The KOH-Number Test and Its Application to the Compounding of Zinc Oxide in Rubber Latex

1939 ◽  
Vol 12 (3) ◽  
pp. 590-603
Author(s):  
H. F. Jordan

Abstract 1. From measurements of the cataphoretic mobility of latex particles in potassium and calcium buffers, respectively, it has been calculated that in order to obtain high stability in latex compounds, the concentration of divalent ions must be of the order of 0.002 M or less. 2. Measurements of the cataphoretic mobility of latex particles suspended in solutions of constant zinc and ammonia concentrations indicate that in the presence of dissolved zinc oxide the stability of latex is increased with increasing pH above pH 9.6. This is attributed to conversion of divalent zinc ammonia ion (Zn(NH3)4++) into monovalent zinc ammonia hydroxide ion (Zn(NH3)3OH+). 3. A consideration of the mass action equations for zinc hydroxide and zinc ammonia hydroxide shows that the concentration of divalent zinc ion decreases rapidly as the ammonia concentration is reduced or as the pH is increased. 4. The EOH number of latex is defined as the number of grams of KOH per 100 grams of rubber corresponding to the end point (at pH 10.7–11) in the electrometric titration of latex with KOH. Experimental precautions in determining the KOH number are discussed. 5. Data are given which show that the KOH number of a normal latex may be reduced more than tenfold by creaming three times from 33% T.S. to 62% T.S. 6. The KOH numbers of commercially available normal latices have been found to vary between 1.2 and 2.4, and those of creamed or centrifuged latices between 0.55 and 0.95. 7. The amount of KOH for optimum stabilization (i.e., maximum stability, minimum viscosity and minimum change of properties with time) of zinc oxide compounds containing no added buffering ingredients varies with the latex, and is numerically equal to the KOH number. This quantity of KOH produces a pH of 10.7–11.0. 8. If appreciable amounts of protective ingredients such as casein, glue or gum arabic are added in compounding, sufficient additional KOH must be added to maintain a pH of 10.7–11 in the latex compound. The amounts of KOH required may be determined by electrometric titration of the protective ingredients.

2021 ◽  
Vol 72 (1) ◽  
pp. 18-24
Author(s):  
Noor Sabeeh Majeed ◽  
Hussein A. Alabdly ◽  
Hussam Nadum Abdalraheem Al Ani ◽  
Dumitru Pascu ◽  
Aurelia Cristina Nechifor

Stability of nanofluids is one of the most important factors to ensure the most benefit of the properties of nanoparticles. Zinc oxide was used in the research with concentration between (0.2-1) wt. % with ethylene glycol base fluid. The stability of ZnO nanofluid was enhanced by adding two types of surfactants Tx-100 and Gum Arabic with concentration of (0.1-0.5) vol. % to stabilize the ZnO nanoparticles in the base fluid. The results showed that the Gum Arabic surfactant led to more stable fluid than that of Tx-100; this was shown from zeta potential and UV spectroscopy measurements. The thermal conductivity coefficient was also measured, and the results showed that the thermal conductivity increased with adding surfactant than without using a stabilizer.


2006 ◽  
Vol 17 (9) ◽  
pp. 835-839 ◽  
Author(s):  
M. R. Towler ◽  
S. Kenny ◽  
D. Boyd ◽  
T. Pembroke ◽  
M. Buggy ◽  
...  
Keyword(s):  
Zinc Ion ◽  

2007 ◽  
Vol 7 (9) ◽  
pp. 1584-1589 ◽  
Author(s):  
Rafael Muñoz-Espí ◽  
Amreesh Chandra ◽  
Gerhard Wegner

2013 ◽  
Vol 718-720 ◽  
pp. 202-208 ◽  
Author(s):  
Mao Ai Chen ◽  
Yuan Ning Jiang ◽  
Chuan Song Wu

With high-speed welding inverter and precisely controlling the welding current with arc-bridge state, advanced pulse current waveforms can be produced to optimize the transfer characteristics of short circuiting transfer welding. In this paper, the images of droplet/wire, and the transient data of welding current and arc voltage were simultaneously recorded to study the influence of peak arcing current, background arcing current and tail-out time on the stability of short circuiting transfer process. It was found that maximum short circuiting transfer stability is reached under specific welding conditions. Any deviation from these conditions will cause abnormal rises in arc voltage indicating instantaneous arc extinguishing and greater spatter. Optimal welding conditions were obtained to achieve the maximum stability of short circuiting metal transfer process.


1997 ◽  
Vol 127 (3) ◽  
pp. 292-299 ◽  
Author(s):  
Yukiko Hanzawa ◽  
Daisuke Hiroishi ◽  
Chihiro Matsuura ◽  
Kenkichi Ishigure ◽  
Masashi Nagao ◽  
...  

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Glaucia A. Rocha-Selmi ◽  
Carmen S. Favaro-Trindade ◽  
Carlos R. F. Grosso

The interest in lycopene has increased in recent years due to studies that associate it with the reduction in risk of developing cardiovascular diseases and cancer. However, due to its high degree of unsaturation, this carotenoid is inclined to isomerize and oxidize during processing and storage, making it difficult to use in the food industry. Microencapsulation can improve this situation, increasing its stability and making incorporation into food formulations possible. Thus, the aim of this study was to microencapsulate lycopene by complex coacervation using gelatin and gum Arabic as the encapsulating agents. The microcapsules were evaluated based on the encapsulation efficiency and their morphology and then submitted to a stability test and applied in cake making. Most of the systems studied presented spherical microcapsules with defined walls. The encapsulation efficiency values were above 90%, and the average diameter of the capsules ranged from 61 to 144 μm. The stability test showed that microencapsulation offered greater protection to the lycopene as compared to its free form. The application of nonfreeze dried coacervated microcapsules in cake making was satisfactory, but the color transference was low when freezedried coacervated microcapsules were used.


2021 ◽  
Vol 10 (1) ◽  
pp. 37-40
Author(s):  
Vesna Savić ◽  
Milica Martinović ◽  
Ivana Nešić ◽  
Jelena Živković ◽  
Ivana Gajić

The aim of this study was to compare the stability and texture of three zinc oxide suspensions with different additives. Suspension 1 was made as official magistral formulation Suspensio album 7.5% from Formulae magistrales 2008. Suspension 2 was prepared when 1% carbomer gel was added to suspension 1 and suspension 3 was prepared when polysorbate 20 was added to suspension 2. After stability tests, texture analysis was performed on all suspensions. Following parameters were measured: hardness cycle 1, hardness cycle 2, cohesiveness, adhesiveness, resilience and springiness. The study showed that suspension 3 had the lowest value of hardness, and therefore the best spreadability. Also, suspension 3 was the least sticky of all three, since it was characterized with the lowest adhesiveness. Further, suspension 3 was the most cohesive and is predicted to withstand the stress during packing and use longer than others. On the other hand, the highest values of resilience and springiness were detected for suspension 1, while the lowest was related to suspension 2. Therefore, the best textural characteristics were assigned to suspension 3. This result is in accordance with the results of performed stability tests. The results of our study offer insight into potential improvements of the current magistral formulation Suspensio album 7.5%.


2021 ◽  
pp. 100-108
Author(s):  
В.И. Токарев ◽  
Н.В. Бабоченко

В статье представлены на рассмотрение характеристики стабильности работы стреловых грузоподъемных средств на колесном шасси в форме математических выражений. Математические выражения представлены в виде не громоздких зависимостей от конкретно заданных параметров. Качество движения зависит от возрастания линейных размеров, масс, моментов инерции, а также скоростей и других механических параметров грузоподъемных средств. Достижение стабильности работы выносных стреловых грузоподъемных средств достигается путем распределения нагрузки между утлегарью (выносной стрелой грузоподъемного средства) и опорными колесами колесного шасси. Считаем, что при существовании ряда концепцией со своими теориями. возможно определение стабильности работы стрелового грузоподъемного средства на колесном шасси. Нами установлено, что возможно обеспечить стабильность работы путем выбора целесообразных значений механических составляющих всех звеньев рабочего механизма для спланировано составленных рабочих ситуаций. В зависимости от возможного размещения грузоподъемного устройства показатели стабильности работы меняются и это подтверждают составленные нами математические выражения, которые приводятся в статье. Установлено, что путем варьирования различными вариантами положений и массой составляющих элементов конструкции грузоподъемного средства, а также графически определяя возможные варианты перемещения груза в зависимости от заданной длины утлегарьи, имеет место выражение, позволяющее определить ряд значений масс, безопасно поднимаемых грузоподъемным средством. Нами получены значения необходимых для графических построений грузовых характеристик грузоподъемного средства, выражающие зависимость между массой груза и вылетом утлегарьи с весом ее элементов. Реакции в шарнирах утлегарьи и усилия в ее составляющих звеньях возможно установить из данных грузовой характеристики. Стремление обеспечить максимальную стабильность работы грузоподъемного средства накладывает ограничения на контроль за несколькими подвижными операциями одновременно, что неблагоприятно сказывается на эффективности рабочего процесса. Установили, что обеспечение стабильности работы в поперечной и продольной плоскостях грузоподъемного средства является необходимым компонентом безопасной эксплуатации. По зависимостям для определения показателя грузового равновесия возможно определение предварительного места установки выносных опор грузоподъемного средства. Как подтверждают полученные результаты, стабильность работы грузоподъемного средства в продольном направлении определяется аналогично стабильности работы в поперечном направлении и для номинальной массы груза при наибольшем вылете утлегарьи и выставленных выносных опорах. В итоге отметим, что показателем грузового равновесия служит отношение удерживающего момента относительно ребра опрокидывания, создаваемого весом грузоподъемного средства на колесном шасси с учетом уменьшающих его дополнительных внешних нагрузок и влияния уклона площадки к опрокидывающему моменту, создаваемому рабочим грузом. The article presents for consideration the characteristics of the stability of the boom lifting equipment on a wheeled chassis in the form of mathematical expressions. Mathematical expressions are presented in the form of not cumbersome dependencies on specified parameters. The quality of movement depends on the increase in linear dimensions, masses, moments of inertia, as well as speeds, and other mechanical parameters of the lifting equipment. Achievement of the stability of the outboard boom lifting device is achieved by distributing the load between the jib boom (outboard boom of the lifting device) and the support wheels of the wheeled chassis. We believe that with the existence of a number of concepts with their theories, it is possible to determine the stability of the boom lifting device on a wheeled chassis. It has been found that it is possible to ensure the stability of work by choosing the appropriate values of the mechanical components of all links of the working mechanism for planned working situations. Depending on the possible placement of the lifting device, the stability indicators are changed, and this is confirmed by the mathematical expressions we compiled, which are given in the article. It has been established that by varying the positions and the mass of the constituent elements of the structure of the lifting device, as well as graphically defining the possible options of the load moving, depending on the given length of the jib boom, an expression takes place that makes it possible to determine a number of values of the masses safely lifted by the lifting device. There have been obtained the values of the cargo characteristics of the lifting device necessary for graphic constructions, expressing the relationship between the weight of the cargo and the overhanging of the jib boom with the weight of its elements. The reactions in the joints of the jig boom and the forces in its constituent links can be established from the data of the load characteristics. The desire to ensure maximum stability in the operation of the lifting device imposes restrictions on the control of several mobile operations at the same time, which adversely affects the efficiency of the work process. It has been established that ensuring the stability of operation in the transverse and longitudinal planes of the lifting device is a necessary component of safe operation. According to the dependencies for determining the indicator of cargo balance, it is possible to determine the preliminary installation site of the outriggers of the lifting device. As the results obtained confirm, the stability of the operation of the lifting device in the longitudinal direction is determined similarly to the stability of the operation in the transverse direction and for the nominal weight of the load with the greatest overhanging of the jib boom and the set outriggers. As a result, we note that the ratio of the holding moment relative to the overturning rib created by the weight of the lifting device on the wheeled chassis, taking into account the additional external loads that reduce it and the influence of the platform slope to the overturning moment created by the working load, serves as an indicator of the cargo balance.


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