scholarly journals Modeling of Viscosity and Thermal Expansion of Bioactive Glasses

ISRN Ceramics ◽  
2012 ◽  
Vol 2012 ◽  
pp. 1-5
Author(s):  
Saad B. H. Farid

The behaviors of viscosity and thermal expansion for different compositions of bioactive glasses have been studied. The effect of phosphorous pentoxide as a second glass former in addition to silica was investigated. Consequently, the nonlinear behaviors of viscosity and thermal expansion with respect to the oxide composition have been modeled. The modeling uses published data on bioactive glass compositions with viscosity and thermal expansion. -regression optimization technique has been utilized for analysis. Linear and nonlinear relations are shown to establish the viscosity and thermal expansion coefficients associated with oxide components of the glasses under study. The modeling allows the calculation of viscosity for a given temperature and, accordingly, the fusion temperature of these glasses along with the coefficient of thermal expansion. The established model relations also suggest first- and second-order phosphorus-alkali and alkaline earth oxides interaction which is reflected on the model coefficient that calculates viscosity and thermal expansion.

1998 ◽  
Vol 550 ◽  
Author(s):  
D.R. Bloyer ◽  
J.M. Mcnaney ◽  
A.P. Tomsia

AbstractA new series of bioactive glasses have been prepared with thermal expansion coefficients that more closely match that of Ti-based implant alloys. It is proposed that these glasses be used as coatings on biological implants that would provide improved fixation between the implant and tissue. As glasses are subject to environmentally assisted crack growth, it is important to develop an understanding of the stress corrosion crack growth (SCCG) behavior of this new family of glasses; furthermore, it is equally important to determine the effect of bioactivity on the SCCG properties of these glasses. This report will present the progress to date in the study of the SCCG properties of these new bioactive glasses


1986 ◽  
Vol 23 (3) ◽  
pp. 327-333 ◽  
Author(s):  
J. G. Agar ◽  
N. R. Morgenstern ◽  
J. D. Scott

The prediction of stress changes and deformations arising from ground heating requires the coupled solution of the heat transfer and consolidation equations. Heat consolidation as a class of problems is distinct from other thermally induced consolidation problems involving processes such as frost heave and thaw consolidation in that it involves heating to elevated temperatures well above normal ground temperatures. Two of the important parameters required in analyses of heat consolidation problems are thermal expansion coefficients and a coefficient of thermal pore pressure generation.Relationships describing thermal expansion behaviour and thermal pore pressure generation in oil sands are presented. Both drained and undrained thermal expansion coefficients for Athabasca oil sand were determined by means of heating experiments in the temperature range 20–300 °C. The thermal pore pressure generation coefficient was evaluated in undrained heating experiments under constant total confining stresses and under constant effective confining stresses. The equipment and experimental methods developed during this study are appropriate for determination of thermal expansion and pore pressure generation properties of oil sands and other unconsolidated geologic materials. Key words: thermal expansion, oil sand, tar sand, thermal pore pressure generation, heat consolidation, thermal consolidation, coefficient of thermal expansion, thermal stresses, ground heating, thermally enhanced oil recovery, thermoelasticity, undrained heating.


RSC Advances ◽  
2014 ◽  
Vol 4 (94) ◽  
pp. 52349-52356 ◽  
Author(s):  
Yuehan Wu ◽  
Xingzhong Zhang ◽  
Bin Li ◽  
Shilin Liu

Highly transparent and flexible silica/cellulose films with low thermal expansion coefficients have been prepared by the in situ synthesis of silica in cellulose scaffolds using Na2SiO3 as a precursor.


2016 ◽  
Vol 30 (11) ◽  
pp. 1650127 ◽  
Author(s):  
Yi Ren ◽  
Wen Ma ◽  
Xiaoying Li ◽  
Jun Wang ◽  
Yu Bai ◽  
...  

The SOFC interconnect materials La[Formula: see text]Sr[Formula: see text]Cr[Formula: see text]O[Formula: see text] [Formula: see text]–[Formula: see text] were prepared using an auto-ignition process. The influences of Cr deficiency on their sintering, thermal expansion and electrical properties were investigated. All the samples were pure perovskite phase after sintering at 1400[Formula: see text]C for 4 h. The cell volume of La[Formula: see text]Sr[Formula: see text]Cr[Formula: see text]O[Formula: see text] decreased with increasing Cr deficient content. The relative density of the sintered bulk samples increased from 93.2% [Formula: see text] to a maximum value of 94.7% [Formula: see text] and then decreased to 87.7% [Formula: see text]. The thermal expansion coefficients of the sintered bulk samples were in the range of [Formula: see text]–[Formula: see text] (30–1000[Formula: see text]C), which are compatible with that of YSZ. Among the investigated samples, the sample with 0.02 Cr deficiency had a maximum conductivity of 40.4 Scm[Formula: see text] and the lowest Seebeck coefficient of 154.8 [Formula: see text]VK[Formula: see text] at 850[Formula: see text]C in pure He. The experimental results indicate that La[Formula: see text]Sr[Formula: see text]Cr[Formula: see text]O[Formula: see text] has the best properties and is much suitable for SOFC interconnect material application.


2006 ◽  
Vol 947 ◽  
Author(s):  
Kyung Choi

ABSTRACTHigh resolution pattern transfers in the nano-scale regime have been considerable challenges in ‘soft lithography’ to achieve nanodevices with enhanced performances. In this technology, the resolution of pattern integrations is significantly rely on the materials' properties of polydimethylsiloxane (PDMS) stamps. Since commercial PDMS stamps have shown limitations in nano-scale resolution soft lithography due to their low physical toughness and high thermal expansion coefficients, we developed stiffer, photocured PDMS silicon elastomers designed, specifically for nano-sized soft lithography and photopatternable nanofabrications.


1985 ◽  
Vol 82 (3) ◽  
pp. 1611-1612 ◽  
Author(s):  
Stanley L. Segel ◽  
H. Karlsson ◽  
T. Gustavson ◽  
K. Edstrom

Author(s):  
Jonathan B. Hopkins ◽  
Lucas A. Shaw ◽  
Todd H. Weisgraber ◽  
George R. Farquar ◽  
Christopher D. Harvey ◽  
...  

The aim of this paper is to introduce an approach for optimally organizing a variety of different unit cell designs within a large lattice such that the bulk behavior of the lattice exhibits a desired Young’s modulus with a graded change in thermal expansion over its geometry. This lattice, called a graded microarchitectured material, can be sandwiched between two other materials with different thermal expansion coefficients to accommodate their different expansions or contractions caused by changing temperature while achieving a desired uniform stiffness. First, this paper provides the theory necessary to calculate the thermal expansion and Young’s modulus of large multi-material lattices that consist of periodic (i.e., repeating) unit cells of the same design. Then it introduces the theory for calculating the graded thermal expansions of a large multimaterial lattice that consists of non-periodic unit cells of different designs. An approach is then provided for optimally designing and organizing different unit cells within a lattice such that both of its ends achieve the same thermal expansion as the two materials between which the lattice is sandwiched. A MATLAB tool is used to generate images of the undeformed and deformed lattices to verify their behavior and various examples are provided as case studies. The theory provided is also verified and validated using finite element analysis and experimentation.


Sign in / Sign up

Export Citation Format

Share Document