Vulcanization of SBR in a Thermal Neutron Field
Abstract The nuclear reactions B10(n,α)Li7* and Li6(n,α)H3 can be used to generate highly ionizing particles in a pure thermal neutron field to vulcanize an otherwise transparent rubber compound. Vulcanizates have satisfactory physical properties comparable with those produced by other means of vulcanization, e.g., gamma rays and peroxides. Such vulcanizates possessed negligible residual radioactivity. The somewhat analogous initiating systems gave vastly different vulcanizates with the same parent rubber compound in a helium atmosphere, and a possible explanation is presented. The G values for lithium methoxide promotion (ca. 3) are comparable with those obtained with gamma-ray vulcanizates. Promotion is less efficient with boron nitride, the average values of G being approximately 0.9. The irradiation atmosphere has a pronounced influence on the type of vulcanizate produced and on the energy utilization. Substitution of air for helium as the irradiation atmosphere increases net crosslinking of cold rubber with boron nitride promotion, while it decreases it when lithium methoxide is used as the promoter.