The Rheology of Processing Quality of Raw Rubbers
Abstract After a crude rubber, such as Hevea or GR-S, has been compounded with the ingredients necessary for vulcanizing, or curing, the raw mix must be formed in some way before it is cured. This forming operation is nearly always either calendering or extruding. Naturally, it is important that the stock should take the desired form as closely as possible; but in practice it is found that elastomers are in general difficult to form. It seems to be inevitable that those materials which exhibit long-range elasticity after curing also exhibit considerable elasticity before curing and refuse, therefore, to hold their shape after a forming operation. This and other processing troubles were handled in the early history of the rubber industry simply by trial-and-error methods in the factories. Later, particularly during the last ten years, further progress in processing problems was made by introducing various plastometers and other devices for testing specific properties of the raw stock. These test methods replaced simple tests by hand and by visual inspection, and made it possible to set up specifications for some of the stock properties empirically found necessary for acceptable processing. As a final step in processing control, there are now being developed, in the industry, methods for making quantitative measurements of particular processing defects. Such methods involve a small or full-scale processing operation under standardized conditions, and a standardized procedure for quantitative evaluation of the results in terms of departures from perfection. In the present discussion of processing quality of raw stocks in the rubber industry, various specific processing defects are described, various rheological methods used for testing raw stocks are mentioned, and finally, a few experimental results are reported which show correlations between some of the rheological tests and quantitative measurements of certain processing properties.