Relationship between Viscoelastic Properties and Characteristics of Filler-Gel in Filled Rubber System

1999 ◽  
Vol 72 (4) ◽  
pp. 657-672 ◽  
Author(s):  
Fumito Yatsuyanagi ◽  
Hiroyuki Kaidou ◽  
Masayoshi Ito
Keyword(s):  
Relaxation Time ◽  
Viscoelastic Properties ◽  
Rolling Resistance ◽  
Rubber Composites ◽  
Component System ◽  
Filled Rubber ◽  
Wide Line ◽  
Dynamic Storage ◽  
Tan Δ ◽  
Multi Component System

Abstract The wide-line NMR and viscoelastic measurements were carried out for the filled rubber systems. NMR results revealed that the filler-gel in the filled rubber composites had a multi-component system depending on the mobility of rubber molecules. The fraction and the spin-spin relaxation time of each component were well correlated with the viscoelastic properties such as dynamic storage modulus (E′) and loss-tangent (tan δ) of the filled rubber systems. Such findings turned out to be useful in designing new tread materials with well-balanced wet traction and rolling resistance in tires.

Study on silica-based rubber composites with epoxidized natural rubber and solution styrene butadiene rubber

2020 ◽  
pp. 096739112097139
Author(s):  
Sung Ho Song
Keyword(s):  
Natural Rubber ◽  
Rolling Resistance ◽  
Epoxidized Natural Rubber ◽  
Rubber Matrix ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Composites ◽  
Filled Rubber ◽  
Polar Functional Groups ◽  
Styrene Butadiene

Carbon black has been replaced with silica as a reinforcing filler in tire tread compounds. This change has led to lower rolling resistance and improved hysteretic losses of so-called “green tires.” However, the dispersion of silica in the rubber matrix is an important issue due to the poor compatibility of hydrophilic silica with a hydrophobic rubber matrix. Recently, some rubbers with polar functional groups that can interact with silica have been studied to improve the interaction in silica-filled rubber composites. In this work, we fabricated the silica-filled rubber composites with solution styrene butadiene rubber (SSBR) and epoxidized natural rubber (ENR) and evaluated their properties in a silica-containing rubber formulation compared to conventional SBR and NR. The silica-embedded polar rubber matrix exhibits remarkable enhancement in the modulus, tensile strength, and abrasion properties due to an efficient dispersion of the silica and improvement of interfacial interactions with the rubber matrix. The polar rubber composite exhibits an enhanced dry and wet braking and improved rolling resistance due to the improved dispersion of the silica in the rubber matrix. These results show that rubber composites prepared with polar rubbers have great potential for tire engineering applications.

scholarly journals High Silica Content Graphene/Natural Rubber Composites Prepared by a Wet Compounding and Latex Mixing Process

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2549
Author(s):  
Jian Wang ◽  
Kaiye Zhang ◽  
Guoxia Fei ◽  
Martina Salzano de Luna ◽  
Marino Lavorgna ◽  
...  
Keyword(s):  
Natural Rubber ◽  
Mechanical Test ◽  
Rolling Resistance ◽  
Silica Content ◽  
Mixing Process ◽  
Rubber Composites ◽  
Mechanical Mixing ◽  
Natural Rubber Composites ◽  
Rubber Composite ◽  
Tan Δ

The reduced graphene oxide (rGO) modified natural rubber composite (NR) filled with high contents of silica was prepared by a wet compounding and latex mixing process using a novel interface modifier cystamine dihydrochloride (CDHC) with coagulation ability. CDHC acts as a coagulation agent through electrostatic interaction with rGO, SiO2, and latex rubber particles during the latex-based preparation process, while in the obtained silica/graphene/natural rubber composites, CDHC acts as an interface modifier. Compared with the composites prepared by the conventional mechanical mixing method, the dispersion of both rGO and SiO2 in the composites made by a wet compounding and latex mixing process is improved. As a result, the obtained silica/graphene/natural rubber composite prepared by this new method has good comprehensive properties. A Dynamic Mechanical Test suggests that the tan δ values of the composites at 60 °C decrease, indicating a low rolling resistance with increasing the graphene content at a low strain, but it increases at a higher strain. This unique feature for this material provides an advantage in the rubber tire application.

Relationships Between the Friction and Viscoelastic Properties of Rubber

2000 ◽  
Vol 28 (3) ◽  
pp. 178-195 ◽  
Author(s):  
N. Amino ◽  
Y. Uchiyama
Keyword(s):  
Viscoelastic Properties ◽  
Skid Resistance ◽  
Grain Sizes ◽  
Abrasive Grain ◽  
The Coefficient Of Friction ◽  
Tan Δ ◽  
Silicone Carbide ◽  
And Storage ◽  
Wet Skid Resistance ◽  
Frequency Curves

Abstract In this study, the relationships between friction and viscoelastic properties such as loss tangent tan δ and storage modulusE′ were examined. Wet skid resistance was measured using the British Pendulum Tester. The rubber specimens were rubbed againstfive silicone carbide cloths of differing abrasive grain sizes. The viscoelastic properties of the rubber specimens were measured with a viscoelasticspectrometer. From the data on wet skid resistance and viscoelastic properties, it is found that the coefficient of friction μ varies as follows:           μ = a + b · tan δ/E′ where a and b are constants. Tan δ/E′ was related to the hysteresis term of friction, and the μ-frequency curves were compared with the tan δ/E′ –frequency curves.

scholarly journals The Influence of the Addition of Nuts on the Thermal and Rheological Properties of Wheat Flour

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 3969
Author(s):  
Karolina Pycia ◽  
Lesław Juszczak
Keyword(s):  
Rheological Properties ◽  
Wheat Flour ◽  
Viscoelastic Properties ◽  
Control Sample ◽  
Scanning Calorimetry ◽  
Creep And Recovery ◽  
Research Material ◽  
Pasting Characteristics ◽  
Tan Δ ◽  
Weak Gels

The aim of the study was to assess the influence of replacing wheat flour with hazelnuts or walnuts, in various amounts, on the thermal and rheological properties of the obtained systems. The research material were systems in which wheat flour was replaced with ground hazelnuts (H) or walnuts (W) in the amount of 5%, 10%, and 15%. The parameters of the thermodynamic gelatinization characteristics were determined by the differential scanning calorimetry method. In addition, the pasting characteristics were determined with the use of a viscosity analyzer and the viscoelastic properties were assessed. Sweep frequency and creep and recovery tests were used to assess the viscoelastic properties of the tested gels. It was found that replacing wheat flour with nuts increased the values of gelatinization temperature, gelatinization, and retrogradation enthalpy, and the degree of retrogradation. The highest viscosity was characteristic of the control sample (2039 mPa·s), and the lowest for the paste with 15% addition of walnuts (1120 mPa·s). Replacing the flour with nuts resulted in a very visible reduction in the viscosity of such systems. In addition, gels based on the systems with the addition of H and W were weak gels (tan δ = G″/G′ > 0.1), and the values of G′ and G″ parameters decreased with the increased share of nuts in the systems. Creep and recovery analysis indicated that the systems in which wheat flour was replaced with hazelnuts were less susceptible to deformation compared to the systems with the addition of W.

Structure development in silica-filled rubber composites

1999 ◽  
Vol 48 (10) ◽  
pp. 1035-1041 ◽  
Author(s):  
Shigeyuki Ono ◽  
Yasutaro Kiuchi ◽  
Junich Sawanobori ◽  
Masayoshi Ito
Keyword(s):  
Structure Development ◽  
Rubber Composites ◽  
Filled Rubber

Multiponental Model Of Education According To The New Paradigm

2021 ◽  
Vol 03 (03) ◽  
pp. 365-370
Author(s):  
Ashurova Dilfuza Nabiyevna ◽  
◽  
Abjalilov Sanakul Xujamovich ◽  
Toshtemirova Kamola Ergashevna ◽  
◽  
...  
Keyword(s):  
Educational System ◽  
Modern Society ◽  
Educational Process ◽  
New Paradigm ◽  
Component System ◽  
Educational Processes ◽  
Multi Component System

In this work on the example of educational system of Uzbekistan the new paradigm of education is substantiated in the following edition: education through all life. It is demonstrated that the proposed in correspondence to this paradigm the formalized model reflects multi-component system, multi-variant approaches and cyclist of educational process in a modern society. The examples of educational processes which are modeled within the framework of proposed formalized model of education are presented.

scholarly journals Statistical physics of fracture and earthquakes

2018 ◽  
Vol 377 (2136) ◽  
pp. 20180202
Author(s):  
Soumyajyoti Biswas ◽  
Lucas Goehring ◽  
Bikas K. Chakrabarti
Keyword(s):  
Complex System ◽  
Stress Field ◽  
Statistical Physics ◽  
Disordered Materials ◽  
Emergent Properties ◽  
Theme Issue ◽  
Component System ◽  
Playing Field ◽  
Collective Response ◽  
Multi Component System

Manifestations of emergent properties in stressed disordered materials are often the result of an interplay between strong perturbations in the stress field around defects. The collective response of a long-ranged correlated multi-component system is an ideal playing field for statistical physics. Hence, many aspects of such collective responses in widely spread length and energy scales can be addressed by the tools of statistical physics. In this theme issue, some of these aspects are treated from various angles of experiments, simulations and analytical methods, and connected together by their common base of complex-system dynamics. This article is part of the theme issue ‘Statistical physics of fracture and earthquakes’ .

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