The Formulation of Nonburning Elastomer Compounds

1973 ◽  
Vol 46 (4) ◽  
pp. 1114-1125 ◽  
Author(s):  
H. E. Trexler

Abstract In this investigation the flammability of 34 polymers was evaluated in 68 compounds; 28 flame retardants were tested in 275 compounds. Only two of 34 polymers evaluated as black-filled compositions were nonburning in the initial screening, five were self-extinguishing, and the rest were completely combustible. Twenty-three of the 32 combustible and self-extinguishing polymers were reformulated into nonburning polymers by the addition of two flame retardants—antimony oxide and either Chlorowax 70 or Dechlorane 515 (Table XIII). Frequently a plasticizer was required. If Chlorowax is compatible with the polymer, it often acts as a plasticizer. Fyrol FR—2 was the only other plasticizer found to be compatible with most polymers and permitting them to retain their nonburning classification.

1975 ◽  
Vol 29 (6) ◽  
pp. 512-517 ◽  
Author(s):  
G. A. Pasteur ◽  
H. Schonhorn

Three new organo-antimony flame retardants which are insoluble in strong acid media have been prepared by the interaction of silanes with antimony oxide using three different procedures. These compounds have been characterized by infrared spectroscopy.


Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 42
Author(s):  
Hyelim Kim ◽  
Ji-Su Kim ◽  
Wonyoung Jeong

Antimony oxide (ATO) is used mainly as a flame retardant, but it is classified as a hazardous substance. Therefore, regulations on the use of antimony trioxide (ATO(3)) and antimony pentoxide (ATO(5)) in textile products are being developed. Accordingly, there is a need for alternative flame retardants. In this study, antimony tetroxide (ATO(4)), which has higher thermal stability and resistance to acids and alkalis than ATO(3) or ATO(5), was selected to assess its use as an alternative flame retardant. First, ATO(3) or ATO(4) were added to poly(acrylonitrile-co-vinylidene chloride) (PANVDC), and the film and wet-spun fiber were prepared. The PANVDC film with flame retardants was prepared to evaluate the flame retardancy and the mechanism of action of the flame retardants. Flame retardancy analysis showed that a limiting oxygen index of 31.2% was obtained when ATO(4) was added, which was higher than when ATO(3) was used. Subsequently, PANVDC fibers with antimony oxide were manufactured and showed improved mechanical and thermal properties when ATO(4) was used, compared to when ATO(3) was tested. In addition, migration analysis due to antimony in the fiber confirmed that the elution amount was below the acceptable standard when PANVDC fibers with ATO(4) were added. Therefore, based on these results, the flame-retardant and thermal properties of antimony tetroxide were superior to antimony trioxide, and it was confirmed that ATO(4) could be used as an alternative flame retardant to ATO(3).


2004 ◽  
Vol 171 (4S) ◽  
pp. 118-119
Author(s):  
Kazuto Ito ◽  
René Raaijmakers ◽  
Monique J. Roobol ◽  
Mark F. Wildhagen ◽  
Hidetoshi Yamanaka ◽  
...  

2004 ◽  
Author(s):  
Kevin D. Carlson ◽  
Mary L. Connerley ◽  
Arlise P. McKinney ◽  
Ross L. Mecham

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