Metal Oxides as Vulcanization Activators for Sodium Butadiene Rubber

1959 ◽  
Vol 32 (1) ◽  
pp. 164-173
Author(s):  
M. Feldshteĭn ◽  
P. Orlovsky ◽  
B. Dogadkin
Keyword(s):  
Zinc Oxide ◽  
Metal Oxides ◽  
Butadiene Rubber ◽  
Metallic Oxides ◽  
High Alkali ◽  
Vulcanization Process

Abstract 1. Differences have been found in the action of metallic oxides as vulcanization activators for sodium butadiene rubbers polymerized by the rod and rodless methods. 2. It was found that unloaded mixes based on rodless sodium butadiene rubber, containing accelerators of the thiazole and sulfenamide types, do not require the addition of metallic oxides as vulcanization activators. 3. It was shown that addition of zinc oxide to mixes based on rodless rubber with high alkali contents retards the vulcanization process.

The Role of Metal Oxides as Activators of Vulcanization

1958 ◽  
Vol 31 (3) ◽  
pp. 526-538 ◽  
Author(s):  
M. Feldstein ◽  
P. Orlovsky ◽  
B. Dogadkin
Keyword(s):  
Zinc Oxide ◽  
Metal Oxides ◽  
Calcium Hydroxide ◽  
Large Degree ◽  
Positive Influence ◽  
Butadiene Rubber ◽  
Activation Effect ◽  
Vulcanization Process ◽  
Butadiene Styrene

Abstract 1. The activation effect of metal oxides on the process of culvanization of nonpigmented compounds of rod polymerized sodium butadiene rubber differs from the effect in rodless polymerized rubber. In the latter case zinc oxide not only is not an activator but it retards the vulcanization process. 2. The role of activators depends, to a large degree, on the type of vulcanization accelerator and active filler used. 3. Metal oxides increase the amount of structure formation in the vulcanizate. 4. With regard to butadiene styrene rubber (SKS-30A), calcium hydroxide appears to have stronger activating effect on vulcanization than zinc oxide. 5. The special effectiveness of calcium hydroxide in compounds of butadiene styrene rubber is a result of its independent structure forming ability and accelerating influence on the reaction between rubber and sulfur. 6. Magnesium oxide has a positive influence on the technical properties of rubber and on the durability of tires prepared with butadiene styrene and sodium butadiene rubbers.

scholarly journals A critical review of synthesis parameters affecting the properties of zinc oxide nanoparticle and its application in wastewater treatment

2021 ◽  
Vol 11 (2) ◽  
Author(s):  
E. Y. Shaba ◽  
J. O. Jacob ◽  
J. O. Tijani ◽  
M. A. T. Suleiman
Keyword(s):  
Zinc Oxide ◽  
Metal Oxides ◽  
Zinc Oxide Nanoparticles ◽  
Textural Properties ◽  
Oxide Nanoparticles ◽  
Zinc Oxide Nanoparticle ◽  
Synthesis Parameters ◽  
Metal Precursors ◽  
Removal Of Heavy Metals ◽  
Oxide Nanoparticle

AbstractIn this era, nanotechnology is gaining enormous popularity due to its ability to reduce metals, metalloids and metal oxides into their nanosize, which essentially alter their physical, chemical, and optical properties. Zinc oxide nanoparticle is one of the most important semiconductor metal oxides with diverse applications in the field of material science. However, several factors, such as pH of the reaction mixture, calcination temperature, reaction time, stirring speed, nature of capping agents, and concentration of metal precursors, greatly affect the properties of the zinc oxide nanoparticles and their applications. This review focuses on the influence of the synthesis parameters on the morphology, mineralogical phase, textural properties, microstructures, and size of the zinc oxide nanoparticles. In addition, the review also examined the application of zinc oxides as nanoadsorbent for the removal of heavy metals from wastewater.

Effect of Calcination on the Basic Strength of Surface Modified Nano-Zinc Oxide Characterised by FTIR and Back Titration Methods

2015 ◽  
Vol 1107 ◽  
pp. 326-332
Author(s):  
Abdul Rahim Yacob ◽  
Kamaluddeen Suleiman Kabo
Keyword(s):  
Zinc Oxide ◽  
Metal Oxides ◽  
Base Catalysis ◽  
Nano Zinc Oxide ◽  
Back Titration ◽  
And Performance ◽  
Nano Zinc ◽  
Surface Modified ◽  
Heterogeneous Base ◽  
Basic Strength

The use of metal oxides in heterogeneous base catalysis has gained a large interest due to their application in many chemical and industrial processes and is environmental friendly. Basic metal oxides are commonly used and their structures, morphology and performance can be modified by method of preparation and thermal activation. In this study, surface modified amphoteric zinc oxide was prepared via hydration-dehydration method and characterised by TGA and FTIR. The basic strength at various temperatures is characterised by FTIR and back titration analyses. The results shows that surface modified zinc oxide has the highest basic strength of 1.453mmolg-1at 400°C making it a relatively good and suitable compound for use in heterogeneous basic catalysis. This result is also supported by FTIR spectra which show possible relationship between the Lewis O2-and increasing basic strength.

Studies on Dicumyl Peroxide Vulcanization of Styrene—Butadiene Rubber in Presence of Sulfur and 2-Mercaptobenzothiazole

1974 ◽  
Vol 47 (2) ◽  
pp. 266-281 ◽  
Author(s):  
C. K. Das ◽  
S. Banerjee
Keyword(s):  
Zinc Oxide ◽  
Stearic Acid ◽  
Crosslink Density ◽  
Addition Reaction ◽  
Styrene Butadiene Rubber ◽  
Methyl Groups ◽  
Butadiene Rubber ◽  
First Order ◽  
First Order Kinetics ◽  
Styrene Butadiene

Abstract The effect of sulfur, MBT, zinc oxide, and stearic acid on the DCP vulcanization of SBR has been studied. DCP decomposition obeys first order kinetics in all cases, but its rate constant is higher in presence of MBT. Sulfur and MBT reduce the crosslink density due to DCP. In the mixes containing sulfur, MBT, zinc oxide, and stearic acid in presence of DCP the crosslink density is initially additive. Here oxidation of some pendent vinyl groups are effected by DCP, and these groups also take part in thiol addition reaction with MBT. The thiazole accelerated sulfuration of SBR proceeds fundamentally by the same mechanism as reported for NR, but the details show slight difference chiefly due to the presence of pendent vinyl groups and styrene units in the chain and due to the absence of pendent methyl groups in SBR.

Farming of maize-like zinc oxide via a modified SILAR technique as a selective and sensitive nitrogen dioxide gas sensor

RSC Advances ◽  
2016 ◽  
Vol 6 (93) ◽  
pp. 90916-90922 ◽  
Author(s):  
V. L. Patil ◽  
S. A. Vanalakar ◽  
A. S. Kamble ◽  
S. S. Shendage ◽  
J. H. Kim ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Nitrogen Dioxide ◽  
Metal Oxides ◽  
Gas Sensor ◽  
Hierarchical Nanostructures ◽  
Silar Technique

Novel hierarchical nanostructures of metal oxides synthesized via simplistic SILAR cycles.

Effects of Amines on Chemical and Physical Behaviors of Viscous Precursor Sols to Indium Gallium Zinc Oxide

2013 ◽  
Vol 1547 ◽  
pp. 123-128 ◽  
Author(s):  
Nobuko Fukuda ◽  
Shintaro Ogura ◽  
Ken-ichi Nomura ◽  
Hirobumi Ushijima
Keyword(s):  
Zinc Oxide ◽  
Shear Rate ◽  
Metal Oxides ◽  
Boiling Point ◽  
Indium Gallium Zinc Oxide ◽  
High Concentration ◽  
Lower Shear ◽  
Metal Nitrates ◽  
Lower Shear Rate ◽  
Indium Gallium

ABSTRACTWe synthesized viscous precursors to indium gallium zinc oxide (IGZO) using three kinds of alcoholamines, ethanolamine (EA), diethanolamine (DEA), and triethanolamine (TEA), by a simple process. The viscous precursors are obtained just by vigorous stirring of alcoholamine and urea in an aqueous solution containing the metal nitrates during heating at 150-160 °C. The precursor containing EA (EA-precursor) is a pale-orange suspension containing aggregates of the metal hydroxides and shows pseudoplastic flow. The precursors containing DEA (DEA-precursor) and TEA (TEA-precursor) are transparent pale-yellow and dark-orange sols, respectively. They give Newtonian flow in the lower shear rate and pseudoplastic flow in the higher shear rate. Higher concentration of metal salts leads to higher viscosity of the precursors. According to thermogravimetry-differential thermal analysis (TG-DTA) for the EA- and DEA-precursors, evaporation of alcoholamine occurs at around each boiling point and subsequently formation of metal oxides occur at around 300 °C. In the case of the TEA-precursor, formation of metal oxides occurs before pyrolysis of TEA attributed to the higher boiling point of TEA. The thin IGZO film, which is prepared by spin-coating of the diluted DEA-precursor and subsequent sintering at 450 °C for 30 min, shows 0.02 cm2 ·V-1s-1 of the mobility and 10-5 of the on/off ratio. The highly viscous DEA-precursor containing high concentration of metal ions allows patterning in an area of 100 cm2 onto a surface of a silicon wafer with screen printing.

The Effects of Moisture in Metal Oxide on the Mechanical and Electric Properties of Dielectric Elastomer Composites

2020 ◽  
Vol 981 ◽  
pp. 40-44
Author(s):  
Syed Muhammad Aiman Syed Mohd Hakhiri ◽  
Ahmad Farimin Ahmad Osman ◽  
Siti Noor Hidayah Mustapha ◽  
Lau Kwan Yiew ◽  
Shamsul Zakaria
Keyword(s):  
Zinc Oxide ◽  
Titanium Dioxide ◽  
Metal Oxides ◽  
Breakdown Strength ◽  
Electrical Breakdown ◽  
Dielectric Elastomer ◽  
Pdms Film ◽  
Pdms Elastomer ◽  
Elastomer Composites ◽  
Major Factors

Dielectric elastomer (DE) technology are used in several applications for example generator, sensor and actuator. One of the major factors that limits the DE performance is premature electrical breakdown. Compositing is the example that have been reported to increase the breakdown strength. In this study polydimethylsiloxane (PDMS) film will be incorporated with two different fillers which are titanium dioxide (TiO2) and zinc oxide (ZnO). Both metal oxides will be calcined up to 300°C before they are added to the PDMS elastomer as fillers. The results show that the calcined TiO2 and ZnO that incorporated in PDMS films show significant increase of breakdown strengths. Meanwhile, the calcined TiO2 PDMS film give higher breakdown strength as comparison to the calcined ZnO counterpart.

scholarly journals Organic Zinc Salts as Pro-Ecological Activators for Sulfur Vulcanization of Styrene–Butadiene Rubber

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1723 ◽  
Author(s):  
Magdalena Maciejewska ◽  
Anna Sowińska ◽  
Judyta Kucharska
Keyword(s):  
Zinc Oxide ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Zinc Ions ◽  
Organic Zinc ◽  
Rubber Compounds ◽  
Curing Characteristics ◽  
Sulfur Vulcanization ◽  
Zinc Salts ◽  
Styrene Butadiene

Organic zinc salts and complexes were applied as activators for sulfur vulcanization of styrene–butadiene elastomer (SBR) in order to reduce the content of zinc ions in rubber compounds as compared with conventionally used zinc oxide. In this article, the effects of different organic zinc activators on the curing characteristics, crosslink densities, and mechanical properties of SBR as well as the aging resistance and thermal behavior of vulcanizates are discussed. Organic zinc salts seem to be good substitutes for zinc oxide as activators for sulfur vulcanization of SBR rubber, without detrimental effects to the vulcanization time and temperature. Moreover, vulcanizates containing organic zinc salts exhibit higher tensile strength and better damping properties than vulcanizate crosslinked with zinc oxide. The application of organic zinc activators allows the amount of zinc ions in SBR compounds to be reduced by 70–90 wt % compared to vulcanizate with zinc oxide. This is very important for ecological reasons, since zinc oxide is classified as being toxic to aquatic species.

ZINC OXIDE VERSUS MAGNESIUM OXIDE REVISITED. PART 1

2012 ◽  
Vol 85 (1) ◽  
pp. 38-55 ◽  
Author(s):  
Manuel Guzmán ◽  
Berta Vega ◽  
Núria Agulló ◽  
Ulrich Giese ◽  
Salvador Borrós
Keyword(s):  
Zinc Oxide ◽  
Environmental Impact ◽  
Natural Rubber ◽  
Metal Oxides ◽  
Environmental Effects ◽  
Model Compound ◽  
Rubber Industry ◽  
Sulfur Vulcanization ◽  
Activator System

Abstract Zinc oxide is a widely used compound in the rubber industry due to the excellent properties that it shows as activator, and consequently, its role in the mechanism of accelerated sulfur vulcanization has been extensively studied. Due to the increased concern about its environmental effects, several research studies have been carried out in order to substitute it with different metal oxides such us MgO. The effect of the activator system in order to minimize the environmental impact of the rubber goods has been explored. The work developed is presented in two parts. In Part 1, the influence of different mixtures of ZnO and MgO on the vulcanization of natural rubber has been investigated. In Part 2, model compound vulcanization has been used to study the role of MgO on the mechanism to gain a better understanding of the differences shown in Part 1.

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