Sequence Distribution of 1,4-Polybutadienes

1978 ◽  
Vol 51 (2) ◽  
pp. 168-179 ◽  
Author(s):  
Yasuyuki Tanaka ◽  
Hisaya Sato ◽  
Koichi Hatada ◽  
Yoshio Teeawaki ◽  
Hiroshi Okuda

Abstract The spin-decoupled 1H NMR and 13C NMR methods were employed for the determination of the cis-trans sequence distribution in polybutadiene. Poly(butadiene-2,3-d2) and cis-trans isomerized polybutadienes were used for the peak assignment and the resonance of methylene protons in cis-trans linkage could be described as an A1B2 system. The dyad and triad sequence distributions of cis-1,4 and trans-1,4 units were determined for isomerized, equibinary, and lithium catalyzed polybutadienes, and polycyclooctadienes. The accuracy of the measurements was also studied comparing the results with those by infrared method.

Polymer ◽  
2006 ◽  
Vol 47 (22) ◽  
pp. 7827-7834 ◽  
Author(s):  
Yanmei Wang ◽  
Hirokuni Ono ◽  
Atsushi Ikeda ◽  
Naruhito Hori ◽  
Akio Takemura ◽  
...  

Carbon ◽  
1998 ◽  
Vol 36 (7-8) ◽  
pp. 1043-1050 ◽  
Author(s):  
J.M. Andrésen ◽  
Y. Martín ◽  
S.R. Moinelo ◽  
M.M. Maroto-Valer ◽  
C.E. Snape

1985 ◽  
Vol 1 (1) ◽  
pp. 91-92 ◽  
Author(s):  
Shigetoshi AMIYA ◽  
Masao UETSUKI

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