scholarly journals RECOGNIZING PORPHYRY COPPER POTENTIAL FROM TILL ZIRCON COMPOSITION: A CASE STUDY FROM THE HIGHLAND VALLEY PORPHYRY DISTRICT, SOUTH-CENTRAL BRITISH COLUMBIA

2021 ◽  
Author(s):  
Robert G. Lee ◽  
Alain Plouffe ◽  
Travis Ferbey ◽  
Craig J.R. Hart ◽  
Pete Hollings ◽  
...  

Abstract The detrital zircons in tills overlying the Guichon Creek batholith, British Columbia, Canada, have trace element concentrations and ages similar to those of zircons from the bedrock samples from which they are interpreted to have been sourced. Rocks from the core of the batholith that host porphyry copper mineralization have distinct zircon compositions relative to the distal, barren margin. We analyzed 296 zircons separated from 12 subglacial till samples to obtain U-Pb ages and trace element compositions. Laser ablation U-Pb ages of the detrital zircons overlap within error with chemical abrasion-thermal ionization mass spectrometry U-Pb ages of the Late Triassic Guichon Creek batholith and confirm that the detrital zircons are likely derived from the batholith. The youngest intrusions of the batholith produced the Highland Valley Copper porphyry deposits and contain distinctive zircons with elevated Eu/EuN* >0.4 attributed to high magmatic water contents and oxidation states, indicating higher porphyry copper potential. Zircon from till samples adjacent to and 9 km down-ice from the mineralized centers have mean Eu/EuN* >0.4, which are indicative of potential porphyry copper mineralization. Detrital zircon grains from more distal up- and down-ice locations (10–15 km) have zircon Eu/EuN* mean values of 0.26 to 0.37, reflecting background values. We conclude that detrital zircon compositions in glacial sediments transported several kilometers can be used to establish the regional potential for porphyry copper mineralization.

2020 ◽  
Vol 115 (7) ◽  
pp. 1413-1442
Author(s):  
Nikolett Kovacs ◽  
Murray M. Allan ◽  
James L. Crowley ◽  
Maurice Colpron ◽  
Craig J.R. Hart ◽  
...  

Abstract Late Triassic to Early Jurassic porphyry Cu mineralization is common in British Columbia, yet there are few age-equivalent porphyry occurrences in Yukon. This study presents new data for the enigmatic Carmacks Copper Cu-Au-Ag deposit in south-central Yukon, Canada, which is hosted in amphibolite facies metamorphic inliers within the Early Jurassic Granite Mountain batholith. Sulfide mineralization occurs mainly as net-textured bornite and chalcopyrite in leucosome, and as chalcopyrite ± pyrite blebs and disseminations in amphibolite and quartz-plagioclase-biotite schist. Several studies suggest that the Carmacks Copper deposit and the nearby Minto deposit are related to porphyry belts in British Columbia, but constraining the timing of alteration, mineralization, and metamorphism has been difficult. This study establishes a geologic and high-precision geochronologic framework for sulfide mineralization and its host rocks at the Carmacks Copper deposit, using Re-Os dating of molybdenite, and chemical abrasion-thermal ionization mass spectrometry (CA-TIMS) analysis of both whole zircon grains and laser-cut fragments of complexly zoned zircon grains. Our data indicate that the igneous protolith of the metamorphic inliers formed at 217.53 ± 0.16 Ma, followed by peak metamorphism at amphibolite facies at 205.82 ± 0.23 Ma, which occurred prior to Granite Mountain batholith emplacement but subsequent to Cu-Au-Ag mineralization of the protolith. An early phase of the Granite Mountain batholith was emplaced at 199.84 ± 0.14 Ma, followed by the main phase at 195 to 194 Ma. A second generation of metamorphic zircon in migmatite at 196.01 ± 0.12 Ma represents a partial melting event associated with Granite Mountain batholith emplacement. Two petrographically distinct populations of molybdenite are present in unstrained, net-textured copper sulfides. A sample dominated by strained molybdenite yielded an 187Re/187Os age of 212.5 ± 1.0 Ma, which represents the minimum mineralization age of the protolith. A sample dominated by euhedral grains yielded an 187Re/187Os age of 198.5 ± 0.9 Ma, constraining the maximum age of sulfide remobilization. These results indicate that primary mineralization is >212.5 Ma and potentially coeval with the ~217.5 Ma generation of Late Triassic magmatism. The mineralized protolith, best interpreted as the potassic alteration zone of a Late Triassic (~217–213 Ma) porphyry Cu-Au system, was metamorphosed to amphibolite facies at ~206 Ma, and subsequently migmatized during 200 to 194 Ma intrusion of the Granite Mountain batholith. The chalcopyrite-bornite-dominant assemblage in neosome precipitated from an immiscible Cu-Fe-S melt phase that partly consumed xenocrystic molybdenite and reprecipitated new molybdenite grains. The Carmacks Copper deposit and the related Minto deposit are remnants of a Late Triassic porphyry belt, where a significant fraction of the original metal endowment was likely lost through digestion of mineralized rocks by midcrustal magma in the Early Jurassic. These Yukon deposits are rare examples of metamorphosed porphyry Cu systems in the global geologic record, where rapid tectonic burial following mineralization was the principal factor in their preservation.


2001 ◽  
Vol 38 (4) ◽  
pp. 639-655 ◽  
Author(s):  
D G MacIntyre ◽  
M E Villeneuve

New U/Pb and 40Ar/39Ar isotopic dating in the Babine porphyry copper district of central British Columbia documents three distinct magmatic events at 107–104, 85–78, and 54–50 Ma. The earliest event involved emplacement of rhyolite domes into submarine volcanic rocks of the Rocky Ridge Formation. The rhyolite domes and related dacitic to basaltic volcanic rocks gave a U–Pb age of 107.9 ± 0.2 Ma and an 40Ar/39Ar age of 104.8 ± 1.2 Ma. The rhyolites, which were previously mapped as Eocene, are reinterpreted to be part of a previously unrecognized mid-Cretaceous cauldron subsidence complex. The regionally extensive Late Cretaceous magmatic event is also recognized in the Babine district and is represented by 40Ar/39Ar ages of 85.2 ± 2.8 and 78.3 ± 0.8 Ma on two Bulkley intrusions, one of which has associated porphyry copper mineralization. The final magmatic event is the most widespread and involved emplacement of the Babine intrusions and formation of numerous porphyry copper deposits including the Bell and Granisle past producers. Twenty-one new 40Ar/39Ar isotopic ages for these intrusions and coeval andesites of the Newman Formation have a narrow range from 53.6 ± 0.9 to 49.9 ± 0.6 Ma, whereas previous K–Ar isotopic dating had a possible range of 15 Ma. The mid-Cretaceous, Late Cretaceous, and Eocene magmatic suites in the Babine district are interpreted to be part of a long-lived volcano-plutonic complex that was the site of periodic magmatism and porphyry copper mineralization over a 60 Ma time period. This complex may have evolved within a zone of extension (pull-apart basins) situated between dextral strike-slip faults that were active during periods of rapid oblique plate convergence.


2017 ◽  
Vol 81 ◽  
pp. 1158-1171 ◽  
Author(s):  
L.H. Ochoa-Landín ◽  
M. Valencia-Moreno ◽  
T. Calmus ◽  
R. Del Rio-Salas ◽  
H. Mendívil-Quijada ◽  
...  

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