The Oil Resistance of Rubber. I Study of the Swelling of Vulcanized Rubber

1936 ◽  
Vol 9 (1) ◽  
pp. 70-73
Author(s):  
Yoshio Tanaka ◽  
Shû Kambara ◽  
Jirô Noto
Keyword(s):  
Molecular Structure ◽  
Elastic Properties ◽  
Mixed Solvents ◽  
Experimental Results ◽  
Stress Strain ◽  
Oil Resistance ◽  
Effect Of Solvents ◽  
Vulcanized Rubber

Abstract To study the effect of solvents on the elastic properties of vulcanized rubber, the following three points were investigated. 1. The swelling maximum obtained by various mixed solvents. 2. The stress-strain curves of rubber swollen to different degrees. 3. Time-swelling and time-deswelling curves. The spiral theory of molecular structure of rubber proposed by Fikentscher and Mark is utilized to explain the experimental results.

The Effect of Solvents on the Stress-Strain Curve of Vulcanized Rubber

1930 ◽  
Vol 3 (1) ◽  
pp. 19-21 ◽  
Author(s):  
H. A. Tiltman ◽  
B. D. Porritt
Keyword(s):  
Tensile Strength ◽  
Marked Effect ◽  
Strain Curve ◽  
Theoretical Interest ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Cohesive Forces ◽  
Effect Of Solvents ◽  
Vulcanized Rubber ◽  
Permanent Effect

Abstract (1) The results indicate that the rigidity of a piece of vulcanized rubber is considerably reduced by the absorption of small amounts of a solvent; thus, at a strain of 6 ( = 600 per cent elongation) the absorption of 5 per cent by weight ( = 8 per cent by volume) of benzene lowers the rigidity by 21 per cent. (2) The greatest effect is produced by the first 20 or 30 per cent (by weight) of absorbed benzene, further absorption having a less marked effect on the stress-strain curve. (3) The absorption of solvent seems to have very little effect on the breaking elongation, although the tensile strength is considerably lowered. This conclusion, however, is probably no longer true in the case of rubber swollen by immersion in liquid, where the absorption is very much greater than in the present tests. (4) Absorption of solvent followed by complete drying appears to produce a slight, but technically negligible, permanent effect on the stress-strain curve. It is evident from these results that when it is necessary to use solvents, either in the process of manufacture or the after-treatment of rubber products, these should be selected as free as possible from high-boiling constituents liable to be permanently retained by the rubber with consequent detriment to its strength. A conclusion of some theoretical interest is that since all the stresses in the present investigation were calculated on the dimensions of the original dry rubber, the low rigidity of swollen rubber cannot be ascribed simply to the “dilution” of the rubber by the absorbed liquid, but must be due to a loosening of the cohesive forces between the ultimate particles of the material.

scholarly journals A parametric prediction of the Young’s modulus of polymers enhanced with ΜWCNTs

2018 ◽  
Vol 233 ◽  
pp. 00025
Author(s):  
P.V. Polydoropoulou ◽  
K.I. Tserpes ◽  
Sp.G. Pantelakis ◽  
Ch.V. Katsiropoulos
Keyword(s):  
Young’S Modulus ◽  
Elastic Properties ◽  
Young's Modulus ◽  
Experimental Results ◽  
Scale Model ◽  
Fe Model ◽  
Multi Scale ◽  
Unit Cells ◽  
Random Dispersion

In this work a multi-scale model simulating the effect of the dispersion, the waviness as well as the agglomerations of MWCNTs on the Young’s modulus of a polymer enhanced with 0.4% MWCNTs (v/v) has been developed. Representative Unit Cells (RUCs) have been employed for the determination of the homogenized elastic properties of the MWCNT/polymer. The elastic properties computed by the RUCs were assigned to the Finite Element (FE) model of a tension specimen which was used to predict the Young’s modulus of the enhanced material. Furthermore, a comparison with experimental results obtained by tensile testing according to ASTM 638 has been made. The results show a remarkable decrease of the Young’s modulus for the polymer enhanced with aligned MWCNTs due to the increase of the CNT agglomerations. On the other hand, slight differences on the Young’s modulus have been observed for the material enhanced with randomly-oriented MWCNTs by the increase of the MWCNTs agglomerations, which might be attributed to the low concentration of the MWCNTs into the polymer. Moreover, the increase of the MWCNTs waviness led to a significant decrease of the Young’s modulus of the polymer enhanced with aligned MWCNTs. The experimental results in terms of the Young’s modulus are predicted well by assuming a random dispersion of MWCNTs into the polymer.

Relation between Molecular Weights and Physical Properties of Rubber Fractions

1941 ◽  
Vol 14 (3) ◽  
pp. 580-589 ◽  
Author(s):  
G. Gee ◽  
L. R. G. Treloar
Keyword(s):  
Molecular Weight ◽  
Natural Rubber ◽  
Physical Properties ◽  
High Molecular Weight ◽  
Elastic Properties ◽  
Elastic Material ◽  
Experimental Results ◽  
Molecular Weights ◽  
High Elasticity ◽  
Latex Rubber

Abstract As high elasticity is a property possessed only by substances of high molecular weight, it is of interest to enquire into the relation between the elastic properties of a highly elastic material such as rubber and its molecular weight. An investigation on these lines has been made possible through the work of Bloomfield and Farmer, who have succeeded in separating natural rubber into fractions having different average molecular weights. The more important physical properties of these fractions have been examined with the object of determining which of the properties are dependent on molecular weight and which are not. Fairly extensive observations were made on the fractions from latex rubber referred to as Nos. 2, 3 and 4 by Bloomfield and Farmer, and some less extensive observations were carried out on the less oxygenated portion of fraction No. 1 obtained from crepe rubber (called hereafter 1b) . Before considering these experimental results, and their relation to the molecular weights of the fractions, it will be necessary to refer briefly to the methods used for the molecular-weight determinations, and to discuss the significance of the figures obtained.

Definition of the yield point in plasticity and its effect on the shape of the yield locus

1966 ◽  
Vol 1 (4) ◽  
pp. 331-338 ◽  
Author(s):  
T C Hsu
Keyword(s):  
Yield Point ◽  
Experimental Work ◽  
Strain Curve ◽  
Yield Locus ◽  
Experimental Results ◽  
Stress Strain Curve ◽  
Proportional Limit ◽  
Stress Strain ◽  
Small Section ◽  
Definition Of

Three different definitions of the yield point have been used in experimental work on the yield locus: proportional limit, proof strain and the ‘yield point’ by backward extrapolation. The theoretical implications of the ‘yield point’ by backward extrapolation are examined in an analysis of the loading and re-loading stress paths. It is shown, in connection with experimental results by Miastkowski and Szczepinski, that the proportional limit found by inspection is in fact a point located by backward extrapolation based on a small section of the stress-strain curve, near the elastic portion of the curve. The effect of different definitions of the yield point on the shape of the yield locus and some considerations for the choice between them are discussed.

scholarly journals Postheated Model of Confined High Strength Fibrous Concrete

2016 ◽  
Vol 2016 ◽  
pp. 1-14 ◽  
Author(s):  
Kaleem A. Zaidi ◽  
Umesh K. Sharma ◽  
N. M. Bhandari ◽  
P. Bhargava
Keyword(s):  
High Temperature ◽  
Volume Fraction ◽  
Fibre Volume Fraction ◽  
High Strength ◽  
Fibre Volume ◽  
Experimental Results ◽  
Confined Concrete ◽  
Structural Safety ◽  
Stress Strain ◽  
Fibrous Concrete

HSC normally suffers from low stiffness and poor strain capacity after exposure to high temperature. High strength confined fibrous concrete (HSCFC) is being used in industrial structures and other high rise buildings that may be subjected to high temperature during operation or in case of an accidental fire. The proper understanding of the effect of elevated temperature on the stress-strain relationship of HSCFC is necessary for the assessment of structural safety. Further stress-strain model of HSCFC after exposure to high temperature is scarce in literature. Experimental results are used to generate the complete stress-strain curves of HSCFC after exposure to high temperature in compression. The variation in concrete mixes was achieved by varying the types of fibre, volume fraction of fibres, and temperature of exposure from ambient to 800°C. The degree of confinement was kept constant in all the specimens. A comparative assessment of different models on the high strength confined concrete was also conducted at different temperature for the accuracy of proposed model. The proposed empirical stress-strain equations are suitable for both high strength confined concrete and HSCFC after exposure to high temperature in compression. The predictions were found to be in good agreement and well fit with experimental results.

scholarly journals A Strain Rate-Dependent Damage Evolution Model for Concrete Based on Experimental Results

2021 ◽  
Vol 2021 ◽  
pp. 1-8
Author(s):  
Bin Xu ◽  
Xiaoyan Lei ◽  
P. Wang ◽  
Hui Song
Keyword(s):  
Strain Rate ◽  
Uniaxial Compression ◽  
Damage Evolution ◽  
Damage Model ◽  
Evolution Model ◽  
Experimental Results ◽  
Strain Rates ◽  
Compression Tests ◽  
Stress Strain ◽  
Actual Damage

There are various definitions of damage variables from the existing damage models. The calculated damage value by the current methods still could not well correspond to the actual damage value. Therefore, it is necessary to establish a damage evolution model corresponding to the actual damage evolution. In this paper, a strain rate-sensitive isotropic damage model for plain concrete is proposed to describe its nonlinear behavior. Cyclic uniaxial compression tests were conducted on concrete samples at three strain rates of 10−3s−1, 10−4s−1, and 10−5s−1, respectively, and ultrasonic wave measurements were made at specified strain values during the loading progress. A damage variable was defined using the secant and initial moduli, and concrete damage evolution was then studied using the experimental results of the cyclic uniaxial compression tests conducted at the different strain rates. A viscoelastic stress-strain relationship, which considered the proposed damage evolution model, was presented according to the principles of irreversible thermodynamics. The model results agreed well with the experiment and indicated that the proposed damage evolution model can accurately characterize the development of macroscopic mechanical weakening of concrete. A damage-coupled viscoelastic constitutive relationship of concrete was recommended. It was concluded that the model could not only characterize the stress-strain response of materials under one-dimensional compressive load but also truly reflect the degradation law of the macromechanical properties of materials. The proposed damage model will advance the understanding of the failure process of concrete materials.

scholarly journals Elastic Properties of Magnetorheological Elastomers in a Heterogeneous Uniaxial Magnetic Field

2018 ◽  
Vol 19 (10) ◽  
pp. 3045 ◽  
Author(s):  
Takehito Kikuchi ◽  
Yusuke Kobayashi ◽  
Mika Kawai ◽  
Tetsu Mitsumata
Keyword(s):  
Magnetic Field ◽  
Elastic Properties ◽  
Uniform Magnetic Field ◽  
Large Strain ◽  
Small Strain ◽  
Experimental Results ◽  
The Other ◽  
Magnetorheological Elastomers ◽  
Other Hand ◽  
Strain Model

Magnetorheological elastomers (MREs) are stimulus-responsive soft materials that consist of polymeric matrices and magnetic particles. In this study, large-strain response of MREs with 5 vol % of carbonyl iron (CI) particles is experimentally characterized for two different conditions: (1) shear deformation in a uniform magnetic field; and (2), compression in a heterogeneous uniaxial magnetic field. For condition (1), dynamic viscoelastic measurements were performed using a rheometer with a rotor disc and an electric magnet that generated a uniform magnetic field on disc-like material samples. For condition (2), on the other hand, three permanent magnets with different surface flux densities were used to generate a heterogeneous uniaxial magnetic field under cylindrical material samples. The experimental results were mathematically modeled, and the relationship between them was investigated. We also used finite-element method (FEM) software to estimate the uniaxial distributions of the magnetic field in the analyzed MREs for condition (2), and developed mathematical models to describe these phenomena. By using these practicable techniques, we established a simple macroscale model of the elastic properties of MREs under simple compression. We estimated the elastic properties of MREs in the small-strain regime (neo–Hookean model) and in the large-strain regime (Mooney–Rivlin model). The small-strain model explains the experimental results for strains under 5%. On the other hand, the large-strain model explains the experimental results for strains above 10%.

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