Stiffening Effect of Pigments in Rubber
Abstract The use of reinforcing pigments in rubber, especially in synthetic rubber, is important in securing desirable physical properties. The earlier literature on the subject has been reviewed by Shepard, Street, and Park. Several theories were advanced to explain the effectiveness of reinforcing pigments in rubber. Some of these emphasized the importance of particle size and shape: others, the chemical composition and surface activity. The electron microscope has now furnished more reliable information on the particle size and shape of pigments, especially of carbon blacks, than was available in the earlier work2. The carbon blacks used in rubber compounding are essentially spherical; the mean diameter varies from 28 to 274 mµ for different types. Systematic studies have been carried out to show the influence of particle size and surface area on various physical testing indices used to evaluate rubber compounds. The x-ray structure of rubber stocks containing carbon black has been investigated. Several articles dealing with the theory of pigment reinforcement have appeared. This additional work has not clarified the original concepts advanced to explain filler reinforcement, but the research of Wiegand shows beyond doubt that particle size is the predominating factor in explaining differences in the properties of rubber compounded with various blacks. The present paper will attempt to explain some of the effects of pigment reinforcement of rubber, particularly increased stiffness, by simple mechanical considerations which may be regarded as extensions or extrapolations of the results of measurements on rubber in compression.