scholarly journals Forms of potassium and sodium in some species of grasses and herbage

2013 ◽  
Vol 35 (1) ◽  
pp. 87-99 ◽  
Author(s):  
Grzegorz Nowak ◽  
Henryk Panak
Keyword(s):  
Acetic Acid ◽  
Dactylis Glomerata ◽  
Mineral Fertilizer ◽  
Taraxacum Officinale ◽  
Poa Annua ◽  
Major Influence ◽  
Festuca Rubra ◽  
Distilled Water ◽  
Pot Culture ◽  
Acetic Acids

The forms of occurence of potassium and sodium were studied in the grasses <i>Dactylis glomerata</i> L., <i>Poa annua</i> L., <i>Festuca rubra</i> L. and dendelion (<i>Taraxacum officinale</i> Web.) treated with increasing mineral fertilizer doses, magnesium and microelements, under conditions of pot culture. The plants took up potassium in amounts greatly exceeding their requirement, and sodium in very small amounts. Mineral NPK doses increased in the tested plants both the content of potassium and sodium forms soluble in trichloroacetic and acetic acids and water. Magnesium and microelements had no major influence on the content of these potassium forms, but they increased the concentration of analogous forms of sodium in <i>Taraxacum officinale</i> and did not influence their accumulation in the grasses. Potassium and sodium compounds were completely extracted from the plants with trichloroacetic, whereas acetic acid extracted 88-95 percent of potassium and 66-74 percent of sodium. Distilled water extracted 70-77 and 28-33 percent of potassium and sodium, respectively.

Evaluation of mineral fertilizer effects in a long-term experiment on a planted sward

2010 ◽  
Vol 59 (2) ◽  
pp. 295-314 ◽  
Author(s):  
Imre Kádár
Keyword(s):  
Festuca Arundinacea ◽  
Dactylis Glomerata ◽  
Mineral Fertilizer ◽  
Phleum Pratense ◽  
Agropyron Cristatum ◽  
Festuca Rubra ◽  
Festuca Pratensis ◽  
Term Experiment ◽  
Long Term Experiment

Egy műtrágyázási tartamkísérlet 32. évében, 2005-ben vizsgáltuk az eltérő N-, P- és K-ellátottsági szintek és kombinációik hatását a réti csenkesz (Festuca pratensis) vezérnövényű, nyolckomponensű, pillangós nélküli gyepkeverék termésére, fejlődésére és elemtartalmára. A termőhely mészlepedékes csernozjom talaja a szántott rétegben mintegy 3% humuszt, 3–5% CaCO3-ot és 20–22% agyagot tartalmazott, N és K elemekben közepesen, P és Zn elemekben gyengén ellátottnak minősült. A kísérlet 4N×4P×4K = 64 kezelést×2 ismétlést = 128 parcellát foglalt magában. A talajvíz 13–15 m mélyen helyezkedik el, a terület aszályérzékeny. A vizsgált 2005. évben azonban kielégítő mennyiségű (649 mm) csapadék hullott és annak eloszlása is kedvező volt. A gyep telepítése spenót elővetemény után 2000. szeptember 20-án történt gabona sortávra 60 kg·ha–1 vetőmaggal, amelynek 25%-át (15 kg) a réti csenkesz (Festuca pratensis); 21–21%-át (12,6 kg) a nádképű csenkesz (Festuca arundinacea) és az angol perje (Lolium perenne); 9%-át (5,4 kg) a taréjos búzafű (Agropyron cristatum), valamint 6–6%-át (3,6 kg) a vörös csenkesz (Festuca rubra), a réti komócsin (Phleum pratense), a zöld pántlikafű (Phalaris arundinacea) és a csomós ebír (Dactylis glomerata) tette ki. Főbb eredményeink: – A meghatározó N-trágyázás nyomán a szénatermés 5-szörösére emelkedett a két kaszálással a N-kontrollhoz viszonyítva. A maximális 10 t·ha–1 körüli légszáraz szénahozamokat a 300 kg N·ha–1·év–1 N-adag, valamint a 150 mg·kg–1 körüli AL-P2O5-, illetve 150 mg·kg–1 feletti AL-K2O-tartalom biztosította. Növénydiagnosztikai szempontból a nagy terméshez kötődő optimális elemtartalom 2% körüli N- és K-, illetve 0,2–0,3% P-koncentráció volt a szénában. – A két kaszálással felvett minimum (a 2 t·ha–1 körüli szénatermést adó N-kontroll) és maximum (a 10 t·ha–1 körüli szénahozamú, nitrogénnel és PK-vel jól ellátott talajok) elemmennyiségek a következőképpen alakultak: N 21–196 kg, K 39–188 kg, Ca 9–48 kg, Mg 4–22 kg, P 6–21 kg. – Az N×P és N×K kölcsönhatások kifejezettebbé váltak a 2. kaszálás idején. A P 0,18–0,55%, a NO3-N 86–1582 mg·kg–1, a Cu 4,7–7,4 mg·kg–1, a Mo 0,7–4,1 mg·kg–1 extrém értékeket jelzett az N×P kezelések függvényében. Az N×K kezelésekben a K 1,44–2,73%, a Mg 0,26–0,39%, a Na 71–2178 mg·kg–1, a Ba 4,1–9,6 mg·kg–1, a Cd 15–44 µg·kg–1 szélsőértékekkel volt jellemezhető. A Sr a 10–26 mg·kg–1 koncentrációtartományban módosult a P×K-ellátottság nyomán. Élettani, takarmányozástani szempontból az indukált kölcsönhatások nyomon követése elengedhetetlen, amennyiben olyan mérvű tápelemhiányok, illetve aránytalanságok jöhetnek létre, melyek anyagcserezavarokat okozhatnak a növényt fogyasztó állatban.

scholarly journals The Effect of Acetic Acid Treatments on the Quality of Stored Carrot (Daucus carota L.) Seeds

Agronomy ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1176
Author(s):  
Hanna Dorna ◽  
Agnieszka Rosińska ◽  
Dorota Szopińska
Keyword(s):  
Acetic Acid ◽  
Distilled Water ◽  
Storage Duration ◽  
Seed Vigour ◽  
Daucus Carota L ◽  
Two Samples ◽  
Before And After ◽  
Alternaria Dauci ◽  
Acid Treatments

Alternaria dauci (J.G. Kühn) J.W. Groves et Skolko and A. radicina Meier, Drechsler et E.D. Eddy are important seed-transmitted pathogens of carrot. The aim of this study was to evaluate the effects of acetic acid treatments on the quality of stored carrot seeds. Seeds of two samples were soaked for 30 min in 0.5, 1 and 2% acetic acid. Controls included untreated seeds, seeds soaked in distilled water and seeds treated with fungicide Zaprawa Nasienna T 75 WS/DS (a.i. thiram 75%). Germination, vigour and health of untreated and treated seeds were evaluated before and after 5 and 12 months of storage at 4 and 20 °C. Seeds of both samples treated with 0.5 and 1% acetic acid were characterized by higher germination capacity after storage than untreated seeds. However, treatments with 1 and 2% acetic acid negatively affected seed vigour. Generally, seeds of both samples treated with acetic acid were characterized by lower infestation with A. alternata and A. radicina after storage than untreated seeds and seeds soaked in distilled water. Moreover, acetic acid often controlled these fungi more effectively than the fungicide. Regardless of the storage duration, infestation with fungi was higher if seeds of both samples were stored at a lower temperature.

COPPER, MOLYBDENUM AND SULFUR CONTENTS OF FORAGE CROPS AT KAPUSKASING, ONTARIO

1970 ◽  
Vol 50 (6) ◽  
pp. 685-691 ◽  
Author(s):  
J. R. LESSARD ◽  
M. HIDIROGLOU ◽  
R. B. CARSON ◽  
J. M. WAUTHY
Keyword(s):  
Dactylis Glomerata ◽  
Phleum Pratense ◽  
Birdsfoot Trefoil ◽  
Festuca Rubra ◽  
Forage Crops ◽  
Reed Canarygrass ◽  
Red Fescue ◽  
Cu Content ◽  
Dactylis Glomerata L ◽  
Phleum Pratense L

Each of the species birdsfoot trefoil (Lotus corniculatus L.), timothy (Phleum pratense L.), bromegrass (Bromus inermis Leyss.), orchardgrass (Dactylis glomerata L.), reed canarygrass (Phalaris arundinacea L.) and creeping red fescue (Festuca rubra L.) was grown in the field on 10 plots sampled at weekly intervals in rotation from June 13. Each plot was resampled after 6 weeks and all samples were analyzed for copper, molybdenum and sulfur. In most species, levels of Cu and Mo were highest in the early samplings and decreased with advancing maturity. Second-cut samples tended to be higher in Cu, Mo and S than first-cut samples. The S content was more uniform in the first cycle but increased considerably in the second cycle, especially in reed canarygrass. The ranges in Cu content were 7.4 to 14.1 ppm for birdsfoot trefoil and 3.7 to 11.4 ppm for the grasses. Mo ranged from 1.9 to 8.1 ppm in birdsfoot trefoil and from 1.0 to 6.5 ppm in the grasses. The overall range in S content was from 0.14 to 0.95%. The mineral composition of the crops is discussed in relation to the requirement of ruminants for these three elements.

CHROMOSOME NUMBERS AND TAXONOMIC NOTES ON NORTHERN GRASSES: II. TRIBE FESTUCEAE

1960 ◽  
Vol 38 (2) ◽  
pp. 117-131 ◽  
Author(s):  
Wray M. Bowden
Keyword(s):  
Chromosome Numbers ◽  
Somatic Chromosome ◽  
Bromus Tectorum ◽  
Dactylis Glomerata ◽  
Bromus Inermis ◽  
Festuca Rubra ◽  
Lolium Rigidum ◽  
Voucher Specimens ◽  
Dactylis Glomerata L ◽  
Somatic Chromosome Numbers

Chromosome numbers and voucher specimens are recorded for some collections of the tribe FESTUCEAE Dumort., mainly collected in Canada. The somatic chromosome numbers of the following are recorded: (1a) Arctagrostis arundinacea (Trin.) Beal var. arundinacea, 2n = 28, 2n = 29, and 2n = 30; (1b) Arctagrostis arundinacea (Trin.) Beal var. crassispica Bowden, 2n = 56; (1c) Arctagrostis latifolia (R.Br.) Griseb., 2n = 56. (2) Beckmannia syzigachne (Steud.) Fern., 2n = 14. (3) Brachyelytrum erectum (Schreb.) Beauv., two vars., 2n = 22. (4a) Bromus ciliatus L., 2n = 14; (4b) Bromus inermis Leyss., two subspecies and two vars., 2n = 56; (4e) Bromus kalmii A. Gray, 2n = 14; (4d) Bromus porteri (Coult.) Nash, 2n = 14; (4c) Bromus tectorum L., 2n = 14. (5) Catabrosa aquatica (L.) Beauv. var. laurentiana Fern., 2n = 20. (6) Dactylis glomerata L., 2n = 28. (7) Distichlisstricta (Torr.) Rydb., 2n = 40. (8a) Dupontiafisheri R.Br, subsp. fisheri, 2n = 132; (8b) Dupontia fisheri R.Br, subsp. psilosantha (Rupr.) Hultén, 2n = 44. (9) Eremopoa persica (Trin.) Roshev., 2n = 28. (10a) Festuca altaica Trin., 2n = 28; (10b) Festuca baffinensis Polunin, 2n = 28; (10c) Festuca brachyphylla Schultes, 2n = 42 and one collection, 2n = 44; (10d) Festuca elatior L., 2n = 14; (10e) Festuca obtusa Bieler, 2n = 42; (10f) Festuca prolifera (Piper) Fern. var. lasiolepis Fern., 2n = 50; (10g) Festuca rubra L., 2n = 42; (10h) Festuca saximontana Rydb., 2n = 42; (10i)Festuca scabrella Torr. ex Hook., two vars., 2n = 56 and 2n = 28. (11a) Glyceria borealis (Nash) Batchelder, 2n = 20; (11b) Glyceria canadensis (Michx.) Trin., 2n = 60; (11c) Glyceria grandis S. Wats., 2n = 20; (11d) Glyceria melicaria (Michx.) Hubb., 2n = 40; (11e) Glyceria pulchella (Nash) K. Schum., 2n = 20; (11f) Glyceria striata (Lam.) Hitchc, 2n = 20; (11g) Glyceria × gatineauensis Bowden (G. melicaria × G. striata), 2n = 30; (11h)Glyceria × ottawensis Bowden (G. canadensis × G. striata), three nothomorphs, 2n = 42, 2n = 46, and 2n = 48. (12) Lolium rigidum Gaud., 2n = 14. (13a) Phippsiaalgida (Sol.) R.Br., 2n = 28; (13b) Phippsia concinna (Th. Fries) Lindeb., 2n = 28. (14) Pleuropogon sabinei R.Br., 2n = 42. (15) Schizachnepurpurascens (Torr.) Swallen, 2n = 20. (16) Torreyochloa fernaldii (Hitchc.) Church, 2n = 14.

scholarly journals Computational notes on the electronic properties of carboxylic acid

2020 ◽  
Vol 9 (2) ◽  
pp. 1079-1082
Keyword(s):  
Acetic Acid ◽  
Carboxylic Acid ◽  
Electronic Properties ◽  
Carboxylic Acids ◽  
Normal Mode ◽  
Normal Modes ◽  
Carboxyl Groups ◽  
Vibrational Characteristics ◽  
Vibrational Features ◽  
Acetic Acids

The present work describing the electronic properties and vibrational characteristics of carboxylic acids. Acetic acid is chosen as model molecules then optimized at B3LYP/6-31g(d,p) level of theory. The vibrational frequencies were calculated at the same level of theory. Band assignments which were calculated as 18 normal modes were assigned as one compare the normal mode coordinates with original one. Band assignments were described indicating the directions of normal modes in terms the vibrating atoms of the acetic acids. It could be concluded that DFT could be a useful tool for elucidation both the structural and vibrational features of carboxylic acids and then further utilized for assignment of the structures contains carboxyl groups which are known as most reactive structures in chemistry, biology and environment.

scholarly journals SYNTHESIS OF ESTERS OF HALOGENOACETIC ACIDS

2020 ◽  
Vol 2020 (3) ◽  
pp. 38-43
Keyword(s):  
Acetic Acid ◽  
Acid Catalyst ◽  
Primary Amines ◽  
Primary Alcohols ◽  
Sulfuric Acid Catalyst ◽  
Nucleophilic Exchange ◽  
Pmr Spectra ◽  
High Yields ◽  
Esterification Reactions ◽  
Acetic Acids

Amidoalkylating reagents containing a phthalimide group are used in the synthesis of hard-to-reach primary amines and complex heterocyclic compounds. These types of amidoalkylating compounds are suitable reagents for nucleophilic substituted reactions in acidic media due to their resistance to acids. Result of reactions of amidoalkylating reagents-N-hydroxyethylphthalimide and N-hydroxymethylphthalimide with aliphatic carbonic acids can also produce new bactericidal and fungicidal esters. In this study, halogen acids reacted with N-hydroxymethylphthalimide monochloric acetic acid, monobromic acetic acid, monoiodic acetic acid, trifluoric acetic acid and trichloroacetic acid, as well as, N-b-hydroxyethylphthaleidyl monohydric acid. As a result of the reactions, new phthalimidomethyl and phthalimidoethyl esters of haloacetic acids were synthesized. The physical properties of crystalline esters have been determined. The structure of these compounds were confirmed by the analysis of their IR and PMR spectra. The esterification reactions of halogenated acetic acids were carried out in a benzene solvent and a sulfuric acid catalyst with primary alcohols, N-hydroxymethylphthalimide and N-β- beta hydroxyethylphthalimide,. It was found that in a benzene solvent, which increases the rate of bimolecular nucleophilic exchange in primary alcohols, phthalimidoethyl esters of halogen acid are formed in high yields, and phthalimidomethyl esters are formed in low yields. It was shown that the reaction of esterification of halogen acids with N-hydroxymethylphthalimide proceeds with monomolecular nucleophilic exchange.

Hydrogen Peroxide Might Bleach Natural Dentin by Oxidizing Phosphoprotein

2018 ◽  
Vol 97 (12) ◽  
pp. 1339-1345 ◽  
Author(s):  
T. Jiang ◽  
Y.R. Guo ◽  
X.W. Feng ◽  
Y. Sa ◽  
X. Yang ◽  
...  
Keyword(s):  
Amino Acids ◽  
Hydrogen Peroxide ◽  
Acetic Acid ◽  
Aromatic Amino Acids ◽  
Disodium Salt ◽  
Tooth Bleaching ◽  
Distilled Water ◽  
Fluorescent Properties ◽  
Fluorescent Intensity ◽  
Tooth Color

Recent studies suggested that bleaching agents may whiten teeth by oxidizing the fluorescent materials, which are the proteins located in the organic-inorganic interface. Therefore, we postulated that fluorescence of dentin came from dentin phosphoprotein (DPP) and that bleaching agents might bleach dentin by oxidizing DPP. Fifty-six specimens were randomly divided into 4 groups and exposed to distilled water, hydrogen peroxide (HP), ethylenediamine tetraacetic acid disodium salt (EDTA), and acetic acid for 24 h. After measuring the organic and inorganic components, fluorescence, and color characteristics of dentin before and after exposure, we found that when DPP was removed from dentin by EDTA, fluorescent intensity declined proportionally with the reduction in Raman relative intensity, and dentin was whitened considerably, with an Δ E value 6 times higher than that of the distilled water group. On the contrary, due to the incapability of acetic acid to dissolve DPP during decalcification, fluorescent intensity values and tooth color remained nearly unchanged after exposure to acetic acid. Dentin exposed to neutral HP showed no obvious morphologic and organic/inorganic component changes except for the destruction of DPP. Similarly, dramatically decreased fluorescent intensity and lightened color were found in the HP group. Moreover, DPP solution of the HP group exhibited decreased ultraviolet absorbance, especially between 250 and 300 nm, which arose from aromatic amino acids. The results indicated that DPP was responsible for the fluorescent properties of dentin and that HP might bleach dentin by the oxidization of aromatic amino acids in DPP. These findings are of great significance in promoting our further understanding of the mechanism of tooth bleaching and the fluorescent property of normal dentin.

EFFECTS OF HERBICIDE RATES AND TIME OF APPLICATION ON THE CONTROL OF TANSY RAGWORT IN PASTURES

1976 ◽  
Vol 56 (3) ◽  
pp. 605-610 ◽  
Author(s):  
W. N. BLACK
Keyword(s):  
Acetic Acid ◽  
Propionic Acid ◽  
Active Ingredient ◽  
White Clover ◽  
Senecio Jacobaea ◽  
Time Of Application ◽  
Trifolium Repens L ◽  
Dichlorophenoxy Acetic Acid ◽  
Acetic Acids ◽  
Tansy Ragwort

The ester of 2,4-D [(2,4-dichlorophenoxy) acetic acid] at 1.1 kg active ingredient (a.i.)/ha failed to control tansy ragwort (Senecio jacobaea L.) in the late-rosette, bud, and flowering stages of development. Sprays of 2,4-D ester at 2.2 kg/ha were more effective than when applied at 1.1 kg/ha, but repeated treatments were necessary for optimum tansy ragwort control. Comparative dosage levels of the esters of 2,4-D and of 2,4-DB [4-(2,4-dichlorophenoxy) butyric acid] showed 2,4-D giving better control of tansy ragwort when applied at equivalent rates. Control of relatively immature tansy ragwort plants with 2,4-D was not significantly different at the 1.1, 2.2, and 4.5 kg/ha levels, but injury to grasses and white clover (Trifolium repens L.) increased at the higher rates. The ester of 2,4-DB at 2.2 and 4.5 kg/ha effectively controlled seedling and early-rosette tansy ragwort plants only. The quantity of water applied as a spray was critical since the frond-type leaves which fold over one another prevented thorough wetting of the entire foliage with spray volumes under 275 liters/ha. Data obtained over a 4-yr period showed that CMPP (±) 2-[(4-chloro-1-tolyl) oxy) propionic acid], CP 1815 (chlorinated benzoic and cresoxy-acetic acids), 2,3,6-TBA (dimethylamine salt of 2,3,6-trichlorobenzoic acid), 2,4-D acid [weedone 638, emulsifiable concentrate-(2,4-dichlorophenoxy) acetic acid], and fenoprop [2-(2,4,5-trichlorophenoxy) propionic acid] were as effective as the ester of 2,4-D for tansy ragwort control but caused more injury to components of the sward.

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