scholarly journals Analysis of the Dielectric Constant as a Function of Temperature at Constant Electric Fields for the Smectic A-Smectic G Transition in A6

2012 ◽  
Vol 2012 ◽  
pp. 1-5
Author(s):  
H. Yurtseven ◽  
E. Kilit

The temperature dependence of the dielectric constant is studied under some fixed electric fields for the smectic G- (tilted-) smectic A (orthogonal) transition of the ferroelectric liquid crystal of compound A6. For this study, a mean field model with the quadrupole-quadrupole interactions is introduced. By fitting the inverse dielectric susceptibility from the mean field model to the experimental data from the literature, the observed behaviour of the dielectric constant is described satisfactorily for the smectic AG transition in A6. The transition temperature induced by an external electric field is also discussed for this ferroelectric compound.

2017 ◽  
Vol 36 (9) ◽  
pp. 863-869
Author(s):  
H. Yurtseven ◽  
M. Celik ◽  
H. Karacali

AbstractThe temperature dependences of the spontaneous polarization and the dielectric constant (susceptibility) are calculated using the mean field model for the ferroelectric N(CH3)4HSO4. Expressions derived from the mean field model for the spontaneous polarization and the inverse susceptibility are fitted to the experimental data from the literature. The fitting parameters in the expansion of the free energy in terms of the spontaneous polarization are determined within the temperature intervals in the ferroelectric and paraelectric phases of N(CH3)4HSO4. Our results show that the temperature dependences of the spontaneous polarization and the dielectric constant as predicted from our mean field model, describe adequately the observed behavior of N(CH3)4HSO4 in the ferroelectric and paraelectric phases.


1998 ◽  
Vol 66 (1-4) ◽  
pp. 259-270 ◽  
Author(s):  
S. SalihoĞLu ◽  
H. Yurtseven ◽  
A. Giz ◽  
D. Kayişoğlu ◽  
A. Konu

1992 ◽  
Vol 45 (11) ◽  
pp. 1899 ◽  
Author(s):  
PA Reynolds ◽  
CD Delfs ◽  
BN Figgis ◽  
B Moubaraki ◽  
KS Murray

The magnetic susceptibilities along and perpendicular to the c axis (hexagonal setting) between 2.0 and 300 K at a magnetic field of 1.00 T, and the magnetizations at field strengths up to 5.00 T, are presented for single crystals of [Co(NH3)5(OH2)] [Cr(CN)6]. The results are interpreted in terms of zero-field splitting (2D) of the ground 4A2g term by spin-orbit coupling and of magnetic exchange interaction between the chromium atoms. The magnetic exchange is modelled as one of Ising or mean-field in type. The exchange is found to be quite small: J = -0.18(6) cm-1 if the Ising model is employed, and -0.03(1) cm-1 for the mean-field model. The model adopted for the exchange has a strong influence on the value of the parameter D obtained. When the Ising model is used D is deduced to be -0.28(9) cm-l; when the mean-field model is used D is -0.14(4) cm-l. The g-values deduced are in agreement with those from e.s.r. measurements at higher temperatures and do not depend on the exchange model. In any case, D is found to be sufficiently large that it must be considered in a polarized neutron diffraction experiment on the compound.


1999 ◽  
Vol 542 (1-2) ◽  
pp. 413-424 ◽  
Author(s):  
P. Bialas ◽  
Z. Burda ◽  
D. Johnston

Sign in / Sign up

Export Citation Format

Share Document