Natural and Synthetic Rubber. VI. the Pyrolysis of Natural Rubber in the Presence of Metallic Oxides

1931 ◽  
Vol 4 (1) ◽  
pp. 98-99
Author(s):  
Thomas Midgley ◽  
Albert L. Henne
Keyword(s):  
Zinc Oxide ◽  
Natural Rubber ◽  
Magnesium Oxide ◽  
Double Bonds ◽  
Decomposition Products ◽  
Metallic Oxides ◽  
Synthetic Rubber ◽  
Natural And Synthetic

Abstract Pale crepe rubber pyrolyzed in the presence of zinc oxide or magnesium oxide gives the same decomposition products as in the absence of the oxides, but in different proportions. This modification is attributed to an action of the oxides upon the double bonds of the rubber molecule.

Natural and Synthetic Rubber. I. Products of the Destructive Distillation of Natural Rubber

1929 ◽  
Vol 2 (3) ◽  
pp. 441-451 ◽  
Author(s):  
Thomas Midgley ◽  
Albert L. Henne
Keyword(s):  
Experimental Data ◽  
Natural Rubber ◽  
Atmospheric Pressure ◽  
Experimental Results ◽  
Double Bonds ◽  
Synthetic Rubber ◽  
Single Bonds ◽  
Natural And Synthetic

Abstract Two hundred pounds of pale crepe rubber have been destructively-distilled at atmospheric pressure. The distillate was fractionated and its components identified from C5 to C10, as shown in the table. Assuming that the Staudinger formula is correct, that the single bonds furthest from the double bonds are the weaker spots and that the formation of six-carbon rings is favored, it has been shown that nearly all of the compounds actually isolated could be predicted. The experimental results, together with forthcoming experimental data, are expected to be used to throw light upon the formula of the rubber molecule.

scholarly journals Historical and Recent Achievements in the Field of Microbial Degradation of Natural and Synthetic Rubber

2012 ◽  
Vol 78 (13) ◽  
pp. 4543-4551 ◽  
Author(s):  
Meral Yikmis ◽  
Alexander Steinbüchel
Keyword(s):  
Natural Rubber ◽  
Microbial Degradation ◽  
Environmental Biotechnology ◽  
Gram Positive ◽  
Gram Negative ◽  
Content Type ◽  
Key Enzymes ◽  
Degrading Bacterium ◽  
Synthetic Rubber ◽  
Natural And Synthetic

ABSTRACTThis review intends to provide an overview of historical and recent achievements in studies of microbial degradation of natural and synthetic rubber. The main scientific focus is on the key enzymes latex-clearing protein (Lcp) from the Gram-positiveStreptomycessp. strain K30 and rubber oxygenase A (RoxA) from the Gram-negativeXanthomonassp. strain 35Y, which has been hitherto the only known rubber-degrading bacterium that does not belong to the actinomycetes. We also emphasize the importance of knowledge of biodegradation in industrial and environmental biotechnology for waste natural rubber disposal.

Kinetic Analysis of Organic Halides. II. Analysis of Macromolecules Built up of Monohalide Units

1951 ◽  
Vol 24 (2) ◽  
pp. 436-446 ◽  
Author(s):  
G. Salomon ◽  
C. Koningsberger
Keyword(s):  
Natural Rubber ◽  
Kinetic Analysis ◽  
Vinyl Chloride ◽  
Physical Factors ◽  
Organic Bases ◽  
Synthetic Rubber ◽  
Organic Halides ◽  
First Time ◽  
Natural And Synthetic

Abstract A number of hydrochlorides of natural and synthetic rubbers and allied polymers have been prepared and subjected to kinetic analysis with organic bases. The hydrochlorides of natural rubber react at 100° C at a rate identical to that of low-molecular tertiary chlorides. At 50° C the reactivity of the polymer is, however, reduced by physical factors. The hydrochloride of GR-S (a synthetic rubber made from butadiene and styrene) has been prepared for the first time by heating the swollen polymer with HC1 under pressure. Kinetic analysis of this product revealed two fractions: the expected secondary chloride, and a small fraction of a very reactive (tertiary?) chloride. After elimination of experimental difficulties, we succeeded in the preparation and kinetic identification of the pure tertiary hydrobromide of natural rubber. Attempts to prepare the secondary bromide under peroxide conditions failed. Kinetic analysis of two types of Neoprene revealed the presence of a small quantity of allylic groups in the polymer, while 95 per cent of the chlorine in Neoprene has the expected stability of a vinyl chloride. This stability can be used for the identification of Neoprene.

Plasma Polymerized Primers for Rubber to Metal Bonding: Characterization of the Interphase

1995 ◽  
Vol 385 ◽  
Author(s):  
Y. M. Tsai ◽  
F. J. Boerio ◽  
Dong K. Kim
Keyword(s):  
Zinc Oxide ◽  
Free Radicals ◽  
Carbon Black ◽  
Stearic Acid ◽  
Natural Rubber ◽  
Rubber Compound ◽  
Carbonyl Groups ◽  
Double Bonds ◽  
Metal Bonding

ABSTRACTPlasma polymerized acetylene films contained mono- and di-substituted acetylene groups, aromatic groups, and carbonyl groups which resulted from reaction of residual free radicals with oxygen when the films were exposed to the atmosphere. There was some evidence for formation of acetylides in the interphase between the films and the substrates. Reactions occurring in the interphase between the plasma polymerized films and natural rubber were simulated using a model rubber compound consisting of a mixture of squalene, zinc oxide, carbon black, sulfur, stearic acid, diaryl-p-diphenyleneamine, and N,N-dicyclohexylbenzothiazole sulfenamide (DCBS). Zinc oxide and cobalt naphthenate reacted with stearic acid to form zinc and cobalt stearates. The stearates reacted with the benzothiazole sulfonamide moiety of DCBS and with sulfur to form zinc and cobalt accelerator complexes and perthiomercaptides. The complexes and perthiomercaptides reacted with squalene and the plasma polymer to form pendant groups which eventually disproportionated to form crosslinks between squalene and the primer. Migration of double bonds during reaction of the model rubber compound with the films resulted in formation of conjugated double bonds in squalene.

Liquid guayule natural rubber, a renewable and crosslinkable processing aid in natural and synthetic rubber compounds

2020 ◽  
Vol 276 ◽  
pp. 122933
Author(s):  
Xianjie Ren ◽  
Cindy S. Barrera ◽  
Janice L. Tardiff ◽  
Andres Gil ◽  
Katrina Cornish
Keyword(s):  
Natural Rubber ◽  
Synthetic Rubber ◽  
Rubber Compounds ◽  
Natural And Synthetic

Natural and Synthetic Rubber. XV. Oxygen in Rubber

1936 ◽  
Vol 9 (1) ◽  
pp. 74-82
Author(s):  
Thomas Midgley ◽  
A. L. Henne ◽  
A. F. Shepard ◽  
Mary W. Renoll
Keyword(s):  
Natural Rubber ◽  
Quantitative Data ◽  
Hydroxyl Group ◽  
Synthetic Rubber ◽  
Natural And Synthetic

Abstract It has been shown that natural rubber conthins oxygen, while synthetic rubber is oxygen free. This oxygen appears to be of an hydroxylic type, and its quantity corresponds to about one hydroxyl group for each one thousand isoprene units of the rubber molecule. Rubber has been allowed to oxidize and a mechanism is proposed to interpret the quantitative data recorded.

Effect of Temperature on Resilience of Natural and Synthetic Rubber

1943 ◽  
Vol 16 (4) ◽  
pp. 881-887
Author(s):  
H. C. Jones ◽  
E. G. Snyder
Keyword(s):  
Natural Rubber ◽  
Effect Of Temperature ◽  
Synthetic Rubber ◽  
Natural And Synthetic

Abstract The necessity of the substitution of synthetic elastomers for natural rubber has been forced on the rubber compounder by the exigencies of war. His background of a hundred years of research and compounding is his principal weapon for making this conversion in the shortest possible time. Too often he finds that this background fails and that practices invaluable in the development of natural rubber stocks are worthless in the case of synthetic rubber, or at least are subject to a different interpretation.

Lignin as a Compounding Ingredient for Natural Rubber

1957 ◽  
Vol 30 (2) ◽  
pp. 639-651 ◽  
Author(s):  
I. Sagajllo
Keyword(s):  
Natural Rubber ◽  
High Resistance ◽  
Pilot Plant ◽  
Test Results ◽  
Dry Powder ◽  
Synthetic Rubber ◽  
Rubber Compounds ◽  
Pilot Plant Scale ◽  
Made In ◽  
Natural And Synthetic

Abstract Important claims have been made in recent years regarding the capacity of lignin to reinforce natural and synthetic rubber. In 1949 Dawson reviewed the literature on the use of lignin in rubber and drew particular attention to the work of Keilen and Pollak who had shown that in certain circumstances lignin could be considered to rival EPC black in its ability to yield strong GR-S vulcanizates with high resistance to tear. Raff and his coworkers subsequently showed that the reinforcement of GR-S by lignin is enhanced if the lignin, before coprecipitation with the latex, is subjected to oxidation; other workers studied the application of lignin to the reinforcement of different elastomers, the influence of coprecipitation conditions on the properties of the product, and the problem of overcoming the delaying effect of lignin on vulcanization of lignin-natural rubber coprecipitates. Keilen and Pollak in their experiments incorporated lignin into rubber by coprecipitation at the latex stage, but they indicated that similar results could be obtained if lignin “in the gelled state” was added to rubber by milling. No reinforcement was observed however when lignin was added to rubber as a dry powder. Lignin is potentially an abundant and cheap material which according to the above claims should extend the range of useful compounds available to rubber manufacturers. The present paper describes work undertaken to gain firsthand knowledge of the technique of coprecipitating lignin with natural rubber from preserved latex, to learn something about the properties of natural rubber compounds prepared from lignin coprecipitates, and to study possible ways of incorporating lignin into rubber by means other than coprecipitation. It also records test results for masterbatches prepared by the Rubber Research Institute of Malaya from fresh latex on a pilot plant scale.

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