Tensile Tests of Plantation Rubber

1940 ◽  
Vol 13 (3) ◽  
pp. 451-467
Author(s):  
I. Slbiriakoff

Abstract The investigation which has just been described can be summarized as follows: (1) A technique for the commercial testing of plantation rubber has been developed which is simple and precise, and by means of which it is possible to reproduce control tests, a feature which is indispensable if rubber is to be sold on a basis of quality rather than superficial appearance. (2) The tentative specifications for testing rubber drawn up by the Crude Rubber Committee of the Division of Rubber Chemistry of the American Chemical Society have been found acceptable as a basis for this testing procedure. (3) It has been found necessary, however, to revise the specifications of the Crude Rubber Committee in some ways and to amplify them, so that they fulfill the three conditions described above and also conform to the particular working conditions of laboratories in the tropics. The revisions to the Crude Rubber Committee specifications include: (1) The use of an autoclave for vulcanizing in open steam. (2) A mill roll temperature of 65° C instead of 70° C. (3) A definite, fixed weight of batch, containing 200 grams of rubber, plus accessory ingredients. (4) A temperature of 25° to 30° C during testing. (5) The use of ring test-specimens instead of dumb-bell specimens.

1938 ◽  
Vol 11 (1) ◽  
pp. 214-223
Author(s):  
R. Ariano

Abstract It is of course a well known fact that both ring test-specimens and flat or straight test-specimens are used in testing rubber. Ring test-specimens have for a long time been the most generally used type for testing rubber mixtures, whereas in American laboratories straight test-specimens are preferred. Ring test-specimens are the more convenient to use, but they are open to one fundamental objection, that different parts of the cross section of the rubber are elongated to different extents at any particular moment. Even straight test-specimens are not free from objectionable features. With this type of test-specimen, the inequality in the deformation at any particular instant results from the necessity of having enlarged ends for the testing machine to avoid breakage of the test-specimens in the jaws. It therefore becomes necessary to study systematically the form and dimensions of the end sections of the test-specimens and of the junction of these end sections with the central section, so that the points of rupture will not become localized in the sections in the jaws or close to these sections. As a matter of fact, an extensive investigation of this problem has been made by the Physical Testing Committee of the Rubber Division of the American Chemical Society. By a proper study of the shape of the test-specimen, it is possible to design the test-specimen so that rupture occurs in the center section and therefore so that satisfactory tensile strength measurements are obtained.


1932 ◽  
Vol 5 (3) ◽  
pp. 351-355 ◽  
Author(s):  
M. Jones

Abstract The evaluation of rubber has centered largely around stress-strain phenomena, and the property of tensile strength is probably the one which has the most general application throughout the industry. Rubber exhibits stress-strain properties quite different from the majority of substances, and peculiar difficulties are introduced during the determination of tensile strength. Although tentative standards have recently been issued by the American Chemical Society, there is no evidence that these are being strictly adhered to, and there is still need for a more rigid standardization of tensile-testing methods. There are essentially two methods of tensile-testing: (1) Using dumb-bell test-pieces with a Bureau of Standards machine, or a Scott type of machine; and (2) Using ring test-pieces with a Schopper type of machine. It is generally supposed that higher tensile results are obtained by the former method. Recently, occasion has occurred to make a comparison between both types and to study the effect of certain factors upon each method.


2020 ◽  
Author(s):  
MAK Williams ◽  
V Cornuault ◽  
AH Irani ◽  
VV Symonds ◽  
J Malmström ◽  
...  

© 2020 American Chemical Society. Evidence is presented that the polysaccharide rhamnogalacturonan I (RGI) can be biosynthesized in remarkably organized branched configurations and surprisingly long versions and can self-assemble into a plethora of structures. AFM imaging has been applied to study the outer mucilage obtained from wild-type (WT) and mutant (bxl1-3 and cesa5-1) Arabidopsis thaliana seeds. For WT mucilage, ordered, multichain structures of the polysaccharide RGI were observed, with a helical twist visible in favorable circumstances. Molecular dynamics (MD) simulations demonstrated the stability of several possible multichain complexes and the possibility of twisted fibril formation. For bxl1-3 seeds, the imaged polymers clearly showed the presence of side chains. These were surprisingly regular and well organized with an average length of ∼100 nm and a spacing of ∼50 nm. The heights of the side chains imaged were suggestive of single polysaccharide chains, while the backbone was on average 4 times this height and showed regular height variations along its length consistent with models of multichain fibrils examined in MD. Finally, in mucilage extracts from cesa5-1 seeds, a minor population of chains in excess of 30 μm long was observed.


2020 ◽  
Vol 27 (35) ◽  
pp. 5970-6014 ◽  
Author(s):  
Md. Jawaid Akhtar ◽  
Mohammad Shahar Yar ◽  
Vinod Kumar Sharma ◽  
Ahsan Ahmed Khan ◽  
Zulphikar Ali ◽  
...  

This review presents the detailed account of factors leading to cancer and design strategy for the synthesis of benzimidazole derivatives as anticancer agents. The recent survey for cancer treatment in Cancer facts and figures 2017 American Chemical Society has shown progressive development in fighting cancer. Researchers all over the world in both developed and developing countries are in a continuous effort to tackle this serious concern. Benzimidazole and its derivatives showed a broad range of biological activities due to their resemblance with naturally occurring nitrogenous base i.e. purine. The review discussed benzimidazole derivatives showing anticancer properties through a different mechanism viz. intercalation, alkylating agents, topoisomerases, DHFR enzymes, and tubulin inhibitors. Benzimidazole derivatives act through a different mechanism and the substituents reported from the earlier and recent research articles are prerequisites for the synthesis of targeted based benzimidazole derivatives as anticancer agents. The review focuses on an easy comparison of the substituent essential for potency and selectivity through SAR presented in figures. This will further provide a better outlook or fulfills the challenges faced in the development of novel benzimidazole derivatives as anticancer.


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