Plasticity Measurements in the Rubber Industry

1933 ◽  
Vol 6 (2) ◽  
pp. 244-260
Author(s):  
J. Behre

Abstract With the growing realization of its importance in factory operations, the plasticity of raw rubber and rubber stocks is being studied more and more. As far as can be seen from the literature, four methods for measuring plasticity are known up to the present time. The most commonly used apparatus is probably that developed by Williams, which depends upon measuring the change in the thickness of rubber under a load. The same principle is followed in the recently published method of Karrer, except that in this case the elastic recovery is also measured. The other two methods, which were used first by Marzetti and by Griffith, depend on the other hand upon a wholly different principle. Here the rubber or the rubber mixture is extruded through a narrow opening under high pressure and the quantity extruded is measured. Griffith used a dead weight whereas Marzetti used compressed air to produce the pressure. For several years the author has worked with an apparatus constructed according to the Marzetti principle, and the present paper deals with experiments with this apparatus.

PeerJ ◽  
2016 ◽  
Vol 4 ◽  
pp. e2020 ◽  
Author(s):  
Daniela Campaniello ◽  
Antonio Bevilacqua ◽  
Milena Sinigaglia ◽  
Maria Rosaria Corbo

Ultrasound (US), Thermo-sonication (TS) and High Pressure Homogenization (HPH) were studied as tools to inactivate the spores ofPenicilliumspp. andMucorspp. inoculated in distilled water. For US, the power ranged from 40% to 100%, pulse from 2 to 10 s, and duration of the treatment from 2 to 10 min. TS was performed combining US (40–80% of power, for 8 min and pulse of 2 s) with a thermal treatment (50, 55 and 60°C at 4, 8 and 12 min). Homogenization was done at 30–150 MPa for 1, 2 and 3 times. Power was the most important factors to determine the antifungal effect of US and TS towards the conidia ofPenicilliumspp.; on the other hand, in US treatmentsMucorspp. was also affected by pulse and time. HPH exerted a significant antifungal effect only if the highest pressures were applied for 2–3 times.


1905 ◽  
Vol 74 (497-506) ◽  
pp. 20-30 ◽  
Author(s):  
William Napier Shaw

In the course of an investigation into the trajectories, or actual paths of air, by means of synoptic charts, which is still in progress,* it became apparent that the paths of air taking part in cyclonic dis­turbances near the British Isles when traced backward did not always originate in anti-cylonic areas, but followed a track skirting the neighbouring high-pressure areas and traversing sometimes a very large part of a belt of the earth in a direction more or less parallel to a line of latitude, and, on the other hand, air moving in the neighbour­hood of a cyclonic depression did not invariably seek the nearest baro­metric minimum, but sometimes passed on, leaving the circulation of the depression on the left hand.


2000 ◽  
Vol 66 (6) ◽  
pp. 2290-2296 ◽  
Author(s):  
Yasuo Kato ◽  
Ryoko Ooi ◽  
Yasuhisa Asano

ABSTRACT The distribution of phenylacetaldoxime-degrading and pyridine-3-aldoxime-degrading ability was examined with intact cells of 975 microorganisms, including 45 genera of bacteria, 11 genera of actinomyces, 22 genera of yeasts, and 37 genera of fungi, by monitoring the decrease of the aldoximes by high-pressure liquid chromatography. The abilities were found to be widely distributed in bacteria, actinomyces, fungi, and some yeasts: 98 and 107 strains degraded phenylacetaldoxime and pyridine-3-aldoxime, respectively. All of the active strains exhibited not only the aldoxime-dehydration activity to form nitrile but also nitrile-hydrolyzing activity. On the other hand, all of 19 nitrile-degrading microorganisms (13 species, 7 genera) were found to exhibit aldoxime dehydration activity. It is shown that aldoxime dehydratase and nitrile-hydrolyzing activities are widely distributed among 188 aldoxime and 19 nitrile degraders and that the enzymes were induced by aldoximes or nitriles.


1946 ◽  
Vol 19 (1) ◽  
pp. 123-124
Author(s):  
A. Haehl

Abstract It might at first be assumed that antioxygenic compounds originally present in scrap rubber used in the manufacture of the reclaimed rubber would be sufficient to explain the extraordinary resistance of the reclaimed rubber to the action of proöxygenic compounds. It is, however, highly improbable that these antioxygenic compounds survive caustic soda treatment at 190° C. On the other hand, a crude-rubber mixture, even when protected by an antioxygenic compound, never shows such great resistance to proöxygenic compounds as that shown by the reclaimed-rubber vulcanizates described in the present work. It seems probable, therefore, that this insensitivity of reclaimed rubber to proöxygenic compounds, both during plasticization and during aging after vulcanization, is in some way connected with the actual chemical structure of the reclaimed rubber itself.


2021 ◽  
pp. 009524432110061
Author(s):  
Neşe Kaynak ◽  
Sinan Şen

In this work, the effects of using feldspar (FLD) as an alumina-silicate inorganic filler, with carbon black (CB) as a novel binary filler system, on the properties of SBR compounds were investigated for tire applications. The bis(triethoxysilylpropyl) disulfide (TESPD) was used for modification of FLD. The SBR hybrid composites were produced by replacing 10 phr of CB filler with neat FLD and functionalized FLD (F-FLD). The TESPD was added directly to the rubber mixture including neat FLD. The SBR composite which has only CB filler (50CB) was found to have the highest damping parameter (tan δ) value at 60°C. On the other hand, the composites loaded with the CB and the FLD fillers exhibited relatively lower tan δ at the same temperature showing lower rolling resistance meaning better fuel saving performance. The lowest rolling resistance was achieved for the 40CB-10F-FLD most probably due to its stronger interaction with the SBR elastomer molecules through the silane agent-assisted crosslinks of the F-FLD. As another dynamic property, the storage moduli at −20°C were found to be lower for the SBR hybrid composites as compared to that of the 50CB composite, exhibiting enhanced winter traction performance of the composites having FLD filler together with CB. The composites containing only 10 phr of FLD and F-FLD, on the other hand, exhibited very low tensile strength values which are not acceptable for tire tread materials.


In a previous paper experiments were described in which the writer’s English vowel sounds were reproduced by means of double resonators tuned to give the two principal audible resonances heard when whispering or breathing the vowel in question. It was found that various consonant sounds could be produced by manipulating these models, as had been previously done by Kratzenstein, de Kempelen, Willis, and Wheatstone, in the case of a single resonator, but that all models did not behave similarly. Complete closure (by hand) and sudden release, under air pressure, of the ei (hay), a (calm), D (not), ou (no), and u (who) models, gave b at low pressure and p at high pressure. Partial closure (allowing a small leakage sufficient to enable the artificial larynx to operate) followed by rapid release, gave m . On the other hand, the same manipulation of the models i (eat), I (it), e (men), A (up), gave a sound like that of w in we, wit, wen, etc.


Author(s):  
Brandon Wee

TORONTO INTERNATIONAL FILM FESTIVALToronto’s 38th edition (5–15 September 2013) was as big and diverse as its ambitions allowed, but its stubborn public image partial to Euro-American content continues to weaken its “international” status. The festival hasn’t struck a respectable balance between indulging the puffery of dominant film industries and supporting lesser-known cinemas. Indeed, this year’s milestones went largely unplugged. There were encores: at least five directors – Hong Sang-soo, Kurosawa Kiyoshi, Kim Ki-duk, Brillante Mendoza and Sono Sion – returned with films for the second year running. There was discontinuity: Miyazaki Hayao and Tsai Ming-liang delivered what could be their last features after retiring. There was politics that ordained merit: no film was as insincerely hyped as 12 Years a Slave, Steve McQueen’s take on Solomon Northup’s 1853 autobiography about chattel slavery – a lifeless adaptation writ large given this skeleton’s dead weight. On the other hand,...


The object of the experiments related in this paper, is to trace the source of the electricity which accompanies the issue of steam of high pressure from the vessels in which it is contained. By means of a suitable apparatus, which the author describes and delineates, he found that electricity is never excited by the passage of pure steam, and is manifested only when water is at the same time present; and hence he concludes that it is altogether the effect of the friction of globules of water against the sides of the opening, or against the substances opposed to its passage, as the water is rapidly moved onwards by the current of steam. Accordingly it was found to be increased in quantity by increasing the pressure and impelling force of the steam. The immediate effect of this friction was, in all cases, to render the steam or water positive, and the solids, of whatever nature they might be, negative. In certain circumstances, however, as when a wire is placed in the current of steam at some distance from the orifice whence it has issued, the solid exhibits the positive electricity already acquired by the steam, and of which it is then merely the recipient and the conductor. In like manner, the results may be greatly modified by the shape, the nature, and the temperature of the passages through which the steam is forced. Heat, by preventing the condensation of the steam into water, likewise prevents the evolution of electricity, which again speedily appears by cooling the passages so as to restore the water which is necessary for the production of that effect. The phenomenon of the evolution of electricity in these circumstances is dependent also on the quality of the fluid in motion, more especially in relation to its conducting power. Water will not excite electricity unless it be pure ; the addition to it of any soluble salt or acid, even in minute quantity, is sufficient to destroy this property. The addition of oil of turpentine, on the other hand, occasions the development of electricity of an opposite kind to that which is excited by water ; and this the author explains by the particles or minute globules of the water having each received a coating of oil in the form of a thin film, so that the friction takes place only between that external film and the solids, along the surface of which the globules are carried. A similar, but a more permanent effect is produced by the presence of olive oil, which is not, like oil of turpentine, subject to rapid dissipation. Similar results were obtained when a stream of compressed air was substituted for steam in these experiments. When moisture was present, the solid exhibited negative, and the stream of air positive electricity ; but when the air was perfectly dry, no electricity of any kind was apparent. The author concludes with an account of some experiments in which dry powders of various kinds were placed in the current of air; the results differed according to the nature of the substances employed, and other circumstances.


1999 ◽  
Vol 173 ◽  
pp. 249-254
Author(s):  
A.M. Silva ◽  
R.D. Miró

AbstractWe have developed a model for theH2OandOHevolution in a comet outburst, assuming that together with the gas, a distribution of icy grains is ejected. With an initial mass of icy grains of 108kg released, theH2OandOHproductions are increased up to a factor two, and the growth curves change drastically in the first two days. The model is applied to eruptions detected in theOHradio monitorings and fits well with the slow variations in the flux. On the other hand, several events of short duration appear, consisting of a sudden rise ofOHflux, followed by a sudden decay on the second day. These apparent short bursts are frequently found as precursors of a more durable eruption. We suggest that both of them are part of a unique eruption, and that the sudden decay is due to collisions that de-excite theOHmaser, when it reaches the Cometopause region located at 1.35 × 105kmfrom the nucleus.


Author(s):  
A. V. Crewe

We have become accustomed to differentiating between the scanning microscope and the conventional transmission microscope according to the resolving power which the two instruments offer. The conventional microscope is capable of a point resolution of a few angstroms and line resolutions of periodic objects of about 1Å. On the other hand, the scanning microscope, in its normal form, is not ordinarily capable of a point resolution better than 100Å. Upon examining reasons for the 100Å limitation, it becomes clear that this is based more on tradition than reason, and in particular, it is a condition imposed upon the microscope by adherence to thermal sources of electrons.


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