroisopropanol (HFIP) functional groups attached via propyl ligand arms to a central silicon atom, has been developed as a model hydrogen-bond (HB) acid sorbent coating and candidate reference HB acid. The HB donor interaction, through the hydroxyl of the HFIP moiety, with a solute HB base can be monitored by observing the hydroxyl stretching frequency through measurements of SiFA4H FTIR spectra before and during vapor exposure. HFIP hydroxyl stretch shifts, upwards of 700 cm-1 have been observed depending on the HB base. For a range of HB bases, the resulting hydroxyl stretch shifts correlate directly with the solute HB basicity scale, “B”, developed by Abraham et al [1]. A variety of techniques exist to measure solute HB basicity, however, the applicability to examine HB bases delivered as vapors or gases and the simplicity of the measurements described herein, with a reusable reference HB acid sorbent coating and standard FTIR spectrophotometer techniques is attractive for some applications including those with hazardous chemicals. Moreover, as an extension of this work we propose employing SiFA4H or related sorbents as molecular sensing coatings, where the semi-selective sorbent is examined by various infrared (IR) spectroscopic techniques to monitor and identify hazardous chemicals, taking advantage of molecular binding phenomena which occur in the sorbent [2].

Improving integration between functional groups: A case in organization change and implications for theory and practice

1971 ◽  
Author(s):  
Warren G. Bennis ◽  
Michael Beer ◽  
Gerald R. Pieters ◽  
Alan T. Hundert ◽  
Samuel H. Marcus ◽  
...  
Keyword(s):  
Functional Groups ◽  
Organization Change ◽  
Theory And Practice

MOLECULAR SPECTROSCOPY WITH OPTOGALVANIC DETECTION

1983 ◽  
Vol 44 (C7) ◽  
pp. C7-395-C7-409
Author(s):  
C. B. Collins
Keyword(s):  
Molecular Spectroscopy

HYDROXYAPATITE, ALGINATE, AND CHITOSAN FOR BONE SCAFFOLDS: SPECTROSCOPY STUDY

2016 ◽  
Vol 19 (2) ◽  
pp. 93-100
Author(s):  
Lalita El Milla
Keyword(s):  
Tissue Engineering ◽  
Bone Tissue Engineering ◽  
Bone Tissue ◽  
Functional Groups ◽  
Bone Growth ◽  
Three Dimensional ◽  
Dimensional Structure ◽  
Tissue Engineering Scaffolds ◽  
Hydroxyapatite Powder ◽  
Materials Used

Scaffolds is three dimensional structure that serves as a framework for bone growth. Natural materials are often used in synthesis of bone tissue engineering scaffolds with respect to compliance with the content of the human body. Among the materials used to make scafffold was hydroxyapatite, alginate and chitosan. Hydroxyapatite powder obtained by mixing phosphoric acid and calcium hydroxide, alginate powders extracted from brown algae and chitosan powder acetylated from crab. The purpose of this study was to examine the functional groups of hydroxyapatite, alginate and chitosan. The method used in this study was laboratory experimental using Fourier Transform Infrared (FTIR) spectroscopy for hydroxyapatite, alginate and chitosan powders. The results indicated the presence of functional groups PO43-, O-H and CO32- in hydroxyapatite. In alginate there were O-H, C=O, COOH and C-O-C functional groups, whereas in chitosan there were O-H, N-H, C=O, C-N, and C-O-C. It was concluded that the third material containing functional groups as found in humans that correspond to the scaffolds material in bone tissue engineering.

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